ABSTRACT
A new strategy for the preparation of hybridized materials with coexisting magnetism and conductivity was developed using singlemolecule magnets (SMMs) and molecular conductors. The new •–”ƒ–‡‰›Šƒ•˜ƒ”‹‘—•ƒ†˜ƒ–ƒ‰‡•‹…Ž—†‹‰‡ƒ•›‘†‹ϐ‹…ƒ–‹‘‘ˆ–Š‡‹” molecular and electronic features. The hybridized materials, [{M n2
4, n = 0, or 2) and [Mn2(5-MeOsaltmen)2(solvent)x][Ni(dmit)2]y · n solvent (x = 0 or 2, y = 2, or 7, n = 0 or 4, solvent = acetone or MeCN), were prepared from cationic SMMs and acceptor types of molecular …‘†—…–‘”•„›†‹ơ—•‹‘‘”‡Ž‡…–”‘…Š‡‹…ƒŽ…”›•–ƒŽŽ‹œƒ–‹‘‡–Š‘†•Ǥ In this review, the strategy for preparation of hybrid materials based on SMMs and molecular conductors and physical properties of the salts are discussed.
