ABSTRACT

Plasmonics [1-13], the study of the interaction between electro-

magnetic field and free electrons in a metal, has drawn increasing

attention recently due to its huge potential for solving many

eminent issues encountered by our world. Up to now, exciting

plasmonic applications, for instance, super-resolution imaging [14-

19], optical cloaking [20-23], and energy harvesting [24-29],

have been reported. Many other potential applications are under

development. All these developments are attributed to the advanced

nanofabrication techniques. Top-down nanofabrication techniques

such as electron-beam lithography [30-33] and focus ion beam

milling [34-40] allow the accurate fabrication of structures at

nanoscale with desirable trade-off on the high equipment expenses,

as well as the considerably long time during sample preparation.

Bottom-up techniques like self-assembly [41-43] can easily achieve

regular patterns at a large scale at a rather low cost but are

not preferred for the cases that require accurate positioning

and alignment with nanometer precision. Despite their strengths

and weaknesses, both top-down and bottom-up techniques make

their unique contributions to plasmonics by providing various

nanostructures for plasmonic applications for different purposes.

However, most plasmonic devices fabricated through top-down

and bottom-up techniques are passive, which greatly limits their

application because of the additional investments required in

fabricating another similar device with little change in the sample

design. Thus, the new research field of active plasmonics emerges,

which deals with reconfigurable function after the devices are

fabricated, with the help of active mediums responsive to certain

stimulus. The first original active plasmonic device is gallium-

coated plasmonic waveguides proposed by Krasavin and Zheludev

[44]. Since then, many other active mediums have been used

to build active plasmonic devices, including liquid crystals [45-

60], molecular machines [61, 62], elastic polymers [63-65], and

chemical oxidation/reduction [66-68]. Among all the mentioned

active mediums, liquid crystal stands out from all the rest because

of its large birefringence on refractive index, low threshold on

transition among different states, and versatile driven methods to

cause the transitions.