ABSTRACT
Our research group has developed a wide range of new experimental methods that are designed to be performed on ions stored within radio-frequency (RF) ion traps. In this chapter, we will emphasize the integration of trap technology within different experimental arrangements in order to perform unique scientic measurements. We will describe measurements of both trapped-ion electron diffraction (TIED) of metal cluster ions and radiative lifetimes of trapped biomolecular ions. Experiments will be discussed in sufcient detail to permit the advantages afforded by ion trap capabilities to be appreciated. This chapter is not intended as an extensive review of trap-related experimental measurements that are referred to and discussed elsewhere in the volumes of this series.
