ABSTRACT

Graphene, a two-dimensional sp2-hybridized carbon, has received

considerable attention due to their high surface area, often-cited

desirable physical and electrochemical properties. Various efforts

have been made on the preparation of the graphene via a number

of physical and chemical methods. Some of these methods provide

high-quality graphene and have opened up new possible routes to

address the challenges in preparation and molecular engineering

of high-quality processable graphene. The high restacking rate of

graphene sheets is the major drawback to attain the forecasted

high surface area of 3620 m2/g and associated electrochemical

properties. As high surface area carbon materials are promising

for enhanced energy storage, attempts have been made to exploit

graphene and graphene-based nanocomposite electrode materials

for supercapacitor, Li-ion battery, and Li-air battery applications.

This chapter highlights the fundamentals and recent progress

in graphene and graphene-based nanocomposite materials as

electrodes for supercapacitor, Li-ion battery, and Li-air battery. And,

a brief description of the synthesis andmodification of graphene and

graphene-based nanocomposite materials is presented.