ABSTRACT

Optical atomic spectral analysis is the detection (qualitative

analysis) and/or determination (quantitative analysis) of chemical elements within the spectral range from 100 nm

to 1 mm, using the characteristic line spectra of free atoms

in the gaseous state. The term spectroscopy is used both for

the visual observation of spectra and as a general term for

all spectroscopic observation and measurement pro-

cedures. The term spectrometry is related to a direct

photoelectric measurement of radiation using a dispersive

spectral apparatus. Depending on the spectral transition

used, we distinguish between atomic absorption spectro-

metry (AAS), atomic fluorescence spectrometry (AFS),

and optical emission spectrometry (OES). According to

IUPAC recommendation the acronym OES should be

used instead of the ambiguous AES for atomic emission

spectrometry in order to avoid confusion with Auger elec-

tron spectroscopy.