chapter  2
38 Pages

Mean Distance of Closest Approach of Ions: From Theory to Experiments

Department of Chemistry and Coimbra Chemistry Centre,University of Coimbra, 3004-535 Coimbra, Portugal, [email protected]

Abstract ................................................................................................... 18 2.1 Introduction .................................................................................... 18 2.2 Different Ways of Estimation of Parameter a from

Experimental and Theoretical Methods ......................................... 19 2.3 Results ............................................................................................ 44 2.5 Conclusion ..................................................................................... 50 Acknowledgments ................................................................................... 50 Keywords ................................................................................................ 50 References ............................................................................................... 50

ABSTRACT

A review on the importance of the estimated numerical values present in the literature for the mean distance of closest approach of ions, a, of electrolytes in aqueous solutions, determined from activity and diffusion coefficients and estimated by using different theoretical approaches, is presented and discussed.