ABSTRACT
Abstract .................................................................................................................214 9.1 Introduction ..................................................................................................214 9.2 Experimental ...............................................................................................214 9.4 Finding ktr by Use of Experimental Data of ................................................219 9.5 Adequacy Verification of the Process Mathematical Model ........................219 9.6 Conclusion ...................................................................................................221 Keywords ..............................................................................................................221 References .............................................................................................................221
The mathematical model of kinetic of radical polymerization of methyl methacrylate with consideration of autoacceleration has been developed using the model of the reaction rate constant of chain termination (the authors of the model being Hui and Hamielec). The parameters of the model have been determined by solving the inverse kinetic problem. The adequacy of the developed kinetic description has been proved by comparing of the theoretically calculated and experimental kinetic curves, and also the number average and weight average molecular weight of polymethyl methacrylate.
