ABSTRACT

Raman scattering (RS) spectroscopy enjoys broad application

in diagnostics of carbon-based materials. This method appears

particularly attractive because each allotropic form of carbon is

easily identifiable by its Raman spectra, is nondestructive, and

requires a small amount of material for analysis (in its confocal

version, the volume of the sample can be as small as 1 μm3).

When applied to analysis of detonation nanodiamonds (DNDs),

Raman spectroscopy can be used to advantage in determination

of the perfection of crystal structure, phase purity, and crystallite

size. The high quantum yield of luminescence of some impurity

centers embedded in diamond and their absolute photostability

have made nanodiamond (ND) one of the most promising materials

for fabrication of single-photon emitters and photoluminescent

biomarkers. This accounts for the pursuit of photoluminescent

properties of ND, including DND, having become a major goal in

present-day nanophotonics.