ABSTRACT

The energies associated with the fundamental vibrational modes of a chemical

compound lie within the range of 400-4000 cm21, a spectral region corresponding

to midinfrared (mid-IR) electromagnetic radiation. Transitions among vibrational

energy levels can be observed directly through their absorbance in the infrared

(IR) region of the spectrum or through inelastic scattering of incident energy via

the Raman effect. Overtones and combination bands of vibrational modes are

observed in the near-infrared (NIR) region of the spectrum (4000 to 13,350 cm21).