ABSTRACT

General Considerations . . . . . . . . . . . . . . . . . . . . . . 645

Preparation of Porous Materials . . . . . . . . . . . . . . . 646

Reactivity of Precursors in Sol-Gel Processes . . 646

Preparation of Materials with Special Functions 648

Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 651

Acknowledgments . . . . . . . . . . . . . . . . . . . . . . . . . . 651

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 651

Sol-gel techniques were used to prepare porous, organically modified silica materials. The introduction of

organic groupings was carried out with alkoxysilanes as precursors; methyl and propyl amino groups were

used. The results show that high-porosity materials can be synthesized; the microstructure strongly depends

on reaction conditions such as composition, solvent, catalyst type, and concentration. Microstructure tailor-

ing affects mechanical as well as adsorption properties, and custom-made materials such as abrasives and

adsorbents with special properties were synthesized.