ABSTRACT
L. I. MATIENKO, V. I. BINYUKOV, L. A. MOSOLOVA, E. M. MIL, and G. E. ZAIKOV
4.1 Introduction .................................................................................. 162 4.2 Experimental ................................................................................ 163 4.3 Results and Discussion ................................................................ 164 4.4 Conclusion ................................................................................... 184 Keywrods .............................................................................................. 186 References ............................................................................................. 186
4.1 INTRODUCTION
Mechanisms of catalysis with binary, and triple catalytic systems {NiII(acac)2+L
2} (L2 = MP, MP=N-metylpirrolidon-2), {NiII(acac)2+NaSt(or LiSt)+PhOH}, {FeIII(acac)3+L
2} (L2 = 18C6, CTAB) in the selective ethyl benzene oxidation by dioxygen into α-phenyl ethyl hydro peroxide are briefly discussed. The possibility of the formation of stable supramolecular nanostructures on the basis of nickel and iron heteroligand complexes NiII(acac)2∙NaSt(or LiSt)∙PhOH, Ni2(OAc)3(acac)L2·2H2O, Fex(acac) y18C6 m(H2O)n, and Fex(acac)y(CTAB)p(H2O)q, due to intermolecular Hbonds is researched with the AFM method. The specific structure self organization of nickel and iron heteroligand complexes as models of Ni(Fe) ARD Dioxygenases may be used for understanding the actions of these enzymes.
