ABSTRACT

KT bulk modulus L filler particle size l length of a crack l0 main chain skeletal length lk specific spatial scale of structural changes lst statistical segment length M repeated link molar mass, m ∞ relative amount of water m0 initial mass of ChT in a film Mcl molecular weight of the chain part between cluster Me molecular weight of chain n the number of cracks NA Avogadro number p solid-state component pc percolation threshold pKa universal index of acidity q parameter q ρmax the greatest and the smallest density values r the radius of a particle R universal gas constant Rcl distance between nanoclusters S macromolecule cross Sg cross-section of the contact channel S

г cross-section of the contact channel T testing temperature Tg testing, glass transition Tm melting temperatures Wc optimum speed of gases Wmax rate of the nucleus growth Wr relative speed of gases in the channel α the solubility coefficient αm parameterβp critical exponents ∆m weight the absorbed film of water ε1 real part of the value of dielectric transmissivity ε2 imaginary part of the value of dielectric transmissivity

εf strain at fracture εm dielectric constant of the surrounding medium εM dielectric transmissivity of the solvent ε

Y yield strain

η exponent qIP angle between the normal to IP λ length of a wave of the electromagnetic irradiation λb the smallest length of acoustic irradiation sequence λk length of irradiation sequence ν Poisson’s ratio νp correlation length ρ polymer density ρ polymer density ρcl nanocluster density ρd density if linear τ

0Y theoretical value of the shear stress at yielding

τin initial internal stress ϕf polymer matrix ϕif interfacial regions relative fraction φn nanofiller volume contents χ relative fraction of elastically Wn nanofiller mass contents