ABSTRACT

This chapter gives an overview of the theoretical background

of polymer field-effect transistors (PFETs). It starts with the

description of the molecular and electronic structures and optical

transitions in conjugated polymers which are used as an active layer

of PFETs. The second part of the chapter focuses on the work-

ing principles of PFETs including metal-insulator-semiconductor

capacitors. Finally, several charge transport models developed for

polymer and organic field-effect transistors and a few recent

progress are discussed.