ABSTRACT

Weoutline the principles ofmid-infrared vibrational spectroscopy of

molecular films on a metal surface structured with subwavelength-

sized geometric features, both self-assembled and fabricated fol-

lowing electromagnetic design. Molecular chemistry, optical physics,

and electromagnetic engineering approaches are presented. We

then review molecular film preparation techniques and substrate

fabrication technologies specific to surface-enhanced mid-infrared

spectroscopy.