This book embodies the proceedings of the Second International Symposium on Silanes and other Adhesion Promoters held in Newark, New Jersey, October 21--23, 1998. Silanes are the most popular and widely used coupling agents (or adhesion promoters) to promote adhesion between dissimilar materials in a variety of situations, e.g. coating technology, adhesive bonding, reinforced composites, etc. Since the first symposium on this topic in 1991, there had been a tremendous R&D activity in developing new and more effective adhesion promoters and in understanding and optimising the performance of available coupling agents. The technical program for the symposium contained 36 papers and reflected both overviews and original research contributors and the presenters hailed from academia, industry and other research laboratories. Many different aspects of coupling agents were discussed, and both fundamental and applied aspects were accorded due coverage. In addition to formal presentations, there were brisk and lively discussions throughout the symposium, and this event provided an opportunity for cross-pollination of ideas in the broad arena of adhesion promoters. This present volume contains 18 papers by experts from academia, industry and other research laboratories. All manuscripts were subjected to rigorous peer review and were suitably revised before inclusion in this volume. The book is divided into two parts as follows: Part 1. Silane Coupling Agents; and Part 2: Non-silane Coupling Agents/Adhesion Promotors. The topics covered include: silane adhesion prompters for hydrosilylation cure systems; sterically hindered silanes; study of silanes hydrolysis; adsorption of silanes on different substrates; interaction of water with silane films studied by neutron reflection; characterization of glass fiber sizings; silanes as dispersion promoters; corrosion protection of metals by silanes; surface 'Intelligraft' as a new class of adhesion promoters; hydroxymethylated resorcinol, sol-gels, and -diketone functionalised polymers as adhesion promoters; and plasma deposition of silanes.

part 1|174 pages

Silane Coupling Agents

chapter |11 pages

Novel silane adhesion promoters for hydrosilylation cure systems

ByMichael A. Lutz, Theresa E. Gentle, Susan V. Perz, Michael J. Owen

chapter |11 pages

Sterically hindered silanes for waterborne systems: A model study of silane hydrolysis

ByE. R. Pohl, A. Chaves, C. T. Danehey, A. Sussman, V. Bennett

chapter |16 pages

Direct spectroscopic measurements of adsorption of siloxane polymers onto glass fiber surfaces

ByL. G. Britcher, D. Kehoe, J. G. Matisons

chapter |13 pages

The use of XPS for characterisation of glass fibre sizings

ByJ. L. Thomason, D. W. Dwight

chapter |10 pages

Corrosion resistance imparted to aluminum by silane coupling agents

ByP. R. Underhill, D. L. Duquesnay

chapter |16 pages

Corrosion protection of aircraft aluminum alloys using bis-functional silanes

ByV. Subramanian, W. J. van Ooij

part 2|118 pages

Non-silane Coupling Agents/Adhesion Promoters

chapter |15 pages

Surface ‘IntelliGraft’ as a new class of adhesion promoters

ByE. T. Kang, J. F. Zhang, C. Q. Cui, T. B. Lim

chapter |16 pages

Hydroxymethylated resorcinol coupling agent for wood surfaces to produce exterior durable bonds

ByAlfred W. Christiansen, Charles B. Vick

chapter |9 pages

Sol-gels as alternative adhesion promoters for low-VOC, nonchromated adhesive and sealant applications

ByWilliam S. De Piero, James J. Mazza, Georgette B. Gaskin, Kay Y. Blohowiak

chapter |30 pages

Interfacial and corrosion studies of plasma polymer coated steel and galvanized steel

ByG. Grundmeier, M. Stratmann