ABSTRACT

Noble metal nanoparticles have attracted enormous scientific and technological interest because of their unique optical properties, which are related to surface plasmon resonances. The interest in nanosized metal particles dates back to ancient societies, when metals were used in various forms as decorative elements. From the famous Lycurgus cup, made by the Romans in the 4th century AD, through thousands of stained glasses in churches and cathedrals all over medieval Europe, bright-yellow, green, or red colors have been obtained by a touch of metallic additions during glass blowing. This peculiar interaction of light with nanometals can be widely tuned through the morphology and assembly of nanoparticles, thereby expanding the range of potential applications, from energy and information storage to biomedicine, including novel diagnostic and therapeutic methods.

This book compiles recent developments that clearly illustrate the state of the art in this cutting-edge research field. It comprises different review articles written by the teams of Prof. Luis Liz-Marzán, an international leader in chemical nanotechnology who has made seminal contributions to the use of colloid chemistry methods to understand and tailor the growth of metal particles at the nanoscale. Apart from synthesis, the book also describes in detail the plasmonic properties of nanomaterials and illustrates some representative applications. This book will appeal to anyone involved in nanotechnology, nanocrystal growth, nanoplasmonics, and surface-enhanced spectroscopies.

chapter Chapter 1|13 pages

Nanometals: Formation and Color*

ByLuis M. Liz-Marzán

chapter Chapter 2|74 pages

Gold Nanorods: Synthesis, Characterization and Applications*

ByJorge Pérez-Juste, Isabel Pastoriza-Santos, Luis M. Liz-Marzán, Paul Mulvaney

chapter Chapter 3|41 pages

The Assembly of Coated Nanocrystals*

ByLuis M. Liz-Marzán, Paul Mulvaney

chapter Chapter 4|28 pages

Tailoring Surface Plasmons through the Morphology and Assembly of Metal Nanoparticles*

ByLuis M. Liz-Marzán

chapter Chapter 5|37 pages

Colloidal Silver Nanoplates: State of the Art and Future Challenges*

ByIsabel Pastoriza-Santos, Luis M. Liz-Marzán

chapter Chapter 6|24 pages

Shape Control in Gold Nanoparticle Synthesis*

ByMarek Grzelczak, Jorge Pérez-Juste, Paul Mulvaney, Luis M. Liz-Marzán

chapter Chapter 7|26 pages

N,N-Dimethylformamide as a Reaction Medium for Metal Nanoparticle Synthesis*

ByIsabel Pastoriza-Santos, Luis M. Liz-Marzán

chapter Chapter 8|37 pages

Recent Progress on Silica Coating of Nanoparticles and Related Nanomaterials*

ByAndres Guerrero-Martínez, Jorge Pérez-Juste, Luis M. Liz-Marzán

chapter Chapter 9|36 pages

Nanostars Shine Bright for You: Colloidal Synthesis, Properties and Applications of Branched Metallic Nanoparticles*

ByAndres Guerrero-Martínez, Silvia Barbosa, Isabel Pastoriza-Santos, Luis M. Liz-Marzán

chapter Chapter 10|33 pages

Controlled Assembly of Plasmonic Colloidal Nanoparticle Clusters*

ByJose M. Romo-Herrera, Ramón A. Alvarez-Puebla, Luis M. Liz-Marzán

chapter Chapter 11|43 pages

From Individual to Collective Chirality in Metal Nanoparticles*

ByAndrés Guerrero-Martinez, José Lorenzo Alonso-Gómez, Baptiste Auguie, M. Magdalena Cid, Luis M. Liz-Marzán

chapter Chapter 12|38 pages

Metallic Janus and Patchy Particles*

ByDenis Rodríguez-Fernández, Luis M. Liz-Marzán

chapter Chapter 13|15 pages

Multifunctionality in Metal@Microgel Colloidal Nanocomposites*

ByJorge Pérez-Juste, Isabel Pastoriza-Santos, Luis M. Liz-Marzán

chapter Chapter 14|35 pages

Oleylamine in Nanoparticle Synthesis*

ByStefanos Mourdikoudis, Luis M. Liz-Marzán

chapter Chapter 15|26 pages

Anisotropic Noble Metal Nanocrystal Growth: The Role of Halides*

BySamuel E. Lohse, Nathan D. Burrows, Leonardo Scarabelli, Luis M. Liz-Marzán, Catherine J. Murphy

chapter Chapter 16|21 pages

The Relevance of Light in the Formation of Colloidal Metal Nanoparticles*

ByMarek Grzelczak, Luis M. Liz-Marzán

chapter Chapter 17|25 pages

Metal Nanoparticles and Supramolecular Macrocycles: A Tale of Synergy*

ByVerónica Montes-García, Jorge Pérez-Juste, Isabel Pastoriza-Santos, Luis M. Liz-Marzán

chapter Chapter 18|60 pages

Recent Approaches toward Creation of Hot Spots for SERS Detection*

ByAmane Shiohara, Yusong Wang, Luis M. Liz-Marzán

chapter Chapter 20|19 pages

Hierarchical Assembly of Plasmonic Nanoparticles*

ByCyrille Hamon, Luis M. Liz-Marzánac

chapter Chapter 21|27 pages

A “Tips and Tricks” Practical Guide to the Synthesis of Gold Nanorods*

ByLeonardo Scarabelli, Ana Sánchez-Iglesias, Jorge Pérez-Juste, Luis M. Liz-Marzánad

chapter Chapter 22|30 pages

Design and Fabrication of Plasmonic Nanomaterials Based on Gold Nanorod Supercrystals*

ByLeonardo Scarabelli, Cyrille Hamon, Luis M. Liz-Marzán

chapter Chapter 23|5 pages

Growing Anisotropic Crystals at the Nanoscale*

ByLuis M. Liz-Marzán, Marek Grzelczak

chapter Chapter 24|42 pages

Anisotropic Metal Nanoparticles for Surface-Enhanced Raman Scattering*

ByJavier Reguera, Judith Langer, Dorleta Jimenez de Aberasturi, Luis M. Liz-Marzán

chapter Chapter 25|66 pages

Silica-Coated Plasmonic Metal Nanoparticles in Action*

ByChristoph Hanske, Marta N. Sanz-Ortiz, Luis M. Liz-Marzán

chapter Chapter 26|24 pages

Composite Polymer Colloids for SERS-Based Applications*

ByMalte S. Strozyk, Dorleta Jimenez de Aberasturi, Luis M. Liz-Marzán

chapter Chapter 27|21 pages

Recent Advances in Chiral Plasmonics: Towards Biomedical Applications*

ByJatish Kumar, Luis M. Liz-Marzán