ABSTRACT
Reactive oligomers (ROs) constitute a starting material for the production of numerous polymeric materials with a pre-assigned set of physico-mechanical and physico-chemical properties. This book is the first to treat systematically various methods for determining the FTD and MWD of functional oligomers. Special attention is given to the application of liquid chromatography in different separation modes: exclusion (gel-permeation chromatography, GPC) and adsorption, as well as to the separation of functional oligomers in the critical region (SCR) at the boundary between the specified modes.
TABLE OF CONTENTS
part I|66 pages
Synthesis and Determination of the Average Functionality of Reactive Oligomers
chapter Chapter 2|41 pages
Synthesis of Reactive Oligomers and the Formation of Functionally-Defective Macromolecules
part II|113 pages
FTD Determination by Liquid Chromatography Methods
chapter Chapter 4|36 pages
Basic Experimental Regularities of Liquid Chromatography of Oligomers with RFGs
chapter Chapter 5|29 pages
General Regularities of the Chromatography of Macromolecules under Critical and Near Critical Conditions
part III|73 pages
Molecular Weight Distribution of Oligomers and the Characteristic Features of Its Study with the Help of Gel Permeation Chromatography
chapter Chapter 9|42 pages
Characteristic Features of Gel Permeation Chromatography of Oligomers with RFGs
part IV|54 pages
Molecular Heterogeneity of Reactive Oligomers and of the Polymers Based on Them