ABSTRACT

Chemical Fixation of Carbon Dioxide presents new concepts and results from research into the problems caused by increasing levels of carbon dioxide. The book discusses the limitations of natural plant photosynthesis as a sink for carbon dioxide and emphasizes chemical fixation as an important alternative. A number of significant topics are covered, including new coupling reactions for producing compounds such as carbamates, urethanes, and heterocyclic structures; new catalyst systems, particularly for methanation and methanol synthesis; the use of homogeneous solution photosensitizers and heterogeneous semiconductor photocatalysts to photoreduce carbon dioxide with visible light and sunlight; and electrochemical reduction.
This book will be a useful reference for organic chemists working on environmental problems, chemical engineers, environmental chemists, professionals at research facilities, and students.

chapter 2|6 pages

Thermodynamics and Thermal Dissociation

chapter 3|4 pages

Dynamics of Carbon Dioxide Reduction

chapter 4|18 pages

Coupling Reactions of Carbon Dioxide

chapter 5|24 pages

Thermal Heterogeneous Reduction

chapter 6|10 pages

Photochemical Reduction

chapter 7|54 pages

Electrochemical Reduction

chapter 8|10 pages

Photoelectrochemical Reduction

chapter 9|12 pages

Heterogeneous Photo-Assisted Reduction

chapter 10|12 pages

Bioconversion