ABSTRACT

Thermites, which are generally considered to be reactive mixtures of powdered metals and metal oxides, are an important subset of energetic materials. The underlying thermodynamic properties of a given mixture dictate whether it may undergo a self-sustaining reaction, liberating heat in the process. Thermodynamic information in the existing scientific literature regarding thermitic combinations is scattered and incomplete. Currently, a comprehensive overview of this nature would be of great use to those working in the areas of pyrotechnics, pyrometallurgy, high-temperature chemistry, and materials science. Thermitic Thermodynamics solves this problem by describing the results of calculations on over 800 combinations of metal, metalloid, and metal oxide reactants.

Other features include:

  • A first-of-its-kind adiabatic survey of binary thermitic reactions
  • Provides an overview of key trends in exothermic metal-metal oxide reactivity
  • Describes the role of non-oxide product formation in thermitic systems
  • Explains how to interpret the results of thermochemical calculations effectively

An invaluable resource, this book provides an accessible introduction for students and is also an enduring guide for professionals.

 

 

part 1|238 pages

Thermitic Thermodynamics

chapter 1|28 pages

An Introduction to Thermitic Reactivity

chapter 4|44 pages

Applying Thermodynamic Concepts

chapter 5|68 pages

Additional Topics

part 2|726 pages

Adiabatic Descriptions of Binary Thermitic Systems

chapter 6|61 pages

Magnesium–Oxidizer Systems

chapter 7|60 pages

Titanium–Oxidizer Systems

chapter 8|40 pages

Zirconium–Oxidizer Systems

chapter 9|39 pages

Hafnium–Oxidizer Systems

chapter 10|41 pages

Vanadium–Oxidizer Systems

chapter 11|41 pages

Niobium–Oxidizer Systems

chapter 12|34 pages

Tantalum–Oxidizer Systems

chapter 13|32 pages

Chromium–Oxidizer Systems

chapter 14|23 pages

Molybdenum–Oxidizer Systems

chapter 15|23 pages

Tungsten–Oxidizer Systems

chapter 16|34 pages

Manganese–Oxidizer Systems

chapter 17|15 pages

Iron–Oxidizer Systems

chapter 18|9 pages

Cobalt–Oxidizer Systems

chapter 19|9 pages

Nickel–Oxidizer Systems

chapter 20|5 pages

Copper–Oxidizer Systems

chapter 21|30 pages

Zinc–Oxidizer Systems

chapter 22|13 pages

Cadmium–Oxidizer Systems

chapter 23|42 pages

Boron–Oxidizer Systems

chapter 24|58 pages

Aluminum–Oxidizer Systems

chapter 25|56 pages

Silicon–Oxidizer Systems

chapter 26|21 pages

Tin–Oxidizer Systems

chapter 27|9 pages

Lead–Oxidizer Systems

chapter 28|9 pages

Antimony–Oxidizer Systems

chapter 29|6 pages

Bismuth–Oxidizer Systems

part 3|96 pages

Additional Adiabatic Descriptions

chapter 31|21 pages

Systems Involving Actinide Elements

chapter 32|18 pages

Metal–Boron Systems and Ti–B4C, Ti–C

chapter 33|15 pages

Metal–Silicon Systems

chapter 34|16 pages

Intermetallic Systems