ABSTRACT
Amphiphilic colloidal particles with hydrophobic cores and hydrophilic shells were prepared via a two-step method. First, polystyrene cores were obtained through the concentrated emulsion polymerization. A mixture of styrene, ethyl benzene, divinyl benzene, azobisisobutyronitrile, and cumene hydroperoxide (CHPO) was partially polymerized at 80°C for 40 min and subsequently used as the dispersed phase of a concentrated emulsion in water. The concentrated emulsion was subjected to complete polymerization at 60°C for 12 h; colloidal particles of crosslinked polystyrene were thus obtained. In the second step, the polystyrene particles were dispersed in water, after which acrylamide, N,N′-methylenebisacrylamide, and ferrous sulfate (FS) were added. The system was heated (typically at 30°C) to conduct the polymerization of the hydrophilic monomers. The CHPO present on the surface of the polystyrene particles and the FS present in the aqueous phase (both together constitute a redox initiator) ensured that the initiation occurred mostly on the surface of the particles and that the hydrophilic polymer obtained formed a shell encapsulating the particles. Under proper conditions, a porous outer shell could be generated, making the hydrophobic core accessible to the outside medium.
