ABSTRACT

Physicochemical properties investigate structural interactions of salts and surfactants separately in common solvents like water. An integrated fluid dynamics being applied by using survismeter not only distinguishes the interaction mechanism of molecules but also determines their specific effect on solvents structure. Surfactants on dissolving in the dispersing medium get quickly dispersed. The dispersing activity is noted as the degree of dispersing or dissociating degree. Dispersing continues up to a certain limit of surfactant composition, but it gets saturated after a certain composition. A longer alkyl chain occupies larger amounts of the structured water, and no more unoccupied structured water is left to support further dissociation of surfactants. The longer the alkyl chain, the lower is the critical micellar concentration value and the higher are the specific conductance and the friccohesity. The electron releasing or withdrawing groups could play a contributory role for developing the concept of friccohesity.