ABSTRACT

Electrochemical sensors, and other modern devices of electroanalytical chemistry, generate experimental data which should be subject to rapid, real-time, on-line analysis. Digital simulations, commonly used for obtaining theoretical transient responses (such as cyclic voltammograms) of electrochemical systems, are often computationally too expensive to be used in such cases. The large simulation costs also hamper the application of advanced but computationally expensive methods of data analysis. In order to overcome these difficulties, the solution mapping method based on the High-Dimensional Model Representation (HDMR) technique can be applied. Principles of the method will be outlined and illustrative maps for selected electrochemical kinetic models will be demonstrated.