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Possible Mechanism of Redox Synthesis of Metal/Carbon Nanocomposites Modified by P, D Elements
DOI link for Possible Mechanism of Redox Synthesis of Metal/Carbon Nanocomposites Modified by P, D Elements
Possible Mechanism of Redox Synthesis of Metal/Carbon Nanocomposites Modified by P, D Elements book
Possible Mechanism of Redox Synthesis of Metal/Carbon Nanocomposites Modified by P, D Elements
DOI link for Possible Mechanism of Redox Synthesis of Metal/Carbon Nanocomposites Modified by P, D Elements
Possible Mechanism of Redox Synthesis of Metal/Carbon Nanocomposites Modified by P, D Elements book
ABSTRACT
The redox synthesis results of modified metal/carbon nanocomposites in which metal may be Copper or Nickel, and the applied modifiers—ammonium polyphosphate, silicon, sodium thiosulfate, metal oxides (Metal: Al, Fe(3), Cu(2) and Ni) were analyzed at the relation changes of modifier and nanocomposite. The hypothesis of redox synthesis with the use of chemical mesoscopic idea about the charge quantilization is proposed. The hypothesis is that the negative charge quants move to reducing element nucleolus to provoke the positive charge quants and the creation of annihilation phenomenon. Therefore, the direct electromagnetic field formed promotes to d electrons shift on higher energetic levels including the carbon shell 44of nanocomposite nanogranyl. The picture of this phenomenon may be presented:
At the joint grinding of modifier with metal/carbon nanocomposites nanogranul the nanoreactor (multiplet) is formed on the boundaries of which the chemical potentials difference creates.
Because of the potentials difference, the delocalized electrons, which are disposed on the nanogranul shell, move to positively charged atoms of modifier and stimulate the positive charges quantiliization.
The annihilation phenomenon arises at the superposition of quants of negative and positive charges on the boundary of reagents. In this case, the electron magnetic field which activates the delocalization of d electrons of nanogranul metals and the electron shift to nanogranul carbon shell.
The electron shift process within nanogranul is facilitated by modified agent polarization growth.
The hypothesis explains the growth of metal atomic magnetic moments which may be bigger than 4.5 μB because of the process of delocalization d electrons. The shift of electrons on nanogranul carbon shells leads to the restoration of the electron balance after redox synthesis. There is a correlation between electron number participated in redox synthesis and the value of atomic magnetic moment as well as between the polarization degree of reactive systems and the increasing of atomic magnetic moments of nanogranul metals.