ABSTRACT

Owing to their ruggedness, the most widely used reference

electrodes are the Ag/AgCl and saturated calomel electrode (SCE).

The electrochemical cell is connected to a potentiostat,

which controls the potential applied at the working elec-

trode. A generic illustration of a potentiostat is given in

Fig. 2. It consists of a waveform generator (waveforms

will be discussed later), a potentiostatic control circuit, a

current-to-voltage (i-to-E) converter, and an output

device. Modern instrumentation can be complicated and

the electronics needed for voltammetric measurements

may differ depending on the application. Here, Fig. 2 is

shown only to illustrate the basic requirements for voltam-

metric measurements.