ABSTRACT

A morphological instability characterized by the separation of grain pairs and the disappearance of grain boundaries is a common feature in polycrystalline bodies that are constrained from shrinking during mass transport. This instability, know as de-sintering, occurs during grain coarsening as sequentially observed for thin films with columnar microstructures constrained by a substrate, fibers with a 'bamboo' microstructure constrained by a matrix, and powder matrices within composites. De-sintering is a common phenomena in partially dense, polycrystalline bodies; it occurs concurrently with densification phenomena and is emphasized in composites where the partially dense matrix is constrained from shrinking by a reinforcement network. De-sintering occurs in any lower density region were shrinkage is constrained by the average shrinkage of the body.