Hydrogenolysis of 2, 4, 6, 8, 10, 12-hexabenzyl-2, 4, 6, 8, 10, 12-hexaazaisowurtzitane (HBIW) with PdX (X=Fe, Ni, Co, Ag, Pt)/mpg-C3N4 catalysts

doi:10.1201/9781003308553-29

Chapter

Hydrogenolysis of 2, 4, 6, 8, 10, 12-hexabenzyl-2, 4, 6, 8, 10, 12-hexaazaisowurtzitane (HBIW) with PdX (X=Fe, Ni, Co, Ag, Pt)/mpg-C3N4 catalysts

ABSTRACT

Palladium-based bimetallic catalysts were synthesized and characterized. These catalysts were applied to 2, 4, 6, 8, 10, 12-hexabenzyl-2, 4, 6, 8, 10, 12-hexaazaisowurtzitane (HBIW) hydrogenolysis. PdNi/mpg-C₃N₄ catalysts had a better 78% yield of 2, 6, 8, 12-tetra acetyl-4,10-dibenzyl-2, 4, 6, 8, 10, 12-hexaazaisowurtzitane (TADBIW) than the 53% yield with PdFe/mpg-C₃N₄ catalysts. The introduction of Co, Ag, and Pt to the metal Pd could completely inhibit the activity of hydrogenolysis of HBIW.