ABSTRACT

Photoinduced energy and charge transfer events in biological

and material functional systems are often ultrafast and involve

delocalized excitations-that is, molecular excitons-and strong

electron-vibration (vibronic) coupling effects which necessitate a

nonperturbative treatment. The ultrafast nature of these processes

is a result of nonadiabatic interactions by which electronically

excited states undergo nonradiative transfer and decay processes.

Examples include biological systems like chromophore-protein

complexes, natural and artificial light-harvesting systems, organic

materials like semiconducting polymers, and various other mole-

cular assemblies. A number of studies involving these and related

systems are presented in this volume.