ABSTRACT

In this chapter, we explain the theory used to treat electronic

excitations in multichromophoric systems like biological light-

harvesting complexes and DNA as well as vibrations in peptides.

Although these systems appear very different, they can be treated on

a common theoretical footing. Twomain issues will appear through-

out this chapter. First, the systems under study are composed

of multiple chromophores interacting with light. These building

blocks are, however, not independent, but coupling between them

leads to collective behavior observable in the optical response. The

second important ingredient of the theory is interaction of the

chromophores with a complex environment, which tends to destroy

the cooperativity.