ABSTRACT

In this section, we describe the basic physical properties of natural

DNA: (1) UV/Vis absorption spectra and (2) magnetic properties.

Absorption spectra provide basic information about the electronic

states of DNA: Is there energy gap? If yes, then how much is

the energy gap and how large are the interactions between the

π electrons of bases of intra-and inter-strand? If the DNA is

semiconducting with the energy gap, magnetism based on the π

electrons will not be expected. On the other hand, it has been

reported that natural DNA is expected to show sizable electrical

conductance on the basis of orbital paramagnetism [32, 34]. A lot

of magnetic properties have been reported so far, and the origin and

mechanism of the observed magnetism have been discussed. With

these viewpoints, it is valuable to reexamine precisely the physical

properties of natural DNA.