Free-radical frontal Polymerization of acrylamide In the presence of nano and Micro additives

The effect of different nanoparticles (bentonite, SiO₂) and finely disperse fillers (chalk, diatomite) on peculiarities of acrylamide frontal free-radical polymerization initiated by azo-iso-butyronitrile and benzoyl peroxide was studied. It was determined that the increase in an order with respect to initiator is conditioned by influence of nano and micro additives not only on the mechanism of initiator decomposition but also on the reaction of chains bimolecular termination.