ABSTRACT
LlG0 ' = nF(E - E0 - <I\) (104) The forward activation free energy is determined along the same lines as presented
for homogeneous electron transfer since both problems are strictly equivalent [43,44,78,79]. Thus, .1Gfct is given as a function of the local driving force [LlG00 in Eq. (104)] and of the associated reorganization energy). el by the expression in Eq. (105), which derives from Eq. (64).
