ABSTRACT

The pure SMPs usually exhibit lower modulus and recovery forces than the shape-memory alloys or shape-memory ceramics, and therefore the unreinforced SMPs are not suitable for many applications that require special performances (e.g., high strength and high recovery force) [1,2]. In order to improve their mechanical properties, the incorporation of various reinforcing llers within SMPs has been investigated. SMPs reinforced by particles

CONTENTS

7.1 Introduction ................................................................................................ 203 7.2 Constitutive Relationship of Shape-Memory Polymers ....................... 204 7.3 Shape-Memory Polymer Composites ...................................................... 213

7.3.1 Shape-Memory Polymer Filled with Carbon Nanotubes ........ 213 7.3.1.1 Static Tensile Property .................................................... 213 7.3.1.2 Shape Recovery Force Measurement ........................... 215

7.3.2 Shape-Memory Polymer Filled with Carbon Nano bers ........ 216 7.3.3 Shape-Memory Polymer Filled with SiC Nanoparticles .......... 218

7.3.3.1 Thermal Transition and Stress-Strain Behavior ........ 219 7.3.3.2 Recoverable Mechanical Property ................................ 220

7.3.4 Shape-Memory Polymer Reinforced by Continuous Fibers .... 221 7.3.4.1 Dynamic Mechanical Analysis .....................................222 7.3.4.2 Shape Recovery Performance ........................................223 7.3.4.3 Deformation Mechanism of Microstructure ...............227