ABSTRACT

The susceptibilities of various orders xin) have to fulfill the Neumann principle [5] stating that any material property must be invariant with respect to symmetry operations constituting the point group which describes the medium symmetry. This principle has far-reaching implications for the susceptibilities. A well-known im­ plication is that all tensor components of even-order susceptibilities (including ^ (2)) have to vanish for media belonging to centrosymmetric point groups. In gen­ eral, the number of independent tensor components is strongly reduced by the presence of symmetry operations, some of the components being equal to zero.