ABSTRACT

Mineral Montmorillonite is the most common mineral of the montmorillonite group. The structural arrangement of this mineral is composed of two silica tetrahedral sheets with a central alumina octahedral sheet. All the tips of the tetrahedra point in the same direction and toward the center of the unit. The silica and gibbsite sheets are combined in such a way that the tips of the tetrahedrons of each silica sheet and one of the hydroxyl layers of the octahedral sheet form a common layer. The atoms common to both the silica and gibbsite layer become oxygen instead of hydroxyIs. The thickness of the silica-gibbsite-silica unit is about 10 A(Fig. 2.5). In stacking these combined units one above the other, oxygen layers of each unit are adjacent to oxygen of the neighboring units with a consequence that there is a very weak bond and an excellent cleavage between them. Water can enter between the sheets, causing them to expand significantly and thus the structure can break into loA thick structural units. Soils containing a considerable amount of montmorillonite minerals will exhibit high swelling and shrinkage characteristics. The lateral dimensions of montmorillonite particles range from 1000 to 5000 A with thickness varying from 10 to 50 A. Bentonite clay belongs to the montmorillonite group. In montmorillonite, there is isomorphous substitution of magnesium and iron for aluminum.