ABSTRACT

Normally, self-organized surface nanopatterns produced by ion

beam sputtering (IBS) result in nanodot or nanoripplemorphologies

depending on geometrical considerations. However, recent studies

show that additional contributions should be considered when

multielemental targets are involved due to the eventual develop-

ment of a modulation between the surface composition and its

morphology. This fact can be extended to targets irradiated with the

presence of intentional or accidental impurities (mainly metals) on

the surface that, for example, may be responsible for triggering the

pattern formation at (near) normal ion incidence onmonoelemental

semiconductors such as silicon. In this chapter, we deepen in the

role of simultaneous metal incorporation in pattern formation on

Si(100) surfaces by normal-incidence IBS with 1 keV Ar+. We show that the level of metal incorporation can additionally be used to

tune the pattern morphology and, in particular, selectively produce

unconventional nanohole patterns formetal levels higher than those

present in the standard nanodot pattern counterpart. We examine

the parameter window for the production of different morphologies

to verify the morphological and compositional correlation. Finally,

we highlight relevant mechanisms that could drive to such pattern

selectivity.