Nanomaterials have got the spanking attentions after the remarkable speech of the physicist Richard Feynman at 1959, which is entitled as “There’s plenty of room at the bottoms”. The nanomaterials have got further increased attentions greater than ever, after they have been realized that the morphology of them also desires the noteworthy properties along with particle size. Every one of the nanostructures is unique in their properties. This makes more attention on the structures of nanomaterials, starting from the synthesis phase to precise study on its various characteristics. Series of studies made on various nanostructures revealed them for variety of noteworthy applications. Diverse of morphological sceneries can be obtained from various synthesizing procedures and is also possible even by varying the parameters in a single method [1-4]. Assorted numbers of nanostructures have been revolutionized in the industries, such as solar cell applications, energy storage, nanoelectronics, printing technology, and so on, based on their respective properties [5-8]. Attracting and distinguished properties of nanostructured materials make the researchers and industrialists to concentrate more on procedures toward producing more quality in nanostructures. Self-assembling process has been recognized as an authentic and guaranteed technique to attain outstanding qualities in both organic and inorganic nanostructures. Self-assembling of materials can result in any dimensionalities (0D, 1D, 2D, and 3D) [9-11]. In this perspective, we will discuss about the various parameters involved in the self-assembling process, various types of conjugations for self-assembling, structuring possibilities of both inorganic and organic materials, applications of self-assembled nanostructures and few others too.