ABSTRACT
S. RAKOVSKY, M. ANACHKOV, V. GEORGIEV, M. BELITSKI, and G. ZAIKOV
12.1 Introduction .................................................................................. 377 12.2 Reaction Mechanisms .................................................................. 377 1.2.1 Thermochemical Analysis ................................................ 379 12.3 Structural-Kinetic Investigations ................................................. 380 12.3.1 Linear and Isoparaffins .................................................. 380 12.3.2 Cycloparaffines .............................................................. 389 12.3.3 Method for Estimation of Reaction Mechanisms
(ERM) .......................................................................................... 396 12.3.4 Application of ERM ....................................................... 400 12.4 Cyclohexane ................................................................................. 407 12.5 Cumene ........................................................................................ 419 12.5.1 Ozonolysis in the Presence of Transition Metal
Compounds .................................................................................. 423 12.5.2 Ozonolysis in the Presence of NIO ................................ 428 12.5.3 Ozonolysis in the Presence of MO and V Oxides .......... 431 12.5.4 Cumenehydroperoxide ................................................... 435
12.6 Polyethylene and Polypropylene ................................................. 440 12.7 Polystyrene ................................................................................... 447 Keywords .............................................................................................. 456 References ............................................................................................. 456
12.1 INTRODUCTION
The ozonolysis of hydrocarbons is the rare reactions that going on at low and ambient temperatures and can transform these non-active organics into new valuable oxygen-containing products [1-12] suitable for synthesis and for special usage.
