ABSTRACT

Self-assembly of plasmonic nanoparticles is a fast, robust, and

cheap route to obtain large-scale materials with promising optical

properties. Although the materials obtained in this way are usually

amorphous, the approach has the advantage that three-dimensional

assemblies of small particles can be obtainedwith control of average

distances at the nanoscale. In this chapter, we will focus on one

particular strategy to assemble plasmonic particles that relies on the

interplay between charged particles, surfaces, and polyelectrolytes.

Several geometrieswill be discussedwith an emphasis on the optical

properties that are dictated by the coupling between plasmons in

different geometries.