ABSTRACT

Molecules existing in two or more states are particularly attractive

as molecular switches for molecular electronics applications. A

stimulusmay change suchmolecules between different redox states,

between translational isomers, between cis and trans isomers, between isomers of electrocyclic reactions, or between different

tautomers. This chapter describes how a variety of redox-and

photoactivemolecules can be used for conductance switching. It also

describes synthetic protocols for some of the switches.