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      Chapter

      Polarized Surface-Enhanced Raman Scattering
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      Chapter

      Polarized Surface-Enhanced Raman Scattering

      DOI link for Polarized Surface-Enhanced Raman Scattering

      Polarized Surface-Enhanced Raman Scattering book

      Polarized Surface-Enhanced Raman Scattering

      DOI link for Polarized Surface-Enhanced Raman Scattering

      Polarized Surface-Enhanced Raman Scattering book

      ByBarbara Fazio, Antonino Foti, Cristiano D’Andrea, Elena Messina, Alessia Irrera, Onofrio Maria Marago`, and Pietro Giuseppe Gucciardi
      BookHandbook of Enhanced Spectroscopy

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      Edition 1st Edition
      First Published 2015
      Imprint Jenny Stanford Publishing
      Pages 40
      eBook ISBN 9780429083150
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      ABSTRACT

      When molecules are near-field coupled with optical nanoantennas,

      their scattering properties are strongly affected by the radiation

      properties of the nanoantenna itself. In surface-enhanced Raman

      spectroscopy (SERS) the scattering cross section is greatly en-

      hanced. As well, the field orientation and polarization are modified

      by the nanoantenna radiation modes. This chapter discusses how

      the polarization of the Raman field, inelastically scattered by

      molecules in SERS, is modified by the interaction with optical

      nanoantennas in a model beyond the E 4 approximation. The polarized SERS intensity is discussed for different nanoantenna

      geometries and insight on how to recover information on the Raman

      polarizability tensor based on the SERS measurements is given.

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