ABSTRACT

Within the academic and industrial communities the selective oxi-

dation of oxygen-containing organic compounds, such as alcohols,

polyols, and aldehydes, primarily for the production of fine and

specialty chemicals, remains a high priority. The main issue with

the current industrial methods for these synthetic processes is

the utilization of stoichiometric inorganic reagents. Due to the

toxicity, waste, and corrosion problems associated with these

inorganic reagents, these approaches are no longer acceptable

from an environmental point of view. Preventing the use of

toxic materials and substituting these routes with environmentally

friendly processes, thus minimizing the formation of waste, remains

one of the key objectives of modern-day research. The utilization

of homogeneous and heterogeneous catalysts as alternatives to

achieving these objectives is highly desirable. On an industrial level,

it is preferable to develop heterogeneous catalysts that can be more

easily recovered and recycled on a process level with a prolonged

lifetime. Furthermore the use of green oxidants such as molecular

oxygen or peroxides (organic and inorganic) is highly desirable

since in this way the reduction of chemical waste associated with

inorganic oxidants, such as K2Cr2O7, can be achieved [1-4].