ABSTRACT

We know that even a single electron in a hydrogen atom generally has orbital angular momentum L (with (2l + 1) possible orientations where l is a integer) and spin angular momentum S (with two possible orientations commonly described as spin up and spin down or s = ± 1/2). In more complicated atoms there may be many components of angular momentum; for example, the helium atom has two electrons both of which have orbital and spin angular momenta. Also, in many atomic systems of physical interest we need to know how to combine angular momenta. This chapter explains how to do it.