ABSTRACT

Hydrocarbons comprise a broad group of organic compounds that contain only hydrogen and carbon. They may be divided into two large categories: aliphatic (straight chain) or aromatic (benzene ring) compounds. Another group, which is of great toxicologic significance, consists of halogenated aliphatic and arpmatic hydrocarbons. Some of these are discussed in this chapter; others, such as organochlorine insecticides, are described in other chapters. Hydrocarbons commonly encountered in acute poisonings consist of a mixture of saturated and unsaturated, aliphatic, ali-cyclic, or aromatic compounds and are usually distillates of crude oil, coal tar, and pine wood. Examples of each of these groups are presented in Table 7.1. Hydrocarbon classification

Aliphatic

Gases — methane, propane, butane

Liquids — hexane, octane, etc.

Waxes — paraffins

Aromatfcs

Benzene, toluene, xylene, styrene, vinyl chloride

Halogenated

Aliphatic — chloroform, carbon tetrachloride methylene chloride

Aromatic — DOT, a chlordane, lindane, p-dichtorobenzene, polychlorinated biphenyls

Petroleum distillates

Petroleum ether (benzine), gasoline, naphtha kerosene, fuel oil, lubricating oil, paraffin, asphalt

Distillates of pine wood

Turpentine

Distillates of coal tar

Benzene, cumene, toluene, xylene

DDT, dichlorodlphenyltrichloroethane.