ABSTRACT

The transfer of a particular chemical species from one phase

to another and themovement of such species along gradients

within phases are fundamentally important processes in any

system involving more than one chemical component.

Forces that can promote such transfer include: free energy,

pressure, electrical charge, temperature, and concentration.

These driving forces are physical quantities of importance

not only in biological systems but also in other systems

encountered in engineering practice.[1] The transport of

chemical species as a result of such driving forces is com-

monly called mass transfer. Mass transfer subdivides into

molecular mass transfer and convective mass transfer. The

term diffusion is often used for the former. Diffusion deals

with random molecular migration of matter through a med-

ium, whereas convective mass transfer involves the migra-

tion of matter into a moving fluid or a stream of gas. For

example, if an open container of acetic acid is placed in one

corner of a room, the odor will soon be detected throughout

the entire room. In this case, there is a combination of

molecular diffusion and convection. If a lump of sugar is

placed in a glass of water, the sugar will eventually dissolve

and spread in all parts of the volume without stirring. In this

case convection will play aminor role. In solids, there can be

no convection and all movements are by molecular diffu-

sion. The general equation for all types of mass transfer is