ABSTRACT

Water consists of molecules that are composed of

hydrogen and oxygen atoms. The molecules are in

constant motion, and there are attractive forces

between them. If a quantity of liquid water in a closed

container has a free surface that is in contact with air

say, some of the molecules have so much kinetic

energy that they can escape the attractive pull of

other water molecules. As a result, they escape into

the vapor region in which the intermolecular attractive

forces are negligibly small. A dynamic equilibrium is

established between the liquid water and its vapor

when the number of molecules leaving the liquid in a

given time equals the number that enters the liquid. At

this point of equilibrium, the pressure that the water

molecules exert on the walls of the container and the

liquid water is known as the saturation vapor pressure.

In the case of a plane or flat surface of water, this

pressure is a function only of temperature. One of the

most accurate expressions that relate the saturation

vapor pressure, ps (Pa), and temperature, T ( C), is

the Goff-Gratch[1] equation, namely