ABSTRACT

TiO2 is a new and preferred material for numerous environment friendly applications, and it has attracted much attention because of its multiple advantages, which include long-term photostability, nontoxicity, low cost, photochemical stability, and strong oxidizing power. The implantation of TiO2 nanostructures with different dopants affects the phase crystallization temperature. The implantation of V and Al ions reduces the crystallization temperature because smaller ions substituted for Ti in the TiO2 crystal structure by the dopant. Calcination time and temperature, atmosphere, pressure, and doping are critical parameters that control the crystallization kinetics of nanostructured TiO2. The anatase-to-rutile transformation is inhibited by interstitial titanium formation, which limits TiO2 structure relaxation.