ABSTRACT
Due to the presence of its unique puckered two-dimensional (2D) structure, wide surface area, high carrier mobility, and strong mechanical strength, black phosphorus (BP) has sparked a lot of research interest, particularly in energy storage and conversion applications. Building a three-dimensional (3D) structure with BP nanosheets as the building blocks may be a good way to take advantage of their amazing properties. The design of 3D BP, on the other hand, is extremely difficult due to its sensitivity to water, air, and oxidants. The fabrication of BP-based 3D structures and their morphological engineering using various deposition techniques are discussed in this chapter. A comparison of BP with other 3D layered material structures is also coordinated, establishing BP as a specific candidate for potential and biomedical applications.
