ABSTRACT

This chapter presents a brief introduction to the path-integral method before applying it to the polaron problem. The coupling theory is based on the path-integral formulation of quantum mechanics developed by Feynman in 1955. The path-integral formalism proves to be a useful tool for many field-theoretic problems. Feynman's path-integral method as applied by Feynman to determine the polaron effective mass has an intuitive rather than formal basis. The comparison revealed unequivocally the superiority of the Feynman model over the entire range of the coupling constant. Schultz also simulated the Feynman approximation by replacing the whole lattice with a second, fictitious particle harmonically bound to the electron by a spring of constant k. Thus, the Feynman's strong-coupling energy is better than the Landau-Pekar energy with the Gaussian trial function. The numerical results reported by Marshall and Mills show that the second-order correction to the Feynman result for the ground state energy is less than 2% for the entire coupling rang.