ABSTRACT

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83NAME:

Common Trade and Other Chemical CAS Number

Class of Chemical

Chief Pesticide Use; Status

Persistence

Effects on Mammals

Adverse effects on other non-target species

Physical properties

Immediate Toxicity (Acute)

Long-Term Toxicity (Chronic)

abamectin

Affirm; Agrimek; Avermectin B1; Avid; Avomec; MK-936; Vertimec

(10E,14E,16E, 22Z)-(1R,4S,5′S,6S,6′R, 8R,12S,13S,2 0R,21 R,24S)-6′[(S)-sec-butyl]-21,24-dihydroxy-5′, 11,13,22-tetramethyl-2-oxo-3,7,19-trioxatetracyclo [15.6.1.14,8.020,24]pentacosa-10.14.16.22-tetraene-6-spiro-2′-(5′,6′-dihydro-2′H-pyran)-12-yl 2.6-di di oxy-4-O-(2,6-di dioxy-3-O-methyl-α-l-arabino-hexapyranosyl)-3-O-methyl-α-l-arabino-hexapyranoside (i) mixture with (10E,14E,16E,22Z)-(1R,4S,5′S,6S,6′R,1R,12S,13S,20R,21R,24S)-21,22-dihydroxy-6′-isopropyl-5′, 11,13,22-tetramethyl-2-oxo-3,7,19-trioxatetracycl o[15.6.1.14,8.020,24] pentacosa-10,14,16,22-tetraene-6-spiro-2′-(5′,6′-dihydro-2′H-pyrano)-12-yl 2,6-dideoxy-4-O-(2,6-dideoxy-3-O-methyl-α-l-arabino-hexopyranoxyl)-3-O-methyl-α-l-arabino-hexapyranoside (ii) (4:1)

CAS # 71751-41-2

biological

insecticide acaricide

mod-pers (1)

oral: very high (2)

dermal: low to medium (3)

inhalation: ?

?

immediate toxicity:

 birds: low to medium (3)

 fish: very high (3)

 aquatic insects: very high (3)

water: slightly soluble

oil: insoluble

non-volatile

acephate

Orthene; Ortho 12420; Ortran

O,S-dimethyl acetylphosphoramidothioate; O,S-dimethyl acetic phosphoramidothioate

CAS # 30560-19-1

organophosphate

insecticide

non-pers (1)

oral: medium to high (2,3)

dermal: ?

inhalation: medium (1)

suspect carcinogen (4)

suspect mutagen (4)

fetotoxin (4)

“some evidence of hormonal effects” (5)

immediate toxicity:

 birds: medium to high (6)

 fish: low (7)

 crustaceans: low (4)

 molluscs: medium (4)

 bees: high (13)

 plants: low; in plant tissue, metabolizes to acephate met (8–10)

long-term toxicity:

 birds: may affect behavior and breeding success (11,12)

water: “very soluble”

slightly volatile

contaminant(s):

O,O,S-trimethyl phosphorothioate

oral: high (1)

delayed toxicity (1)

methylthioacetate

dermal: medium to high (1)

inhalation: medium (1)

suspect mutagen (1)

eye damage (1)

transformation product(s):

acephate-met (see acephate-met)

84 acephate-met

BAY 71628; Baythroid TM (with cyfluthrin); methamidophos; Monitor; Ortho 9006; SRA 5172; Tamaron; Tamaron (with parathion)

O,S-dimethyl phosphoramidothioate

CAS # 10265-92-6

organophosphate

insecticide

restricted use: USA

non-pers (1)

oral: very high (2)

dermal: very high (2)

inhalation: high (3)

hair loss (8) decreased fertility (8)

immediate toxicity:

 birds: high (4)

 fish: low (5)

 bees: high (6)

 crustaceans: very high (7)

water: “readily soluble”

slightly volatile

acetochlor

Acenit; Harness

2-chloro-N-ethoxymethyl-6′-ethylacet-o-toluidide; chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl) acetamide

CAS # 34256-82-1

amide

herbicide

?

oral: medium (1)

dermal: medium (1)

inhalation: low to medium (1)

suspect carcinogen (2)

immediate toxicity:

 birds: medium (1)

 fish: high (1)

 crustacean: medium (1)

water: soluble

“negligible vapor pressure”

acifluorfen

Blazer 2L; Blazer 2S; Galaxy (with bentazon); Storm (with bentazone); Tackle

5-(2-chloro-α,α,α-trifluoro-p-tolyloxy)- 2-nitrobenzoic acid; 5-[2-chloro-4-(trifluoromethyl) phenoxy]-2-nitrobenzoic acid

CAS # 50594-66-6

phenoxy

herbicide

non-pers to mod-pers (1)

oral: medium (1)

dermal: ?

inhalation: ?

carcinogen (2)

heart, kidney, blood & liver damage (2)

delayed fetal development (2)

immediate toxicity:

 birds: medium to high (1)

 fish: low to medium (1)

 crustaceans: low (1)

water: very soluble

non-volatile

combustible

acrolein

acrylaldehyde; Aqualin; Aqualin Biocide; Aqualin Slimicide; Magnicide H Herbicide

acrylic aldehyde;

allyl aldehyde;

ethylene aldehyde;

α-pentyl-β-phenyl acrylaldehyde; 2-propenal

CAS # 107-02-8

aldehyde

fungicide herbicide

restricted use, USA

non-pers (1)

oral: very high (1)

dermal: high (2)

inhalation: “extremely toxic” (2)

suspect mutagen (3–5)

teratogen (4)

embryotoxin (4)

immediate toxicity:

 birds: very high (6)

 fish: very high (7)

water: “soluble”

highly volatile

flammable

acrylonitrile

Acritet; Acrylofume; Aerylon; Carbacryl; Miller’s Fumigrain; VCN; Ventox

vinyl cyanide;

cyanoethylene;

propenenitrile

CAS # 107-13-1

cyanide

fumigant insecticide

voluntary cancellation of most uses by producer, USA, 1978

?

oral: high (1)

dermal: ?

inhalation: ?

carcinogen (2,3)

mutagen (4)

teratogen (5)

water: “soluble” flammable

Akton

Akton; Axiom; SD 9098

O-[2-chloro-1-(2,5-dichlorophenyl) vinyl]O,O-diethyl phosphorothioate

CAS # 1757-18-2

organophosphate

insecticide

mod-pers (1)

oral: very high (2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: medium (3)

 fish: high to very high (4)

 bees: medium (5)

85 alachlor

Adeochlor; Bronco (with glyphosate); Bullet; Cannon; CP 50144; Lariat; Lasso (with atrazine); Lazo; Partner-Mon-9848; Pillarzo; Rambo (with atrazine)

2-chloro-2′,6′-diethyl-N-(methoxymethyl)-acetanilide

CAS # 15972-60-8

amide

herbicide

banned in Canada, Sweden

restricted use, USA

non-pers to mod-pers (1)

oral: medium (2)

dermal: medium (1)

inhalation: ?

carcinogen (3,4)

suspect mutagen (5,6)

eye damage: (3)

kidney and liver damage (3)

immediate toxicity:

 birds: low to medium (1,7)

 fish: medium to high (1,8)

 bees: low to medium (9)

water: soluble

slightly volatile

aldicarb

OMS771; Sentry (with lindane); Temik (with lindane); UC 21149

2-methyl-2-(methylthio) propionaldehyde O-(methylcarbamoyl) oxime

CAS # 116-06-3

carbamate

insecticide acaracide nematocide

restricted use: USA

non-pers to pers (1,2)

oral: very high (1)

dermal: very high (1)

inhalation: “toxic” (1)

suspect mutagen (3)

may decrease learning behavior (4)

immediate toxicity:

 birds: high to very high (5.6)

 fish: high to very high (6.7)

 bees: very high (8)

 aquatic insects: high (6)

water: soluble

highly volatile

transformation product(s):

aldicarb sulfoxide

2-methyl-2-(methylsulfinyl) propionaldehyde O-(methylcarbamoyl) oxime

CAS # 1646-87-3

oral: very high (1)

aldicarb sulfone

2-methyl-2-(methylsulfonyl) propionaldehyde O-(methylcarbamoyl) oxime

CAS # 1646-88-4

oral: very high (1)

aldrin

Aldrex; aldrine (France); Aldrite; Aldrosol; Altox; Compound 118; Drinox; HHDN; Octalene; Seedrin

hexachlrohexahydro-endo-exo-dimethanonaphthalene; 1,2,3,4,10,10,-hexachloro-1,4, 4a,5,8a-hexahydro-1,4-endo-exo-5,8-dimethanonaphthalene

CAS # 309-00-2

organochlorine

insecticide

most uses banned: USA, 1974 all products cancelled by 1987 with termiticide use ended

mod-pers to pers (1,2)

oral: high to very high (3)

dermal: very high (3)

inhalation: ?

cumulative (1,2)

carcinogen (1/2,4)

suspect teratogen (2,5)

liver and kidney damage (2,6)

BIOCIDE

immediate toxicity:

 birds: very high (3,7)

 fish: very high (7)

 amphibians: medium (7)

 aquatic insects: very high (7)

 crustaceans: very high (7)

 molluscs: very high (7)

 bees: very high (8)

 aquatic worms: medium (9)

aquatic

 plants: medium (7)

water: “insoluble”

oil: “moderately soluble”

slightly volatile

flammable to combustible

transformation product(s):

dieldrin (see dieldrin)

86 allethrin

Allethrin concentrate MGK; Alleviate; allycinerin; Exbiol; FDA 1446; FMC 249; Necarboxylic acid; Neo-Pynamin 5/1/30 (with phenothrin & piperonyl butoxide); NIA 249; OMS 468; pallethrine; Pesguard (with phenothrin & piperonyl butoxide); Pynamin; Pyrescel; Pyresin; Pyrocide; RU 28173; Sumithrin Plus (with phenothrin)

(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1RS)-Cis,trans-chrysanthemate; (RS)-allethronyl (1R,Cis,trans)chrysanthemate

CAS # 584-79-2

pyrethroid

insecticide

?

oral: medium to high (1,2,3)

dermal: low to medium (2,4)

inhalation: medium to high (3)

suspect mutagen (5)

suspect immunotoxin (6)

immediate toxicity:

 birds: low to medium (7,8)

 fish: low to very high (9,10)

 crustaceans: very high (10)

 aquatic insects: very high (10)

volatile to highly volatile

isomer(s):

d-cis/trans-allethrin

Pynamin Forte

d-cis/trans-allethrin; (RS)-[1R,cis/trans]-chrysanthemate

CAS # 42534-61-2

pyrethroid

insecticide

?

oral: high (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: “very high” (2)

combustible

esbiothrin

allethrin stereoisomer; Detrans (with deltamethrin); K-O (with deltamethrin & piperonyl butoxide); OMS 3045; RU 27436

(RS)-allethronyl [1R,trans]-chrysanthemate

pyrethroid

insecticide

?

oral: high (1)

dermal: “low” (2)

inhalation: ?

?

S-bioallethrin

Esbiol; esdepallethrin; OMS 3046; RU 16 121; RU 3054

d-allethronyl d-trans-allethrin; (+)-allethronyl (+)-trans-allethrin

CAS # 28434-00-6

pyrethroid

insecticide

?

oral: medium to high (1,2)

dermal: ?

inhalation: medium to high (1)

?

immediate toxicity:

 birds: low (1)

 fish: medium to very high (1)

water: medium

volatile

combustible

bioallethrin

allethrin stereoisomer; depallethrin; Kefil (with permethrin & piperonyl butoxide); RU 11705; Vapona Flykiller (with permethrin & piperonyl butoxide)

d-trans-allethrin;

(+)-trans-allethrin;

(RS)-allethronyl [1R,trans]-chrysanthemate

CAS # 584-79-2

pyrethroid

insecticide

?

oral: medium to high (1,2)

dermal: ?

inhalation: medium (1)

suspect teratogen (3)

immediate toxicity:

 fish: very high (2)

 crustaceans: low (2)

water: slightly soluble

oil: slightly volatile to volatile

combustible

allyl alcohol

Hopkins Allyl Alcohol

2-propene-1-ol; vinyl carbinol; 1-propenol-3

CAS # 107-18-6

alcohol

soil fumigant insecticide

restricted use, USA, 1976

?

oral: high (1)

dermal: very high (1)

inhalation: very high (2)

suspect mutagen (3,4)

liver damage (5,6)

water: soluble

highly volatile

flammable

transformation product(s):

acrolein

(see acrolein)

87 aluminum phosphide

Celphos (India); Delicia (E. Germany); Phostoxin

aluminum phosphide

CAS # 1302-45-0

metal/mineral

aluminum

insecticide fumigant

restricted use: USA

?

oral: very high (2)

dermal: ?

inhalation: ?

gastrointesti nal damage (1)

liver, heart, and kidney damage (1)

water: “slightly soluble”

transformation product(s):

phosphine gas

CAS # 7803-51-2

oral: very high (1)

dermal: medium (1)

inhalation: “poisonous” (2)

water: “slightly soluble”

oil: “insoluble”

combustible, “can ignite spontaneously in cold air; explosive”

ametryn

A 1093; Ametrex; ametryne; Evik; G-34162; Gesapax; Gesapax combi (with atrazine); Gesapax H (with 2,4-D); Trinatox D

2-(ethylamino)-4-(isopropyl amino)-6-(methylthio)-s-triazi ne; N-ethyl-N′-(1-methyl ethyl)-6-(methylthio)-1,3,5-triazine-2,4-diamine

CAS # 834-12-8

triazine

herbicide

non-pers to mod-pers (1)

oral: medium (2)

dermal: low to medium (2)

inhalation: ?

?

immediate toxicity:

 birds: low (1)

 fish: medium (1)

 crustaceans: high (3)

 bees: low (4)

 molluscs: medium to high (1)

water: soluble

oil: “soluble”

slightly volatile

“nonflammable”

aminocarb

A363; BAY 44646; Matacil

4-(dimethylamino)-m-tolyl methylcarbamate

CAS # 2032-59-9

carbamate

insecticide

non-pers (1)

oral: very high (2)

dermal: high (3)

inhalation: medium (4)

suspect mutagen (5)

immediate toxicity:

 birds: very high (4)

 fish: high (6)

 crustaceans: low (6)

 bees: high (7)

water: “slightly soluble”

slightly soluble

amitraz

Azadieno; Azaform; BAAM; BTS 27419; Estrella; JA 119; Mitaban; Taktic; Triatox; Triazid; U-36059; Zipak (with bifenthrin)

N′-(2,4-dimethylphenyl)-N-((2,4-dimethylphenyl(imino) methyl)-N-methylmethami midamide; N-methyl-N′-2,4-xy lyl-N-(N-2,4-xylyl-formimidoyl)formamidine; N′,N′-[(methylimino)dimethylidyne] bis[2,4-xylidine]

CAS # 33089-61-1

miscellaneous

insecticide acaricide

cancelled USA

?

oral: medium (1)

dermal: medium to high (1)

inhalation: ?

suspect carcinogen (2,3)

immediate toxicity:

 birds: medium (1)

 fish: medium to high (1,4)

 bees: low to medium (5)

water: insoluble

oil: “soluble”

slightly volatile

transformation product(s):

N′-[2,4-xylyl]N-methyl formamidine

oral: high (1)

decreased fertility and viability in young (1)

water: “sparingly soluble”

slightly volatile

88 amitrole

3,A-T; Altazin (with atrazine); Amerol; Amino Triazole; aminotriazole; Amitrole-T; Amizol; AT; ATA; Azolan; Azole; Chempar Amitrole; Cytrol; Diurol; Domatol; Herbizole; Ustinex; Vorox; Weedazol; Weedazol T; X-All

3-amino-1,2,4-triazole; 3-amino-s-tri azole

CAS # 61-82-5

triazole

herbicide

restricted use, USA

non-pers to mod-pers (1)

oral: low (2)

dermal: low to medium (1)

inhalation: ?

carcinogen (3,4)

suspect mutagen (3)

fetotoxin (9)

liver damage (9)

goiters (5)

immediate toxicity:

 birds: low to medium (6)

 fish: low (7)

 crustaceans: low (7)

 bees: low to medium (8)

water: “soluble”

oil: “insoluble”

slightly volatile

ammonium arsenate

inorganic

ammonium thiocyanate

Amitrile T.L. (with amitrole); Amitrole-T (with amitrole); ammonium rhodanide; ammonium sulfocyanate; ammonium sulfocyanide; Amthio; Cytrol Amitrole-T (with amitrole); Giror (with amitrole & paraquat); Radazone TL (with amitrole)

CAS # 1762-95-4

cyanide

herbicide soil sterilant

non-pers to mod-pers (1)

oral: medium (2)

dermal: ?

inhalation: ?

may metabolize slowly in the body to cyanide (3)

water: “very soluble”

“noncombustible”

amobam

Amobam; Chem-O-Bam

diammonium ethylene bisdithiocarbamate

CAS # 3566-10-7

thiocarbamate

fungicide

?

oral: high (1)

dermal: ?

inhalation: ?

?

water: “very soluble”

transformation product(s):

ethylene thiourea

ETU

2-imidazolidinethione

CAS # 96-45-7

oral: medium (1)

carcinogen (2,3)

suspect mutagen (4)

teratogen (4,5,6)

increased fluid in skull (5,7)

goitrogenic (3)

AMS

Amcide; Ammat; Ammate X; Ammate X-NI; ammonium amidosulphate; ammonium sulphamidate; Ikurin; Sulfamate; sulfamate

ammonium amidosulphate;

ammonium sulphamidate;

ammonium sulfamate

CAS # 773-06-0

metal\mineral

sulfur

herbicide

non-pers to mod-pers (1)

oral: medium (2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: medium (2)

 fish: low (1)

 bees: low to medium (3)

water: very soluble

non-volatile

“nonflammable”

anilazine

B-622; Direz; Dyrene; Kemate; Triasyn

2,4-dichloro-6-(o-chloroanilino)-s-triazine

CAS # 101-05-3

triazine

fungicide

non-pers (1)

oral: low to high (1)

dermal: medium (1)

inhalation: ?

?

BIOCIDE

immediate toxicity:

 birds: low (2)

 fish: very high (1)

 crustaceans: high (2)

 bees: low (3)

phytoplankton: high (2)

 plants: toxic to some (4)

water: “insoluble”

89 anthraquinone

Anthracene; anthradione; Corbit; Heolite; Morkit; Quinolate AC, Fs, Quinolate AC Kara (with oxine-copper); Quinolate Triple Kara (with oxine-copper & lindane); Quinolate V 4 X AC, FS, DS (with oxine-copper & carboxin)

9.10-anthraquinone; 9.10-anthracenedione

CAS # 84-65-1

quinone

bird repellent

?

oral: medium (1)

dermal: low to medium (2)

inhalation: ?

suspect mutagen (3,4)

immediate toxicity:

 birds: low (5)

water: “insoluble”

combustible

antimycin A

antimycin A1; antipiricullin; Fintrol; virosin

3-[[3-(formylamino)-2-hydroxybenzoyl]amino]-8-hexyl-2,6-dimethyl-4,9-dioxo-1,5-dioxonan-7-yl 3-methyl butanoate

CAS # 1397-94-0

antibiotic

fungicide piscicide

non-pers (1)

oral: ?

dermal: ?

inhalation: ?

?

immediate toxicity:

 amphibians: low (3)

reptiles: low (3)

 crustaceans: low to medium (2)

plankton: low (3)

water: “insoluble”

antimycin A3

Blastmycin

[2R-(2R*,3S*,6S*,7R*,8R*)]-8-butyl-3-[[3-(formylamino)-2-hydroxybenzoyl] amino]-2,6-dimethyl-4,9-dioxo-1,5-dioxonan-7-yl-3-metylbutanoate

CAS # 522-70-3

antibiotic

fungicide piscicide

non-pers (1)

oral: very high (2)

dermal: ?

inhalation: ?

?

water: “insoluble”

ANTU

Alrato; Antu; Anturat; Bantu; Chemical 109; Dirax; Kill Kantz; Killer Katz; Kripid; krysid (USSR); Naphtox; Rat-tu; Rattrack; Rattract; Smeesana; U5227

α-napthyl thiourea; 1-(1-napthyl)-2-thiourea;

α-naphthylthiocarbamide; 1-naphthalenylthiourea

CAS # 86-88-4

miscellaneous

rodenticide

registration voluntarily cancelled by manufacturer, USA

?

oral: very high (1)

dermal: ?

inhalation: ?

formerly carcinogenic napthylamines suspected as impurities (2)

immediate toxicity:

 birds: medium (2)

water: soluble

contaminant(s):

B naphthylamine

carcinogen (1)

Aramite

88R; Acacide; Aracide; Aramite-15W; Aratron; CES; Niagaramite; Ortho-mite

2(p-tert-butylphenoxy)-1-methylethyl-2′-chloroethyl sulfite

CAS # 140-57-8

organic

acaricide insecticide

registration voluntarily cancelled by manufacturer USA

non-pers (1)

oral: medium (2)

dermal: ?

inhalation: ?

carcinogen (3)

BIOCIDE

immediate toxicity:

 birds: very high (4)

 fish: very high (5)

 crustaceans: very high (5)

 bees: low to medium (6)

 aquatic insects: very high (5)

water: “insoluble”

oil: “soluble”

90 Arosurf

Arosurf

poly(oxy-1,2-ethanediyl), α-isooctadecyl-ω-hydroxy

CAS # 52292-17-8

miscellaneous

insecticide surfactant

non-pers (1)

oral: low (1)

dermal: ?

inhalation: low (1)

?

immediate toxicity:

 fish: low (1)

 crustaceans: high (1)

combustible

arsenic

colloidal arsenic; metallic arsenic

Characteristics as a class are given here; variations are indicted for each compound below

CAS # 7440-38-2

metal/mineral

arsenic

insecticide herbicide rodenticide

pers (1)

oral: high (2)

dermal: ?

inhalation: ?

cumulative (3)

carcinogen (4–6)

mutagen (3)

teratogen (3,7)

water: “insoluble”

compound(s):

ammonium arsenate

CAS # 53404-17-4

inorganic

ammonium methanearsonate

AMA; Ansar 157; Super Crab-E-Rad A.M.A.

monoammonium methanearsonate; monoammonium methylarsonate; methanearsonic acid, monoammonium salt; methylarsonic acid, monoammonium salt; MAMA; MM A; amine methanearsonate* (also called AMA)

*combination of dodecylammonium methanearsonate and octylammonium methanearsonate

CAS # 2321-53-1

organic

herbicide

oral: medium (1,2)

arsenic acid

Crab Grass Killer; Hi-Yield Dessicant H-10;

Zotox

arsenic acid;

o-arsenic acid

CAS # 7778-39-4

inorganic

herbicide

oral: high to very high (1)

suspect mutagen (2)

arsenic pentoxide

arsenic acid anhydride;

arsenic anhydride;

arsenic oxide;

arsenic penthoxide;

arsenic [V] oxide

CAS # 1303-28-2

inorganic

herbicide fungicide wood preservative

suspect mutagen (1,2)

testicular damage (3)

water: soluble

arsenic trioxide

Arsenolite; Arsodent; Clandelite; white arsenic

arsenic oxide;

arsenic (III) oxide;

arsenic sesquioxide;

arsenious acid;

91arsenious trioxide;

arsenolite;

arsenous acid;

arsenous acid, anhydride;

arsenous oxide

arsenous oxide, anhydride;

arsentrioxide

CAS # 1327-53-3

inorganic

herbicide insecticide rodenticide

cancelled USA, 1977

oral: high (1)

carcinogen (2)

suspect mutagen (3)

fetotoxin (3,4)

cacodylic acid

Cotton Aide HC; Dilie; DMAA; Moncide;

Montar; Phytar 138; Rad-E-Cate 25; Silvisar

dimethylhydroxyarsine oxide;

dimethylarsinic acid;

dimethylarsenic acid;

CAS # 75-60-5

organic

oral: medium

calcium acid methanearsenate

CAMA; Super Crab-E-Rad-Calar; Super Dal-E-Rad

methanearsonic acid, calcium salt;

calcium acid methanearsenate;

calcium acid methyl arsenate;

calcium methanearsenate

CAS # 5902-95-4

organic

herbicide

oral: medium (1)

“nonflammable”

calcium arsenate

Chip-Cal Granular; Cucumber Dust; FLAC; KALO;

Kilmag; Pencal; Security; Spra-Cal

arsenic acid, calcium salt;

calcium arsenate;

calcium o-arsenate;

tricalcium arsenate

CAS # 7778-44-1

inorganic

insecticide

cancelled USA

pers (1)

oral: medium to very high (2,3)

dermal: medium (4)

immediate toxicity:

 bees: medium (5)

water: insoluble to soluble

calcium arsenite

inorganic

insecticide

water: “slightly soluble”

calcium propanearsenate

propanearsonic acid, calcium salt;

calcium propanearsonate;

calcium propyl arsonate

CAS # 126-94-3

organic

herbicide

oral: high (1)

chromated copper arsenate

CCA; Osmose; Wolmanized; WoodPlus

copper chromated arsenate

inorganic

fungicide insecticide

restricted use, USA

“arsenic can be released from pressure treated wood” (1)

“sealant…did not reduce the dislodgeable arsenic levels” from wood. (1)

92 copper acetoarsenite

Emerald green; French green; mitis green; Paris green; Schweinfurt green

CAS # 12001-03-8

organic

cancelled USA, 1977

oral: very high (1)

immediate toxicity:

 amphibians: very high (1)

cupric arsenite

Scheele’s green

arsonic acid copper (2+) salt; arsenious acid copper (2 +) salt

inorganic

fungicide insecticide rodenticide

water: “practically insoluble”

DSMA

Arrhenal; Arsinyl; Di-Tac; disodium methanearsonate; DMA; DMA 100; Methar 30; Sodar

disodium methanearsoate;

disodium methylarsonate;

methanearsonic acid, disodium salt;

methylarsonic acid, disodium salt;

disodium acid methanearsonate

CAS # 144-21-8

organic

herbicide

mod-pers (1)

oral: medium (2,3)

dermal: very high (4)

inhalation: low (2)

lead arsenate

arsenate of lead; dibasic lead arsonate; Gypsine; lead acid arsonate; Soprabel; Talbot

arsenic acid, lead salt;

acid lead arsonate; acid lead o-arsenate

CAS # 7784-40-9

inorganic

insecticide; fungicide

cancelled, USA

pers (1)

oral: medium to high (1)

water: “slightly soluble”

methyl arsonic acid

MAA

methanearsonic acid;

methylarsenic acid;

monomethylarsinic acid

CAS # 1 24-58-3

organic

MSMA

Check Mate; Herb-All; Merge 823; monosodium methanearsonate; Quadmec (with 2,4-D & dicamba & mecoprop); Silvisar; Target MSMA; Trans-Vert

monosodium methanearsonate;

monosodium methylarsonate;

methanearsonic acid, monosodium salt;

methylarsonic acid, monosodium salt;

monosodium acid methanearsonate

CAS # 2163-80-6

organic

herbicide

mod-pers to pers (1,2)

oral: medium to very high (3,4)

dermal: medium to very high (4,5)

inhalation: low (3)

toxic hepatitis (6)

immediate toxicity:

 fish: low to medium (3)

long-term toxicity:

may accumulate in plants (7)

water: very soluble

OBPA

10,10′-oxybis-10H-phenox arsine

CAS # 58-36-6

organic

antibiotic

restricted USA, 1979

oral: very high (1)

dermal: very high (1)

inhalation: low (1)

cumulative (1)

immediate toxicity:

 birds: low (1)

 fish: very high (1)

 crustaceans: very high (1)

water: slightly soluble

highly volatile

93 sodium arsenate [I]

Fatsco Ant Poison; Sweeney′s Ant-Go

sodium arsenate;

sodium m-arsenate;

sodium o-arsenate

CAS # 7631-89-2

inorganic

wood preservative

all non wood preservative uses cancelled, USA 1986

teratogen (1)

embryotoxin (2)

liver and kidney effects (3)

water: “very soluble”

sodium arsenate [II]

disodium arsenate;

disodium arsenic acid;

disodium hydrogen arsenate;

disodium hydrogen o-arsenate;

disodium monohydrogen arsenate;

sodium acid arsenate;

dibasic sodium arsenate;

sodium arsenate dibasic anhydrous

CAS # 7778-43-0

inorganic

wood preservation

all nonwood preservative cancelled, uses USA, 1986

carcinogen (1)

suspect mutagen (2,3)

water: “very soluble”

sodium arsenate [III]

arsenic acid, disodium salt, heptahydrate;

dibasic sodium arsenate;

disodium arsenate, heptahydrate;

sodium acid arsenate, heptahydrate;

sodium arsenate;

dibasic, heptahydrate;

disodium arsenate heptahydrate;

sodium arseniate

CAS # 10048-95-0

inorganic

wood preservative

all non wood preservation uses cancelled, USA, 1986

suspect mutagen (1/2)

teratogen (3,4)

embryotoxin (5)

sodium arsenite

Atlas ‘A’; Chem Pels; Chem-Sen 56; Kill-All;

Penite; Prodalumnol Double

sodium arsenite;

sodium m-arsenite;

arsenous acid, sodium salt;

arsenious acid, monosodium salt;

arsenious acid; sodium salt

CAS # 7784-46-5

inorganic

fungicide herbicide insecticide

cancelled, most uses, USA, 1978

pers (1)

oral: very high (2)

dermal: very high (3)

inhalation: ?

suspect mutagen (4,5)

teratogen (6)

fetotoxin (6)

embryotoxin (7)

immediate toxicity:

 birds: high to very high (2)

 crustaceans: very high (9)

 fish: high to very high (9)

 molluscs: very high (9)

water: “very soluble”

asulam

Asilan; Asulfox F; Asulox; Asulox 40; Candex (with atrazine); Dialam (with diuron); Graslam (with mecoprop & MCPA); Jonnix; Krater (with diuron); MB 9057; Slam (with dalapon); Talent (with paraquat); Target (with dalapon); Tartan (with diuron)

methyl sulfanilylcarbamate; methyl [(4-ami nophenyl)sulfonyl]carbamate

CAS # 3337-71-1

carbamate

herbicide

non-pers (1)

oral: low (1)

dermal: low to medium (1)

inhalation: low to medium (1)

suspect carcinogen (2)

immediate toxicity:

 birds: low to medium (1)

 fish: low (3)

 crustaceans: low (2)

 bees: low to medium (4)

water: slightly soluble

non-volatile

“nonflammable”

94 atrazine

AAtrex; Altacide Extra (with sodium chlorate); Atlazin (with amitrole); Atradex; Atradex 50; Atranex; Bel later (with cyanazine); Bicep (with metolachlor); Extrazine (with cyanazine); Fogard; Fogard L; Geigy 30,027; Gesaprim; Gesaprim D (with 2,4-D); Lasso (with alachlor); Primatol; Sutan +; Vectal; Vorox Granulat 371; Weedex A

2-chloro-4-ethylamino-6-isopropylamino-s-triazine

CAS # 1912-24-9

triazine

herbicide

restricted use, USA, 1990

mod-pers to pers (1,2)

oral: low to medium (3,4)

dermal: medium (3)

inhalation: “low” (4)

carcinogen (5,6)

mutagen (7,8)

immunotoxin (9)

adrenal damage (10)

immediate toxicity:

 fish: low to high (4)

 crustaceans: low to medium (4)

 bees: medium (2)

 molluscs: high (1)

 aquatic insects: high to very high (13)

long-term toxicity: soil invertebrates: may reduce populations (11)

 amphibians: may impair reproduction (13)

water: slightly soluble

slightly volatile

transformation product(s):

N-nitrosoatrazine

auramine

4,4-carbonimidoylbis[N,N-dimethylbenzenamine]monohydrochloride

CAS # 492-80-8

miscellaneous

fungicide

?

oral: ?

dermal: ?

inhalation: ?

carcinogen (1,2)

suspect mutagen (3)

?

Avitrol 100

Avitrol 100

4-nitropyridine N-oxide

CAS # 1124-33-0

miscellaneous

avicide

?

oral: ?

dermal: ?

inhalation: ?

suspect mutagen (1,2)

immediate toxicity:

 birds: very high (3)

Avitrol 200

Avitrol 200

4-aminopyridine; 4-aminopyridine hydrochloride

CAS # 504-24-5

miscellaneous

avicide

restricted, USA

mod-pers to pers (1)

oral: very high (1)

dermal: high (1)

inhalation: ?

?

immediate toxicity:

 birds: very high (2)

 fish: very high (1)

water: very soluble

azacosterol

azacholesterol; Azasterol; diazasterol; ornitrol; SC-12937

azacosterol hydrochloride; 20,25-diazacholesterol dihydrochloride; 17-β-(dimethylamino)propyl) methylamino)adrost-5-en-3-β-ol dihydrochloride

CAS # 1249-84-9

miscellaneous

bird sterilant

?

oral: medium to high (1)

dermal: ?

inhalation: ?

?

water: “moderately soluble”

oil: “insoluble”

azinphos-ethyl

Acifon; Azinos; azinphos-ethyl; BAY 16259; Bionex; Cotnion-Ethyl; Crysthion; Ethyl Guthion; ethylazinphos; Gusathion A; R1513; triazotion (USSR)

O,O-diethyl 3-(4-oxo-1,2,3-benzotriazin-3 (4H)-yl)methyl phosphorodithioate

CAS # 2642-71-9

organophosphate

insecticide

not registered, USA

?

oral: very high (1)

dermal: high (1)

inhalation: ?

?

immediate toxicity:

 birds: “toxic” (1)

 fish: “toxic” (1)

non-volatile to slightly volatile

“flammable”

95 azinphos-methyl

azinphos-methyl; BAY 17147; Carfene; Cotnion-methyl; Gusathion; Guthion; Methyl Guthion; methylazinphos; metil-triazotion (USSR)

O,O-dimethyl S[4-oxo-1,2,3-benzotriazin- 3(4H)ylmethyl]phosphorodithioate

CAS # 86-50-0

organophosphate

insecticide acaricide

restricted use, USA, 1977

non-pers (1)

oral: high to very high (2,3)

dermal: high to very high (2,3)

inhalation: ?

suspect carcinogen (4,5)

suspect mutagen (6,7)

immediate toxicity:

 birds: high (3)

 fish: very high (3)

 crustaceans: very high (3)

 aquatic insects: very high (3)

slightly volatile

combustible

transformation product(s):

oxygen analogue of azinphosmethyl

appears one week after spraying with azinphosmethyl (1)

aziprotryne

aziprotryn; Brasoran; Brassoron; C07019; Mesoranil; Mezuron

2-azido-4-isopropylamino-6-methylthio-s-triazine;

4-azi do-N-(1-methylethyl)-6-(methylthio)-1,3,5-triazin-2-amine

CAS # 4658-28-0

triazine

herbicide

not registered, USA

non-pers to mod-pers (1)

oral: low to medium (2)

dermal: low to medium (2)

inhalation: ?

?

water: slightly soluble

slightly volatile

azobenzene

diphenyldiimide; diphenyldiazene; azobenzide; azobenzol

CAS # 103-33-3

miscellaneous

acaricide fumigant

withdrawn from market by manufacturer USA

?

oral: medium (1)

dermal: ?

inhalation: ?

carcinogen (2,3)

mutagen (4,5)

liver damage (6)

spleen damage (4)

water: “practically insoluble”

transformation product(s):

azoxybenzene

Azomyte

diphenyldiazene 1-oxide;

azobenzenoxide;

azoxybenzide; azosydibenzene

CAS # 495-48-7

miscellaneous

acaricide

oral: low to medium (1)

water: “insoluble”

Bacillus thuringiensis (Berliner)

B.T.

biological

insecticide

non-pers (1)

oral, dermal, inhalation: “non-toxic” (2,3)

?

?

varieties:

Bacillus thuringiensis var. aizawei

Certan

Bacillus thuringiensis, variety aizawei

larvacide for wax moth

Bacillus thuringiensis var. israelensis

Bactimos; BMC; Skeetal; Teknar; Vectobac

Bacillus turingiensis, variety israelensis

larvacide for mosquitoes and some other flies

water: “insoluble”

96 Bacillus thuringiensis var. kurstaki

Agritol; Attack; Bactospeine; Bactur; Bakthane; Biotrol; BTV; Bug Time; Cekubacillina; Dipel; Foray; Javelin; Larvatrol; Leptox; Novabac; Thuricide; Tri bactur

Bacillus thuringiensis, variety kurstaki

larvacide for moths

water: “insoluble”

Bacillus thuringiensis var. san diego

M-One

Bacillus thuringiensis, variety san diego

larvacide for some beetles

Bacillus thuringiensis var. tenebrionis

Trident

Bacillus thuringiensis, variety tenebrionis

larvacide for some beetles

barban

barbamate (So. Africa); barbane (France); Carbyen; Caryne; CBN; chlorinat (USSR); Fisons B25; Neoban

4-chloro-2-butynyl m-chlorocarbanilate; 4-chloro-2-butyl N-(3-chlorophenyl) carbamate

CAS # 101-27-9

carbamate

herbicide

mod-pers (1)

oral: medium (2)

dermal: ?

inhalation: low (2)

?

immediate toxicity:

 fish: medium (1)

 bees: low to medium (3)

water: slightly soluble to very soluble

slightly volatile

flammable

barium metaborate

metal/mineral

fungicide

?

oral: ?

dermal: ?

inhalation: ?

?

water: soluble

barthrin

6-chloropiperonyl chrysanthemate; 6-chloropiperonyl-2,2-dimethyl-3-(2-methylpropenyl) cyclopropanecarboxylate

CAS # 70-43-9

pyrethroid

insecticide

?

oral: low (1)

dermal: ?

inhalation: ?

?

oil: “soluble in kerosene”

benalaxyl

Galben C. (with copper oxychloride); Galben F (with folpet); Galben M (with mancozeb); Galben RF (with copper sulfate and folpet); Galben Z (with zineb); Galben; Tairel; Tairel C. (with copper oxychloride); Tairel F (with folpet); Tairel M (with mancozeb); Tairel Z (with zineb)

methyl N-phenylacetyl-N-2, 6-xylyl-dl-alaninate

CAS # 71626-11-4

miscellaneous

fungicide

not registred for use in U.S.

?

oral: medium (1)

dermal: ?

inhalation: low to medium

?

immediate toxicity:

 birds: low (1)

 fish: medium (1)

water: slightly soluble

slightly volatile

combustible

97 benazolin

Asset; Banzsalox; Benazolox (with clopyralid); Bencornox; Benopan; Bensecal; Benzar; Cresopur; Galipan; Galtak; Grassland Weedkiller; Herbazolin; Keropur; Legumex Estra; Ley-Cornox (with 2,4-DB & MCPA); Leymin; Springclene 2; Tri-Cornox (with dicamba & dichlorprop); Tri-Cornox Special

4-chloro-2-oxo-3-benzothiazoline acetic acid;

4-chloro-2-oxobenzothiazolin-3-yl-acetic acid;

4-chloro-2-oxo-3(2H)-benzothiazol acetic acid

CAS # 3813-05-6

miscellaneous

herbicide

?

oral: low to medium (1,2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: medium (3)

 crustaceans: medium (3)

 bees: “non-toxic” (3)

water: insoluble

“nonflammable”

bendiocarb

Dycarb; Ficam; Garvox; Multamat; Niomil; Seedox; Tatoo; Turcam

2,2-di methyl-1,3-benzodioxol-4-yl methylcarbamate

CAS # 22781-23-3

carbamate

insecticide

non-pers to mod-pers (1)

oral: very high (1)

dermal: high (1)

inhalation: ?

cataracts (1)

immediate toxicity:

 birds: very high (2)

 fish: high (1)

 bees: “highly toxic” (3)

 plants: toxic to some (4)

water: very soluble

oil: soluble

slightly volatile

contaminant(s):

dibenzodioxin or dibenzofuran impurities

dibenzodioxin/dibenzofuran

transformation product(s):

methyl isocyanate

(the Bhopal chemical)

oral: high (1)

dermal: medium to high (2)

inhalation: medium (1)

suspect mutagen (3)

suspect fetotoxin (3)

lung damage (3)

water: “sparingly soluble”

highly volatile

benefin

Balan; Balfin; Benefex; benfluralin; bethrodine; Binnell; El 110; Quilan

N-butyl-N-ethyl-α,α,α-trifluoro-2, 6-dinitro-p-toluidine

CAS # 1861-40-1

dinitroaniline

herbicide

mod-pers (1)

oral: low to medium (2)

dermal: low (2)

inhalation: medium to high (2)

?

immediate toxicity:

 birds: low (2)

 fish: “toxic” (2)

 bees: “relatively nontoxic” (3)

water: insoluble

slightly volatile

“nonflammable”

benomyl

Benlate; DuPont 1991; Tersan 1991; Turf Fungicide

methyl 1-(butylcarbamoyl)-2-benzimidazole carbamate

CAS # 17804-35-2

benzimidazole

fungicide

restricted, USA, 1982

mod-pers (1)

oral: low (2)

dermal: low to medium (3)

inhalation: ?

suspect carcinogen (4,5)

mutagen (4,5)

teratogen (4,5)

liver and testes damage (5,6)

reduced sperm (6)

blood damage (5)

immediate toxicity:

 birds: high (7)

 fish: high to very high (8)

 earthworms: high (9)

 crustaceans: low (9)

 bees: low (10)

long-term toxicity:

 plants: mutagen

water: “insoluble”

oil: “insoluble”

98transformation product(s):

thiophanate methyl

(see thiophanate methyl)

carbendazim

(see carbendazim)

bensulide

Betasan; Disan; Exporsan; Prefar; Presan; R-4461

S-2-benzenesulfonamidoethyl O,O-di-isopropyl phophorodithioate; O,O-di-isopropyl S-2-phenylsulfonaminoethyl phospnorodithioate

CAS # 741-58-2

organophosphate

herbicide

mod-pers (1)

oral: medium to high (2)

dermal: medium (1)

inhalation: ?

?

immediate toxicity:

 fish: high (2)

 bees: low to medium (3)

water: slightly soluble

combustible

bentazon

Basagran DP (with dichlorprop); Basagran Ultra (with ioxynil & dichlorprop); Basagran-M60; bendioxide (So. Africa); bentazone; Galaxy (with acifluorfen); Laddok (with atrazine); Storm (with acifluorfen); Triagran (with MCPA & dichlorprop); Ultima (with dichlorprop); Vega (with cyanazine & dichlorprop)

3-isopropyl-1H-1,2,3-benzothioadiazi n-4-(3H)-one 2,2-dioxide

CAS # 2505-89-0

miscellaneous

herbicide

non-pers (1)

oral: medium to high (1,2)

dermal: medium (1)

inhalation: ?

teratogen (3)

immediate toxicity:

 birds: medium (1)

 fish: low (1)

 bees: “harmless” (1)

water: soluble

oil: very soluble

non-volatile

combustible

benthiocarb

B-3015; Bolero; Saturn; Saturno; thiobencarb

S-[(4-chlorophenyl)methyl)] diethylcarbamothioate

CAS # 28249-77-6

carbamate

herbicide

non-pers to mod-pers (1,2)

oral: medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: low (1)

 fish: medium to high (3)

 crustaceans: medium (2)

water: slightly soluble

slightly volatile

flammable

benzalkonium chloride

Barquat MB-50; Barquat MB-80; BTC; Hyamine 3500; Zephiram

alkyl dimethyl benzylammonium chloride

CAS # 8001-54-5

quaternary ammonium

antibiotic algacide fungicide

?

oral: high (1)

dermal: ?

inhalation: ?

mutagen (3)

immediate toxicity:

 birds: “slightly toxic” (2)

 fish: “moderately to highly toxic” (2)

flammable

benzene

benzol; benzole; benzolene; bicarburet of hydrogen; carbon oil; coal naphtha; cyclohexatriene; minderal naptha; motor benzol; phene; phenyl hydride; pyrobenzol; pyrobenzole

benzene

CAS # 71-43-2

aromatic hydrocarbon

fumigant insecticide solvent

pesticide uses cancelled, USA

?

oral: low to high (1,2)

dermal: ?

inhalation: “very high” (2)

carcinogen (4,5,6)

mutagen (4,7)

teratogen (8,9)

blood damage (5,10)

bone damage (2)

water: soluble

flammable

99transformation product(s):

phenol

(see phenol)

1.2.4-benzenetriol

1.2.4-benzenetriol

suspect mutagen (1)

benzene hexachloride

666 (Denmark); Benzahex; Benzex; BHC; DHB; Dol; Dolmix; FBHC; Gexane; HCCH; HCH (Europe); Heapoudre; Hexablanc; hexachloran (USSR); Hexafor; Hexamul; Hexyclan; Kotol; Lindacol; Soprocide

1,2,3,4,5,6-hexachlorocyclohexane

CAS # 608-73-1

 MX8007-42-9

 319-84-6 (α isomer)

 319-85-7 (β isomer)

 319-86-8 (Δ isomer)

 58-89-9 (γ isomer)

 6108-10-7 (ϵ isomer)

organochlorine

insecticide

“not produced or registered in USA”

pers (1)

oral: high (2)

dermal: ?

inhalation: ?

cumulative (3,4)

carcinogen (4,5)

mutagen (6)

fetotoxin (7)

liver damage (8)

reproductive effects (7)

bone marrow damage (aplastic anemia) (9)

immediate toxicity:

 birds: medium to high (10)

 fish: very high (11)

 amphibians: medium (12)

 crustaceans: very high (11)

 aquatic insects: very high (11)

 aquatic worms: high (14)

 bees: very high (13)

 plants: high (12)

long-term toxicity:

 plants: mutagen (15)

water: “insoluble”

slightly volatile

combustible

transformation product(s):

2,4,6-trichlorophenol

(see 2,4,6-trichlorophenol)

2,4,5-trichlorophenol

(see 2,4,5-trichlorophenol)

benzthiazuron

BAY 60618; Gatinon; Gatnon; S 22012

1-benzothiazol-2-yl-3-methyl urea; N-(2-benzothiazolyl)-N′-methyl urea

CAS # 1929-88-0

urea

herbicide

not registered for use in USA

?

oral: medium (1)

dermal: ?

inhalation: ?

?

water: slightly soluble

slightly volatile

6-benzyladenine

BAP; Paturyl

6-benzyladenine; 6-benzylamino-purine

CAS # 1214-39-7

miscellaneous

growth regulator

?

oral: very high (1)

dermal: ?

inhalation: ?

suspect mutagen (2)

immediate toxicity:

 fish: “toxic” (1)

 bees: “toxic” (1)

water: insoluble

bifenox

Mowdown (with 2,4-D)

methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate; 5-(2,4-dichlorophenoxy)-2-nitro-benzoic acid, methyl ester

CAS # 42576-02-3

phenoxy

herbicide

non-pers to mod-pers (1)

oral: low (1)

dermal: low to medium (1)

inhalation: low (2)

?

immediate toxicity:

 birds: low (1)

 fish: high (3)

 crustaceans: medium (4)

 aquatic insects: high (4)

water: insoluble

oil: soluble

slightly volatile

combustible

100 bifenthrin

biphenate; Brigade; FMC 54800; OMS 3024; Talstar; Torant (with clofentezine); Zipak (with amitraz)

2-methylbiphenyl-3-yl methyl (Z)-(1RS,3RS)-3-)2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropanecarboxylate

CAS # 82657-04-3

pyrethroid

insecticide acaricide

mod-pers (1)

oral: high to very high (1,2)

dermal: ?

inhalation: ?

suspect carcinogen (1)

suspect mutagen (1)

immediate toxicity:

 birds: medium (1,2)

 fish: very high (1,2)

 crustaceans: very high (2)

 aquatic invertebrates: very high (1)

water: insoluble

slightly volatile

combustible

binapacryl

Acricide; Ambox; Dapacril; dinoseb methacrylate; Endosan; FMC 9044; HOE 2784; Morocide; NIA 9044

2-sec-butyl-4,6-dinitrophenyl-3-methyl-2-butenoate

CAS # 485-31-4

phenol

insecticide acaricide fungicide

?

oral: medium to high (1,2)

dermal: high (2)

inhalation: ?

?

immediate toxicity:

 fish: high (3)

 bees: medium (4)

water: “practically insoluble”

bithionol

Actamer; Bithin; Lorothidol; TBP; Vancide BL or BN; XL-7

2,2′-thiobis(4,6-dichlorophenol)

CAS #97-18-7

organochlorine

fungicide

cancelled, USA, 1968

?

oral: low to medium (1)

dermal: ?

inhalation: ?

?

water: “practically insoluble”

oil: soluble

non-volatile

blasticidin S

BLA-S

(S)-4-[[3-amino-5-[(aminoiminomethyl)methylamino]-1-oxopentyl]amino]-1-(4-amino-2-oxo-1-(2H)-py rimidinyl)-1,2,3,4-tetradeoxy-d-erythro-hex-2-enopyranuronic acid

CAS # 2079-00-7

antibiotic

fungicide

used only in Japan

?

oral: high to very high (1,2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: “slightly toxic” (3)

water: “insoiuble to soluble”

“nonflammable”

Bomyl

Bomyl; Fly Bait Grits; GC 3707; Swat

dimethyl 3-hydroxyglutconate dimethyl-phosphate; dimethyl 3-[(dimethoxyphosphinyl)oxy]-2-pentendioate

CAS # 122-10-1

organophosphate

insecticide acaricide

restricted use, USA

non-pers (1)

oral: very high (2)

“highly toxic to humans and animals by ingestion, inhalation, or skin contact” (3)

?

immediate toxicity:

 birds: very high (4)

 bees: very high (5)

water: “insoluble”

oil: “insoluble”

highly volatile

borax

Agriben (with bromacil); Borascu; Borate; Borocil; Borospray; Gerstley; Neobor; Polybor 3; Pyrobor; Trona; Tronabor; V-Bor

sodium tetraborate decahydrate;

sodium biborate;

sodium pyroborate;

sodium tetraborate anhydrous

CAS # 1303-96-4

mineral: borate

fungicide herbicide insecticide

mod-pers (1)

oral: low to medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: low (2)

water: very soluble

“nonflammable”

accumulates in soils

101 Bordeaux mixture

Bor-Dax; Copper Hydro Bordo; FT 2M (with mancozeb); Fungi-Bordo

mixture of calcium hydroxide and copper sulfate

CAS # 8011-63-0

inorganic

fungicide

?

oral: ?

dermal: ?

inhalation: ?

?

water: “insoluble”

boric acid

Borofax; borsaure; NCI-C566417; P.F. Harris Famous Tablets; Roach Prufe

boracic acid; orthoboric acid

CAS # 10043-35-3

inorganic

insecticide fungicide herbicide

?

oral: low to medium (1)

dermal: “well absorbed through denuded or abraded skin” (3)

inhalation: ?

testes damage (2)

gastrointestinal, skin, kidney damage (3)

?

brodifacoum

brodifakum (Czech); Havoc; Klerat; Lim-N8; Matikus; PP 581; Ratak Plus; Ropax; Talon; Volid; WBA 8119

3-(4-(4′-bromo(1,1′-biphenyl)-4-yl)-1,2,3,4-tetrahydro-1-naphthalenyl-4-hydroxy-2H-1-benzopyran-2-one; 3-[3-(4′-bromobiphenyl-4-yl)-1,2,3,4-tetrahydro-1-naphthyl]-4-hydroxycoumarin

CAS # 56073-10-0

coumarin

rodenticide

mod-pers (1)

oral: very high (2)

dermal: very high (2)

inhalation: ?

?

immediate toxicity:

 birds: very high (1)

 fish: active ingredient (very high) Talon (low) (1)

long-term toxicity: “keep away from children, domestic animals, and wildlife” (2)

water: “insoluble”

oil: “insoluble”

bromacil

Agriben (with borax); Bromox; Brush-Off; Croptex Onyx; Cynogan; Du-Dusit (with dichlobenil); Fasco Gransil-X; Foremost Weed-Zapper; Galar (with diuron); Habco Bromex; Herbicide 976; HK-80 Weed Killer; Hysan “600” Weed Killer; Hyvar X; Puritan 3925; Rokar X; Terra-Var; Urox HX; Zep Formula 777; Zilch Liquid Weed Killer

5-bromo-3-sec-butyl-6-methyluracil; 5-bromo-6-methyl-3-(1-methylpropyl)uracil

CAS # 314-40-9

uracil

herbicide

mod-pers (1)

oral: low (1)

dermal: ?

inhalation: “low” (1)

?

immediate toxicity:

 birds: low (3)

 fish: low (2)

 bees: low (4)

water: soluble

“combustible”

bromadiolone

Apobas; bromakil; Bromatrol; Bromone; Bromorat; Canadien 2000; Deadline; Deturi Ratones; Lanirat; Maki; Musal; Ratinus; Rodine-C; Slaymore; Spyant Ratones; Super Asecho; Super-Caid; Super-Rozol; Temus; Topidion

3-[3-(4′-bromo(1,1′-biphenyl]-4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy-2H-1-benzopyran-2-one; 3-[-[p-(p-bromophenyl)-hydroxyphenethyl]-benzyl-4-hydroxycoumarin]

CAS # 28772-56-7

coumarin

rodenticide

?

oral: very high (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: high (2)

water: “insoluble”

“nonflammable”

102 bromethalin

EL-614; Vengeance

N-methyl-2,4-dinitro-N-(2,4,6-tribromophenyl)-6-(trifluoromethyl)-benzenamine

CAS # 63333-35-7

miscellaneous

rodenticide

?

oral: high to very high (1,2)

dermal: ?

inhalation: high (1)

?

immediate toxicity:

 birds: very high (2)

 fish: very high (2)

 aquatic insects: very high (2)

water: “not soluble”

bromophos

Brofene; bromofos; Brophene; CELA-S-1942; Kilsect; Netal; Nexion; Omexan; OMS 658

O-(4-bromo-2,5-dichlorophenyl)-O,O-dimethylphosphorothioate

CAS # 2104-96-3

organophosphate

insecticide acaricide

non-pers to mod-pers (1,2)

oral: low to medium (3,4)

dermal: medium to high (4)

inhalation: ?

mutagen (5)

immediate toxicity:

 birds: low (4)

 fish: high to very high (3,6)

 bees: “toxic” (3)

water: slightly soluble

volatile

bromophos-ethyl

bromofos-ethyl; CELA S-2225; Filariol; Nexagan; OMS 659; Paraban

O-(4-bromo-2,5-dichlorophenyl)-O,O-diethylphosphorothioate

CAS # 4824-78-6

organophosphate

insecticide acaricide

not registered for use in USA

?

oral: high (1)

dermal: high (2)

inhalation: ?

?

immediate toxicity:

 birds: medium to high (3)

water: slightly soluble

slightly volatile

bromopropylate

GS 19851; Neoron; phenisobromolate; qAcarol

isopropyl 4,4′-dibromobenzilate; 1-methylethyl 4-bromo-α-(4-bromophenyl)-α-hydroxybenzeneacetate

CAS # 18181-80-1

miscellaneous

acaricide

non-pers (1)

oral: low (2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: medium to high (2)

 bees: low to medium (3)

water: slightly soluble

non-volatile

bromoxynil

Actril S (with ioxynil & dichlorprop & MCPA); Brominal; Brominil; Buctril; Buctril 20; Buctril 21; Buctril ME4; butichlorfos (USSR); Chipco Buctril; Chipco Crab-kleen; Dantril (with ioxynil & dichlorprop & MCPA); Harness; MB 10064; Nu-Lawn Weeder; One Shot (with diclofop-methyl & MCPA); Oxytril P (with dichlorprop & ioxynil); Partner; Tetroxone M (with dichlorprop & ioxynil & MCPA); Torch 3F (with atrazine); Trio (with 2,4-D & propanil)

3,5-dibromo-4-hydroxybenzonitrile

CAS # 1689-84-5

benzonitrile

herbicide

restricted USA

non-pers (1)

oral: high (2)

dermal: medium (2)

inhalation: ?

teratogen (3)

immediate toxicity:

 birds: medium to high (2)

 fish: very high (2)

 bees: low to medium (4)

 aquatic insects: very high (2)

water: soluble

oil: soluble

slightly volatile

combustible

bronopol

Bronocot; Bronosol; Bronotak

2-bromo-2-nitropropan-1,3-diol; β-bromo-β-nitromethyleneglycol

CAS #52-51-7

miscellaneous

bactericide antibiotic

?

oral: high (1)

dermal: ?

inhalation: ?

?

water: very soluble

oil: “insoluble”

slightly volatile

bufencarb

Bux; Bux-Ten Granular; metalkamate; Ortho 5353; RE-5353

mixture: m-(ethylpropyl)phenyl methylcarbamate and m-(1-methylbutyl)phenyl methylcarbamate

CAS # 8065-36-9

carbamate

insecticide

cancelled USA

non-pers (1)

oral: high (2)

dermal: high (2)

inhalation: ?

?

immediate toxicity:

 birds: low to very high (3)

 fish: high to very high (2)

 bees: high (4)

water: slightly soluble

slightly volatile

103 butachlor

Butanex; Butanox; CP 53619; Lambast; Machete; Rasayanchlor

N-(butoxymethyl)-2-chloro-2′,6-diethylacetanilide; N-(butoxymethyl)-2-chloro-N-(2,6-diethylphenyl) acetamide

CAS # 23184-66-9

amide

herbicide

not registered: USA

non-pers (1)

oral: medium (1,2)

dermal: medium (2)

inhalation: medium (1)

suspect mutagen (3)

immediate toxicity:

 fish: medium to high (1)

 birds: low to medium (1)

water: slightly soluble

slightly volatile

combustible

butam

Comodor; S-15544; Tebutam; Tebutame

2,2-dimethyl-N-(1-methylethyl)-N-(phenylmethyl)propanamide

CAS # 35256-85-0

amide

herbicide

non-pers (1)

oral: low to medium (1,2)

dermal: ?

inhalation: ?

?

oil: “insoluble” flammable

2-butanamine

2-AB; Betafume; Deccotane; Frucote; Tutane

2-butanamine; sec-butylamine; 2-aminobutane

CAS # 513-49-5

miscellaneous

fungicide

?

oral: high (1)

dermal: ? inhalation: ?

suspect carcinogen (2,3)

immediate toxicity:

 birds: high (1)

 fish: low (4)

 bees: low to medium (5)

water: “soluble”

highly volatile flammable

transformation product(s):

N-nitrosomethyl-n-butylamine

carcinogen (1,2)

butoxycarboxim

Plant Pin

3-(methylsulphonyl)-2-butanone O-[(methylammino)carbaryl]oxime

CAS # 34681-10-2

carbamate

insecticide

non-pers to mod-pers (1)

oral: high (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: low (2)

water: “soluble”

butoxy polypropylene glycol

Crag Fly Repellent; Stabilene Fly Repellent

polypropylene glycol monobutylether

CAS # 9003-13-8

insect repellent acaricide

?

oral: low (1)

dermal: ?

inhalation: ?

?

water: “slightly soluble”

volatile

butralin

A-820; Amchem 70–25; Amex 820; Sector; Tamex

N-sec-butyl-4-tert-butyl-2,6-dinitrobenzamine; 4-(1,1-dimethylethyl)-N-(1-methylpropyl)-2,6-dinitrobenzamine; N-sec-butyl-2,6-dinitroanaline

CAS # 33629-47-9

dinitroaniline

herbicide

not registered: USA

mod-pers (1)

oral: low to medium (2,3)

dermal: medium (4)

inhalation: low (5)

?

immediate toxicity:

 fish: high (4)

water: slightly soluble

slightly volatile

flammable

butylate

R-1910; Stauffer R-1910; Sutan GR (with atrazine); Sutan Plus; Sutazin (with atrazine); Sutazine + 18–6G

S-ethyl diisobutylthiocarbamate; S-ethyl bis(2-methylpropyl)carbamothiote

CAS # 2008-41-5

thiocarbamate

herbicide

non-pers (1)

oral: low to medium (1)

dermal: low to medium (1)

?

immediate toxicity:

 fish: medium (1)

 bees: low to medium (3)

 aquatic invertebrates: medium (2)

water: slightly soluble

volatile

combustible

104 4,4-bipyridyl

miscellaneous

oral: high (1)

dermal: ?

inhalation: ?

pulmonary toxin (1)

cadmium

Characteristics as a class are given here; variations are indicated for each compound below

CAS # 7440-43-9

metal/mineral

cadmium

fungicide

restricted use in USA

perm

oral: “?”

dermal: ?

inhalation: very high (1)

cumulative (2,3)

kidney damage (4,5)

reduced number and growth of young (6)

immediate toxicity:

 fish: very high (3)

 crustaceans: medium (8)

 molluscs: low to medium (8)

water: “insoluble”

compound(s):

cadmium carbonate

CAS #513-78-0

organic

fungicide

water: “soluble”

cadmium chloride

Caddy; Vi-Cad

CAS # 1018-64-2

inorganic

fungicide

oral: high to very high (1,2)

carcinogen (3)

suspect mutagen (4)

teratogen (5)

suspect fetotoxin (6)

cumulative (13)

suspect neurotoxin (7)

kidney and liver damage (8,9)

testes damage (10)

immunotoxin (11,12)

immediate toxicity:

 crustaceans: low to high (16)

cadmium oxide

CAS # 1306-19-0

inorganic

nematocide

carcinogen (1)

water: “insoluble”

cadmium sebacate

cadmium decanedioate

CAS # 4476-04-4

organic

fungicide

oral: high (1)

dermal: high (1)

cadmium succinate

Cadminate; Kroma-Clor; Ultra-Clor

CAS # 141-00-4

organic

fungicide

oral: medium to high (1,2)

water: very soluble

cadmium sulfate

CAS # 10124-36-4

inorganic

fungicide nematocide

carcinogen (1)

suspect mutagen (1,2)

teratogen (3)

water: “soluble”

calcium

Characteristics are indicted for each compound below

CAS # 7440-70-2

metal/mineral

calcium

perm

compound(s):

calcium chlorate

calcium chlorate

CAS # 5902-95-4

inorganic

herbicide insecticide

oral: medium (1)

heart damage (2)

calcium cyanamide

Cyanamid

cyanide

herbicide

fungicide

oral: medium (1)

105 calcium cyanide

A-Dust; Cyanogas; Degesch Calcium Cyanide A-Dust

CAS # 592-01-8

cyanide

fumigant insecticide rodenticide

restricted use, USA

oral: very high (1)

calcium hypochlorite

chloride of lime

CAS # 7778-54-3

inorganic

fungicide antibiotic algacide

water: soluble

calcium phosphide

inorganic

rodenticide

calcium polysulfide

lime sulphur

CAS # 1344-81-6

metal/mineral

sulfur

fungicide

calcium propionate

organic

fungicide

water: “soluble”

calcium sulfate

anhydrous gypsum; Plaster of Paris

CAS # 7778-18-9

metal/mineral

sulfur

“inert”

carrier

camphor

(1R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one; 2-camphanone

CAS # 76-22-2

botanical

i nsect repellent

?

oral: ?

dermal: ?

inhalation: ?

humans seem more susceptible than other species (1)

liver damage (2)

water: “insoluble” combustible

captafol

Bayleton Triple (with triadimefon & carbendazim); Crisfolatan; Difolatan; Difosan; Folcid; Foltapet (with folpet); Haipen; Merpafol; Mycodifol; Ortho 5865; Sanspor; Sufonimide; Sulfemmide

cis-N-[(1,1,2,2-tetrachloroethyl)thio]-4-cyclohexene-1,2-dicarboximide

CAS # 2425-06-1

phthalate

fungicide

cancelled USA, 1986

non-pers (1)

oral: low (2)

dermal: medium (3)

inhalation: ?

carcinogen (4,5)

suspect mutagen (6.7)

suspect teratogen (6.8)

immediate toxicity:

 fish: very high (10)

 birds: low (9)

 aquatic insects: very high (10)

 crustaceans: very high (10)

water: slightly soluble

captan

Acme Garden Fungicide; Aliette Extra (with fosetyl-al & thiabendazole); Captaf; captane (France); Captanex; D-264 Plus Captan; Drexel Captan; Drexel Captan Plus Molybdenum; Merpan; Orthocide Garden Fungicide; SR 406; Stauufer Captan 80; Voncaptan

N-[(trichloromethyl)thio]-4-cyclohexene

CAS # 133-06-2

phthalate

fungicide

most food crop uses cancelled in USA, 1989

non-pers to mod-pers (1,2)

oral: low (2,3)

dermal: ?

inhalation: ?

carcinogen (4–6)

suspect mutagen (1,7)

teratogen (8)

fetotoxin (1)

immunotoxin (9)

immediate toxicity:

 birds: low to medium (2)

 fish: very high (1)

 earthworms: low to medium (2)

 bees: low (dermal), high (oral) (1,10)

long-term toxicity:

 plants: increased incidence of gall in cherry trees (11)

water: slightly soluble

oil: insoluble

slightly volatile

106transformation product(s):

delta 4 tetrahydrophthalimide

CAS # 85-40-5

suspect fetotoxin (1)

carbanolate

Banol; Sok; U-12927

6-chloro-3,4-xylyl methylcarbamate; 2-chloro-4,5-dimethylphenyl methylcarbamate

CAS # 671-04-5

carbamate

insecticide

?

oral: very high (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 bees: high (2)

carbaryl

Arylam; Bercema NMC50; Carpolin; Crag Sevin; Dicarbam; Dyna-carbyl; Germain’s; Hexavin; Karbatox 75; Menaphtham; Nac; Pomex; Ravyon; Sevin; Sok; Tercyl; Tricarnam; UC 7744; Vioxan; Zrylam

1-naphthyl methylcarbamate; methylcarbamate 1-naphthalenol

CAS # 63-25-2

carbamate

insecticide acaricide mollusicide

non-per to mod-pers (1,2)

oral: medium to high (3)

dermal: ?

inhalation: low

suspect carcinogen (5)

suspect mutagen (6)

teratogen (4)

fetotoxin (6)

suspect viral enhancer (6)

decreased fertility from ovary and testes damage through successive generations (7)

immediate toxicity:

 birds: low to medium (3)

 fish: very high (10)

 bees: “extremely toxic” (6)

 crustaceans: very high (6)

 earthworms: “extremely toxic” (10)

 aquatic worms: high to very high (11)

 aquatic insects: very high (10)

 plants: toxic to some; chromosome damage in some (12)

long-term toxicity:

 birds: may affect breeding success (8,9)

 fish: reduction in sex hormone, may affect reproduction (13); increased vulnerability to predation; affects swimming capacity (14)

water: slightly soluble to soluble

slightly volatile

combustible

transformation product(s):

1-naphthol α-naphthol

CAS # 90-15-3

miscellaneous

oral: high (1)

liver damage (1)

nitrosocarbaryl

from reaction with nitric acid often present in air, soil, saliva when carbaryl is ingested

carcinogen (1)

mutagen (1,2)

carbendazim

BCM; BMC; Carbate; carbendazol; Cekudazim; CTR 6669; Custos; Delsene; Delsene M; Equitdazin; Focal; Hoe 17411; Kemdazin; Lignasan; MBC*; MCB; Pillarstin; Supercarb; Tritocol

2-(methoxycarbonylamino)-benzimidazole; methyl 1H-benzimidazol-2-yl-carbamate; methyl-2-benzimidazole carbamate *MBC also used as a trade name for sodium chlorate

CAS # 10605-21-7

benzimidazole

fungicide

mod-pers

oral: low to medium

dermal: low to medium

inhalation: ?

suspect carcinogen suspect mutagen testes damage

immediate toxicity:

 birds: low

 fish: low to high

 earthworms: “very toxic”

water: slightly soluble

non-volatile

107 carbofuran

Barbodan; BAY 78537; Brifur; Bripoxur; Carma (with isofenphos); Chinufur; Curaterr; D 1221; FM 10242; Furacarb; Furadan; Furadan 15G; Kenofuran; NIA 10242; Yaltox

2,3-dihydro-2,2-dimethyl-7-benzofuranyl methylcarbamate

CAS # 1563-66-2

carbamate

insecticide nematocide acaricide

non-pers to mod-pers (1,2)

oral: high to very high (2,3)

dermal: ?

inhalation: ?

“carbofuran is high toxic by the oral, dermal, and inhalation routes of exposure” (4)

suspect mutagen (3)

immunotoxin (5)

immediate toxicity:

 birds: very high (3,6)

 fish: high to very high (2)

water: soluble

slightly volatile

carbon disulfide

carbon bisulfide

CAS # 75-15-0

metal\mineral sulfur

fumigant insecticide herbicide fungicide rodenticide soil sterilant nematocide

?

oral: ?

dermal: ?

inhalation: “highly poisonous” (1)

neurotoxin (2)

heart damage (3)

fetotoxin (3)

liver damage (3)

kidney damage (3)

thyroid, adrenal changes (3)

water: soluble

highly volatile

flammable

carbon tetrachloride

Granosan (with ethylene dichloride); Necatorina

perchloromethane; tetrachloromethane

CAS # 56-23-5

“susceptibility to carbon tetrachloride poisoning is enhanced by the contemporaneous use of alcohol” (8)

organochlorine

insecticide fumigant

cancelled USA, 1986

?

oral: low to medium (1,2)

dermal: ?

inhalation: low (1)

carcinogen (2,3)

fetotoxin (2)

liver damage (4,5)

eye damage (6)

kidney damage (6)

testes damage (7)

water: “very slightly soluble”

“non-inflammable”

transformation product(s):

phosgene gas

inhalation: “danger period is usually 6 to 24 hours after exposure” (1)

lung damage (2)

water: “slightly soluble”

highly volatile

“nonflammable gas”

carbophenothion

Acarithion; Dagadip; Endyl; Garrathion; Hexathion; Lethox; Nephocarp; R-1303; Stauffer; Trithion

S-[(p-chlorophenylthio)methyl O,O-diethyl phosphorodithioate; O,O-diethyl S-[(p-chlorophenylthio)-methyl]phosphorodithioate

CAS # 786-19-6

organophosphate

insecticide acaricide

?

oral: very high (1)

dermal: high to very high (2)

inhalation: ?

?

immediate toxicity:

 birds: high to very high (3)

 fish: high to very high (4)

 crustaceans: very high (4)

 amphibians: very high (5)

 bees: high (6)

water: slightly soluble

volatile

carboxin

Arrest 75W; Ceravax; D 735; DCMO; Kemekar; Pro-Gro; Quinolate V4 X AC, FS, DS (with oxine-copper & anthraquinone; Uniroyal D 735; Vitaflo; Vitavax; Vitavax 100

5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide; 2,3-dihydro-5-carboxanilido-6-methyl-1,4-oxathiin; 5,6-dihydro-2-methyl-1,4-oxathiin-3-carboxanilide

CAS # 5234-68-4

amide

fungicide

non-pers (1,2)

oral: medium to high (3,4)

dermal: low to medium (3)

inhalation: low (1)

?

immediate toxicity:

 birds: low to medium (1,5)

 fish: high (5)

 crustaceans: low (5)

 bees: low (6)

 aquatic insects: low (5)

water: soluble

combustible

108 cartap

Cadan; Caldan; Padan; Patap; Sanvex; T-1258; Vegetox

S,S′-(2-dimethylaminotri methylene)-bis(thiocarbamate); 1,3-bis(carbamoylthio)-2-(N,N-dimethylamino)propane

CAS # 15263-53-3

thiocarbamate

insecticide

?

oral: high (1)

dermal: low to high (2)

inhalation: ?

?

?

CDAA

allidochlor; CP-6343; Limit; Randox

N,N-diallyl-2-chloroacetamide; 2-chloro-N,N-di-2-propenyl-acetamide; α-chloro-N,N-diallylacetamide

CAS # 93-71-0

amide

herbicide

non-pers (1)

oral: medium to high (1,2)

dermal: medium to high (1)

inhalation: ?

?

immediate toxicity:

 fish: medium (1)

water: very soluble

volatile

“nonflammable”

CDEC

sulfallate; Vegadex

2-chloroallyl diethyldithiocarbamate

CAS # 95-06-7

thiocarbamate

herbicide

withdrawn from market by manufacturer in USA & Canada

non-pers (1,2)

oral: medium (3)

dermal: ?

inhalation: ?

carcinogen (4)

immediate toxicity:

 birds: low (5)

 bees: low to medium (6)

water: soluble

oil: “soluble”

volatile

combustible

transformation product(s):

2-chloroacrolein

suspect mutagen (1)

chloramben

Amchem Garden Weeder; Amiben (ammonium salt of chloramben); Amilon-WP; chlorambene (France); Ornamental Weeder 46; Vegiven (methyl salt of chloramben)

3-amino-2,5-dichlorobenzoic acid

CAS # 133-90-4

miscellaneous

herbicide

non-pers (1)

oral: low (2)

dermal: medium (2)

inhalation: low (3)

suspect carcinogen (3,4)

fetotoxin (5)

liver damage (5)

immediate toxicity:

 fish: low (3)

water: soluble

“nonflammable”

chloranil

G-25804; G-444-E; Spergon; Vulklor

2,3,5,6-tetrachloro-p-benzoquinone

CAS # 118-75-2

quinone

fungicide

cancelled USA, 1977

?

oral: medium (1)

dermal: ?

inhalation: ?

carcinogen (2,3)

water: soluble

slightly volatile

chlorbenside

Chlorocide; Chlorparacide; Chlorsulphacide; Midox; Mitox

p-chlorobenzyl p-chlorophenyl sulfide

CAS # 103-17-3

organochlorine

acaricide

non-pers (1)

oral: low to medium (2)

dermal: ?

inhalation: ?

?

water: soluble

oil: very soluble

slightly volatile

chlorbromuron

Bromex (with naled); C-6313; chlorobromuron (France); CIBA 6313; Maloran

3-(4-bromo-3-chlorophenyl)-1-methoxy-1-methyl urea; N′-(4-bromo-3-chlorophenyl)-N-methoxy-N-methylurea

CAS # 13364-45-7

urea

herbicide

non-pers (1)

oral: low (1)

dermal: medium (1)

inhalation: ?

?

?

109 chlordane

1068; Aspon-chlordane; Belt; Chlor Kil; Chlordan; Corodane; Kypchlor; Niran; Octa-Klor; Octachlor; Ortho-Klor; Synklor; Termide; Topiclor 20; Velsicol 1068

1,2,4,5,6,7,8,8-octachlor-2,3, 3a,4,7a-hexahydro-4,7-methanoindane (technical chlordane is a mixture of chlorinated hydrocarbons consisting of isomers of chlordane and closely related compounds and byproducts)

CAS # 57-74-9

organochlorine

insecticide

fire ant control in power plants only use of chlordane/heptachlor permitted in USA, 1988

mod-pers to pers (1–3)

oral: medium to high (4)

dermal: ?

inhalation: “hazardous by inhalation” (5)

cumulative (2)

carcinogen (6)

suspect mutagen (1)

liver damage (7)

testicular damage (8)

affects hormone levels (9)

neurotoxin (2)

blood damage (10)

immediate toxicity:

bird: medium to very high (12)

 fish: high to very high (4,13)

 crustaceans: high to very high (4,13)

 aquatic insects: very high (13)

long-term toxicity: tendency to bioaccumulate in certain food chains (14)

water: insoluble

oil: very soluble

slightly volatile

contaminant(s):

hydrogen chloride

hydrochloric acid

hydrogen chloride

CAS # 7647-01-0

oral: low (1)

phosgene gas

(see carbon tetrachloride)

hexachlorocyclopentadiene

carbon monoxide

can potentiate cardiovascular stress in diseased heart (1,2)

brain damage (3)

transformation product(s):

oxychlordane

1-exo,2-endo,4,5,6,7,8,8-octachloro-2,3-exo-epoxy-2,3,3a,4,7,7a-hexahydro-4,7-methanoindene

oral: very high (1)

more toxic than chlordane (1)

most cumulative of all chlordane derivatives, often found in human fatty tissue (2)

nonachlor

also component of technical grade chlordane

often found in human adipose tissue (1)

heptachlor

(see heptachlor)

chlordecone

Black Flag Ant Trap; GC 1189; Kepone; Tat Ant Trap

1,1 a,3,3a,4,5,5,5a,5b,6-decachloro-octachloro-1,3,4-metheno-2H-cyclobutano(cd) pentalen-2-one

CAS # 143-50-0

organochlorine

insecticide acaricide fungicide

cancelled USA, 1977

pers (1)

oral: high (2,3)

dermal: high (4)

inhalation: ?

cumulative (5,6)

carcinogen (7,8)

suspect fetotoxin (9,10)

liver damage (6)

neurotoxin (11)

reproductive ability

decreased (12)

suppresses pituitary cell hormones (13)

testicular atrophy (17)

immediate toxicity:

 birds: high (14)

 fish: very high (15)

 bees: medium (16)

long-term toxicity:

 birds: affects reproduction (15)

 fish: abnormal bone development (16)

water: “slightly soluble”

110 chlordimeform

Acaron; Bermat; chlorphenamidine; CIBA 8514; EP-333; Fundal 500; Fundal Forte (with formetanate hydrochloride); Fundex; Galecron; Ovatoxion; RS141; Schering 36268; Spanon; Spanone

N, N-dimethyl-N′-(2-methyl-4-chlorophenyl)-formamidine; N-(4-chloro-2-methylphenyl)-N,N-dimethyl formamidine

CAS # 6164-98-3

amide

insecticide acaricide

cancelled USA, 1989

non-pers (1)

oral: high (1)

dermal: medium to high (1,2)

inhalation: high (3)

carcinogen (1)

immediate toxicity:

 bees: “nontoxic” (4)

 fish: medium to high (4)

water: soluble

slightly volatile

transformation product(s):

4-chloro-o-toluidine

carcinogen (1)

N-formyl-chloro-o-toluidine

carcinogen (1)

chlorfenethol

BCPE; DCPC; DCPE; Dimite; DMC; Milbex; Qikron

4,4′-dichloro-α-methylbenzhydrol; 1,1-bis(4-chlorophenyl)ethanol; 4-chloro-α-(4-chlorophenyl)-α-methylbenzenemethanol

CAS # 80-06-8

organochlorine

acaricide

?

oral: medium (1)

dermal: ?

inhalation: ?

“effects similar to DDT” (2)

water: “practically insoluble”

chlorfenson

C-106; chlorofenizon; CPCBS; difenson; ephirsulphonate; Estonmite; Genite 883; K-6451; Lethalaire G-58; Mitran; Orthotran; Ovex; Ovochlor; Ovotox; Ovotran C-854; PCPCBS; Trichlorfenson

4-chlorphenyl 4-chlorobenzenesulphonate

CAS # 80-33-1

miscellaneous

acaricide

cancelled USA

?

oral: medium (1,2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: medium (3)

water: “insoluble”

oil: very soluble

chlorfensulphide

Micasin

4-chlorophenyl 2,4,5-trichlorophenylazosulphide

CAS # 2274-74-0

metal/mineral sulfur

acaricide

?

oral: medium (1)

dermal: ?

inhalation: ?

?

water: “practically insoluble”

oil: “soluble in petroleum solvents”

chlorfenvinphos

Apachlor; Birlane; C 8949; CFV; CGA 26351; Compound 4072; Sapecron; SD 7849; Steladone; Supona; Unitox; Vinylphate

2-chloro-1-(2,4-dichlorophenyl)vinyl diethylphosphate; 2,4-dichloro-α-(chloromethylene)benzyl diethyl phosphate

CAS # 470-90-6

organophosphate

insecticide acaricide

non-pers to mod-pers (1,2)

oral: high to very high (2,3)

dermal: high to very high (2,4)

inhalation: ?

?

immediate toxicity:

 birds: high (5)

 fish: high (4)

water: soluble

slightly volatile

“nonflammable”

chlorfluazuron

CGA 112913; CGA 913; IKI-7899; UC-62644

1-[3,5-dichloro-4-(3-chloro-5-trifluoromethyl-2-pyridiloxy)phenyl]-3-(2,6-difluorobenzoyl) urea

CAS # 71422-67-8

urea

insect growth regulator

?

oral: low (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: low (1)

water: insoluble

111 sodium dichloroisocyanurate

1,3-dichloro-s-triazine-2,4,6(1H,3H,5H) trione sodium salt

CAS # 2893-78-9

sodium dichloroisocyanurate dihydrate

ACL 56; CDB Clearon; DICD

1,3-dichloro-s-triazine-2,4,6(1H,3H,5H) trione sodium salt dihydrate

CAS # 51580-86-0

trichloroisocyanuric acid

ACL 90; CDB 90; Plus; T.I.C.A.; TCCA

trichloro-s-triazinetrione; trichloroisocyanurate

CAS # 87-90-1

immediate toxicity:

 birds: medium (1)

 fish: high (1)

 crustaceans: high to very high (1)

chlorinated isocyanurates

triazine

fungicide aigacide

cancelled, most uses, USA

?

oral: “low” (1)

dermal: “low” (1)

inhalation: ?

kidney and urinary tract stone formation (1)

?

compound(s):

dichloroisocyanuric acid

ACL 70

1,3-dichloro-s-triazine-2,4,6(1H,3H,5H) trione; dichloro-s-triazinetrione

CAS # 2782-57-2

penta-s-triazinetrione

ACL 66; DS

[Mono-(1,3,5-trichloro) tetra(1-potassium-3,5-dichloro] penta-s-triazinetrione

CAS # 30622-37-8

potassium dichloroisocyanurate

ACL 59; P.D.I.C.

1,3-dichloro-s-triazine-2,4,6(1H,3H,5H) trione potassium salt

CAS # 2244-21-5

chlorflurecol

CF 125; chlorflurecol-methyl (USA, Gr. Britain); chlorflurenol (not to be confused with chlorofluorenol); chlorflurenol-methyl; Curbiset; IT 3456; Maintain; Maintain CF 125

methyl 2-chloro-9-hydroxyfluorene-9-carboxylate; methyl 3-chloro-9-hydroxyfluorene-9H-carboxylic acid

CAS # 2536-31-4

miscellaneous

herbicide

non-pers (1)

oral: low to medium (1,2)

dermal: medium (1)

inhalation: ?

?

immediate toxicity:

bird: low (1)

 fish: medium (1)

bee: “nontoxic” (2)

water: slightly soluble

oil: soluble

slightly volatile

flammable

112 chlorimuron

Canopy (with metribuzin); Classic; DPX-F6025; Gemini (with linuron)

2-[[[[(4-chloro-6-methoxyprimidin-2-yl)amino]carbonyl]amino]sulfonyl]benzoate

CAS # 90982-32-4

urea

herbicide

non-pers (1)

oral: medium (1)

dermal; ?

inhalation: low to medium (1)

?

immediate toxicity:

 birds: low to medium (1)

 fish: low (1)

 crustaceans: low (1)

water: slightly soluble

non-volatile

chlorine

chloor (Durch); Chlor (German); chlore (French); cloro (Italian)

chlorine

CAS # 7782-50-5

miscellaneous

algaecide antibiotic fungicide

?

oral: ?

dermal: “causes burns” (1)

inhalation: “low” (2)

erosion of teeth (2)

BIOCIDE

immediate toxicity:

 fish: very high (3)

 crustaceans: very high (3)

 aquatic insects: very high (3)

 aquatic worms: high (3)

 molluscs: very high (3)

 amphibians: medium (3)

phytoplankton: high to very high (3)

long-term toxicity:

 crustaceans: decreased reproduction (3)

 fish: disequilibrium (4,5)

“reacts explosively or forms explosive compounds with many common substances”

water: soluble

highly volatile

contaminant(s):

hexachlorobenzene

(see hexachlorobenzene)

transformation product(s):

chloroform

(see chloroform)

chlormephos

Dotan; MC 2188

S-(chloromethyl) O,O-diethyl phosphorodithioate

CAS # 24934-91-6

organophosphate

insecticide

non-pers (1,2)

oral: very high (1)

dermal: very high (1)

inhalation: ?

?

immediate toxicity:

 bees: “toxic” (1)

 birds: high (1)

 fish: high (3)

water: slightly soluble

volatile

chlormequat

2-chloroethyl-N,N,N-trimethylammoniumion

CAS # 7003-89-6

bypiridyl

growth regulator

“persists in soil less than one season” (1)

oral: medium (2)

dermal: ?

inhalation: low to medium (2)

?

immediate toxicity:

 birds: medium (2)

 fish: low (2)

 molluscs: low (2)

 crustaceans: medium (2)

“non-volatile”

salt(s):

chlormequat chloride

Arotex-extra; Barleyquat-B; Bettaquat-B; CCC; CeCeCe; chlorocholine chloride; Cycocel; Cycocel-Extra; Cycogan Extra; Cycogen; Ethanaminium; Farmacel; Hico CCC; Hormocel; Lihocin; Minc; Nainit; Padquat; Titan

2-chloroethyl-N,N,N-trimethylammonium chloride

CAS #991-81-5

113 chlorobenzilate

Acaraben; Akar; Benz-O-Chlor; Benzilan; Compound 338; Folbex; G 23992; Geigy 338; Kop-Mite

ethyl 4,4′-dichlorobenzilate

CAS # 510-15-6

organochlorine

acaricide

restricted USA, 1979

non-pers (1)

oral: medium (2)

dermal: ?

inhalation: low (1)

carcinogen (3,4)

testes damage (1,4)

immediate toxicity:

 birds: low (1)

 fish: high (1)

 bees: low (5)

water: slightly soluble

slightly volatile

chlorofluorocarbons

Freon Genetron

1,2-dichloro-1,1,2,2-tetrafluorethane

CAS # 76-12-0

miscellaneous

aerosol propellant

almost all pesticide uses banned, USA

?

oral: ?

dermal: ?

inhalation: low (1)

see piperonyl butoxide (1)

long-term toxicity:

reduction in protective ozone layer in earth’s stratosphere, producing a global increase in ultraviolet radiation at the earth’s surface; increase in skin cancers and mutation rates; may also cause climate changes

transformation product(s):

chlorine

(see chlorine)

phosgene gas

(see carbon tetrachloride)

chloroform

trichloromethane; formyl trichloride

CAS # 67-66-3

organochlorine

acaricide insecticide fumigant

?

oral: medium to very high (1,2)

dermal: ?

inhalation: very high (3)

carcinogen (2,4,5)

mutagen (6)

fetotoxin (2,4)

neurotoxin (7,8)

liver damage (3,7)

kidney damage (2)

lung,thyroid and bladder damage (5)

water: soluble

highly volatile

“nonflammable”

transformation product(s):

phosgene gas

(see carbon tetrachloride)

chloroneb

chloronebe (France); Demosan (with thiram); Soil Fungicide 1823; Teremec; Terraneb; Tersan SP Turf Fungicide

1,4-dichloro-2,5-dimethoxybenzene

organochlorine

fungicide

mod pers to pers (1)

oral: low to medium (1,2)

dermal: ?

inhalation: low (1)

kidney and liver damage (1)

blood cell, spleen, and bone marrow damage (1)

immediate toxicity:

 birds: low (1)

 fish: medium (1)

 crustaceans: medium (1)

water: slightly soluble

volatile

transformation product(s):

TCDD

2,3,7,8-tetrachlorodibenzo-p-dioxin

CAS # 1746-01-6

dibenzo-dioxin

mod-pers to perm (1,2)

oral: very high (2,3)

dermal: very high (2)

inhalation: ?

cumulative (4,5)

carcinogen (4,6)

suspect mutagen (7)

teratogen (8,9)

chloracne (2,7)

thymic atrophy (10,11)

hirsutism (7)

affects vitamin A Balance in liver & kidney (12,13)

immediate toxicity:

 birds: very high (14)

 amphibians: very high (2)

water: insoluble

oil: slightly soluble

slightly volatile

114 chlorophacinone

Actosin C; Afnor; Caid; Delta; Drat; Lepit; Liphadione; LM 91; Microzul; Muriol; Partox; Quick; Ramucide; Ranac; Ratomet; Raviac; Ravicac; Rozol; Topitox

2-(α-p-chlorophenyl-α-phenylacetyl)-indane-1, 3-dione;

2-((p-chlorophenyl)phenylacetyl)-1,3-indandione;

2-[(4-chlorophenyl)phenylacetyl]-1.3-indandione

CAS # 3691-35-8

indandione

rodenticide

?

oral: very high (1)

dermal: high to very high (2)

inhalation: ?

?

immediate toxicity:

 birds: high (2)

water: “sparingly soluble”

oil: “soluble”

“nonflammable”

chloropicrin

Acquinite; Aquinite; Chlor-O-Pic; Dojyopicrin; Dolochlor; Dowfume MC 33; G-25; Larvacide; Niklor; Nitrochloroform; Pic-Clor; Picfume; Fieride; PS; S-1; Tear Gas; Terr-O-Gas (with methyl bromide); Triclor; Vomiting GAs; Vorlex 201

trichloronitromethane

CAS # 76-06-2

organochlorine

fumigant

?

oral: high (1)

dermal: ?

inhalation: high (1)

suspect mutagen (2)

anemia (3)

irregular heartbeat (3)

recurrent asthma (3)

water: slightly soluble

highly volatile

“nonflammable”

chloropropylate

Acaralate; Chlormite; G 24163; Rospin

isopropyl 4,4′-dichlorobenzilate

CAS # 5836-10-2

organochlorine

acaricide

discontinued, USA

?

oral: medium (1)

dermal: low to medium (2)

inhalation: ?

?

immediate toxicity:

 fish: low (4)

 bees: low to medium (5)

water: slightly soluble

slightly volatile

chlorothalonil

Blazon; Bravo; Bravo C/M; Bravocarb (with carbendazim); chlorthalonil; Clortocar Ramato; Clortosip (with copper oxychloride & maneb); Dacobre; Daconil 2787; Exotherm; Exotherm Termil; Forturf; Nopocide; Termil

tetrachloroisophthalonitrile

CAS # 1897-45-6

benzonitrile

fungicide

mod-pers (1,2)

oral: low (3)

dermal: low to medium (3)

inhalation: high (3)

carcinogen (4,5)

hyperexcitability (5)

skin damage (6)

eye damage (7)

kidney damage (5)

immediate toxicity:

 birds: low to medium (1)

 fish: very high (1)

 bees: low (9)

“aquatic organisms”: very high (1)

 plants: toxic to some (10)

water: insoluble

oil: slightly soluble

slightly volatile

transformation product(s):

4-hydroxy-2,5,6-trichloroisophtalonitrile

anemia (1)

immediate toxicity:

 birds: medium (1)

chloroxuron

Aitkens Lawn Sand Plus (with ferrous sulfate); Ashlade D-Moss (with ferrous sulfate); C-1983; chloroxifenidim; Norex; Tenoram

3-[p-(p-chlorophenoxy)phenyl]-1,1-dimethylurea

CAS # 1982-47-4

urea

herbicide

mod-pers (1)

oral: low (1)

dermal: medium (2)

inhalation: ?

?

immediate toxicity:

 birds: low to medium (3)

 fish: low to medium (1)

 bees: low (4)

water: slightly soluble

non-volatile

nonflammable

115 chlorphoxim

BAY SRA 7747; Baythion C

2-chloro-α-[(diethoxyphosphinothioyloxyimino)-phenylacetonitrile;O-diethyl phosphorothioate

CAS # 14816-20-7

organophosphate

insecticide; acaricide

?

oral: low to medium (1)

dermal: low to high (1)

inhalation: ?

?

water: slightly soluble

slightly volatile

chlorpropham

Beet Kleen (with fenuron & propham); Chloro-IPC; Chlorpropham; chlorprophame (France); CICP; CIPC; Faso Wy-Hoe; Furloe; Herbon Yellow (with fenuron); Jack Wilson Chloro 51; Morlex (with fenuron & ethofumesate & propham); Preweed; Sprout Nip; Spud-Nic; T-H Klean Drop; Taterpex; Triherbide-CIPC; Y-3 isopropyl m-chlorocarbanilate; isopropyl N-(3-chlorophenyl)carbamate

CAS # 101-21-3

carbamate

herbicide

mod-pers (1)

oral: medium (2)

dermal: medium (1)

inhalation: low (1)

decreased body weight (3)

immediate toxicity:

 birds: low to medium (3)

chlorpyrifos

Dowco 179; Dursban; Lepister (with flucythrinate); Lorsban; Pyrinex; Salut (with dimethoate)

O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate

CAS # 2921-88-2

organophosphate

insecticide

mod-pers (1)

oral: medium to high (1,2)

dermal: medium to high (3,4)

inhalation: high (6)

cumulative (13,14)

fetotoxin (6)

delayed neurotoxin (7)

bulls: sterility and impotence (8)

BIOCIDE

immediate toxicity:

 birds: high to very high (1,9)

 molluscs: very high (1)

 fish: very high (1)

 amphibians: low to high (2)

 crustaceans: very high (1)

 bees: very high (10)

 aquatic insects: very high (1)

long-term toxicity:

 birds: leg weakness (1); delayed neurotoxicity (11)

 fish: affects growth (1)

 crustaceans: affects reproduction & equilibrium (1)

 plants: toxic to some (12)

water: slightly soluble

slightly volatile

contaminant(s):

sulfoTEPP

(see sulfoTEPP)

transformation product(s):

pyridinol

3,5,6-trichloro-2-pyridinol

slightly volatile

chlorsulfuron

DPX-W4189; Finesse; Glean; Glean 20DF; Glean T; Glean TP; Telar

2-chloro-N-[(4-methoxy-1,3,5-triazin-2-yl)aminocarbonyl]benzenesulfonamide

CAS # 64902-72-3

urea

herbicide

non-pers to mod-pers (1)

oral: low (2)

dermal: medium (2)

inhalation: low to medium (1)

?

immediate toxicity:

 birds: low to medium (1)

 fish: low (1)

water: soluble “slightly volatile”

“nonflammable”

116 cholecalciferol

Quintox; Rampage; Vitamin D3

9,10-Seocholestra-5,7,10(19)-t rein-3 betaol; activated 7-dehydro-colesterol; oleovitamin D3

CAS # 434-16-2

miscellaneous

rodenticide

?

oral: very high (1)

dermal: ?

inhalation: ?

arterial damage (2)

immediate toxicity:

 birds: “low” (3)

water: “insoluble”

oil: “soluble”

transformation product(s):

calcitriol

teratogen (1) fetotoxin (1)

cinmethylin

Argold; Cinch

exo-1-methyl-4-(1-methylethyl)-2-[(2-methylphenyl)methoxy]-7-oxabicyclo[2.2.1]heptane

CAS # 87818-31-3

miscellaneous

herbicide

mod-pers (1)

oral: medium (2)

dermal: low to medium (1)

inhalation: ?

?

water: slightly soluble

slightly volatile

combustible

citronella

Ceylon citronella oil; Java citronello oil; oil of citronell

Ceylon: mixture of 60% geraniol, 15% citronellal, 10–15% camphene & diphenthene;

Java: mixture of 25–50% citronellal, 25–45% geraniol

CAS # MX8000-29-1

oil

insect repellent

?

?

?

water: “not soluble” to “slightly soluble”

combustible

clofentezine

Acaristop; Apollo; Apolo; NC-21314; Panatac; Torero (with tau-fluvalinate); Viktor (with fenpropathrin)

3,6-bis(2-chlorophenyl)-1,2,4,5-tetrazine

CAS # 74115-24-5

miscellaneous

acaricide

mod-pers (1)

oral: low to medium (2)

dermal: low to medium (2)

inhalation: ?

?

immediate toxicity:

 birds: low (3)

 fish: low to high (3,4)

water: insoluble

non-volatile to slightly volatile

clomazone

Command; Commence (with trifluralin); Dimethazone; Fenoxan; FMC-57020; Gamit; Merit

2-[(2-chlorophenyl)methyl]-4,4-dimethyl-3-isoxazolidinone

CAS # 81777-89-1

miscellaneous

herbicide

non-pers to mod-pers (1,2)

oral: medium (1/3)

dermal: low to medium (3)

inhalation: medium (3)

?

immediate toxicity:

 birds: low to medium (1/4)

 fish: low to medium (1,4)

 aquatic insects: medium (1)

 crustaceans: medium to high (1)

 molluscs: medium (5)

water: soluble

volatile

combustible

clopyralid

3,6-DPA; Benazolox (with benazolin); Curtail (with 2,4-D); Dowco 290; Format; Kerb Mix Matrikerb (with pronamide); Lontrel (with 2,4-D); Lontrel Plus (with mecoprop & dichlorprop & MCPA); Mayclene (with dichlorprop & MCPA); Reclaim; Stinger

3,6-dichloro-2-pyridine carboxylic acid; 3,6-dichloropicolinic acid

CAS # 1702-17-6

miscellaneous

herbicide

non-pers to mod-pers (1)

oral: medium to high (1)

dermal: low to medium (1)

inhalation: ?

?

immediate toxicity:

 fish: low (2)

slightly volatile

flammable to combustible

117 CNP

chlornitrofen; MC 1478; MO; Mo-338

2,4,6-trichlorophenyl-4-nitrophenyl ether

CAS # 1836-77-7

phenoxy

herbicide

?

oral: low (1)

dermal: low to medium (1)

inhalation: ?

?

immediate toxicity:

 fish: low (1)

water: insoluble

copper

Characteristics as a class are given here; variations are indicated for each compound below

CAS # 7440-50-8

metal/mineral

copper

perm

oral: ?

dermal: ?

inhalation: ?

?

?

compound(s):

basic copper carbonate

Bremen blue; Bremen gree; Cobredon;

Copophos; Kop Karb; Malachite; Nutra-Spray

Basic Copper Carbonate

cupric carbonate;

copper carbonate hydroxide;

cupric subcarbonate

CAS # 12069-69-1

organic

fungicide

oral: high (1)

immediate toxicity:

 fish: “toxic” (1)

water: “insoluble”

basic copper chloride

inorganic

oral: medium (1)

“irreversible eye damage” (2)

immediate toxicity:

 fish: high (3)

water: “insoluble”

“corrosive”

basic cupric acetate

cupric subacetate

CAS # 142-71-2

organic

fungicide

oral: medium (1)

water: “soluble”

Bordeaux mixture

Bor-Dax; Copper Hydro Bordo; FT 2M (with mancozeb); Fungi-Bordo mixture of calcium hydroxide and copper sulfate (see these separate listings)

CAS # 8011-63-0

copper

fungicide

water: “insoluble”

chromated copper arsenate

(see arsenic)

copper ammonium carbonate

Cal Cop 1-; Copper-Count-N; For-Cop-80NC; K-Cop Sol Kop 10; Taytox

CAS # 33113-08-5

organic

fungicide antibiotic

“long lasting once applied to the crop” (1)

immediate toxicity:

 fish: “toxic to fish” (1)

water: “readily soluble” to very soluble

copper ammonium sulfate

inorganic

immediate toxicity:

 fish: medium to very high (1)

copper bis(3-phenylsalicylate)

bis(2-hydroxyl[1,1′-biphenyl]-3-carboxylato-O,O)copper; bis(3-phenylsalicylato)copper; copper-3-phanyl salicylate

CAS # 5328-04-1

organic

fungicide

oral: medium (1)

water: “practically insoluble”

oil: very soluble

“non-volatile”

copper carbonate

organic

fungicide

water: “practically insoluble”

118 copper chelate

organic

herbicide algacide

oral: medium (1)

immediate toxicity:

 fish: medium to high (1)

 crustaceans: low (1)

water: “soluble”

oil: “insoluble”

highly volatile “nonflammable”

copper citrate

Cuprocitrol

2-hydroxyl-2,3-propanetricarbo xylic acid copper salt;

cupric citrate

CAS # 10402-15-0

organic

algacide

antibiotic

copper ethylenediamine complex

Komeen

organic

herbicide

immediate toxicity:

 fish: low to high (1)

water: “soluble”

“nonflammable”

copper hydroxide

Blue Shield; Champion; Comae Parasol; Criscobre; Cudrox; Cuidrox; Cupravit Blue; Kocide; Kocide 101; Kocide 404S; Parasol

copper (II) hydroxide;

cupric hydroxide;

hydrated cupric oxide

CAS # 20427-59-2

inorganic

antibiotic

fungicide

oral: medium (1)

“causes irreversible eye damage” (2)

immediate toxicity:

 birds: low to medium (1)

 fish: low to high (1)

water: slightly soluble

copper linoleate

Citcop; Cop-O-cide; Copoloid; Gro-Tone Liquid; Knew; TC-90

copper salts of fatty and rosin acid. 20 - 25% copper abietate, 8 - 12% copper linoleate and copper oleate

organic

fungicide

voluntary cancellation by producer, USA

“relatively low toxicity” (1)

immediate toxicity:

 fish: “toxic to fish” (1)

water: insoluble to slightly soluble

oil: “soluble”

copper napthenate

Cop-R-Nap; Copper-Cure; Coppernate; Cuprinol Brown; Cuprinol Green; Curpinol; NCN; Tryosan; Tuscopper

copper salt of napthenic acid

CAS # 1338-02-9

organic

fungicide insecticide

oral: low to very high (1,2)

dermal: low to medium (3)

water: “soluble”

oil: very soluble

? volatile

“flammable”

copper nitrate

CAS # 3251-23-8

inorganic

fungicide

copper oxalate

CAS #814-91-5

organic

bird repellent

water: “practically insoluble”

copper oxide

Caocobre; Copox; Copper-Sandoz; Copper-Sardez; Cuprocide; Fungi-Rhap; Kuprite; Nordox; Oleocuivre; Perecot; Perenox; Triangle*; Yellow Cuprocide

brown copper oxide;

cuprous oxide;

dicopper oxide

*see Bordeaux mixture

CAS # 1317-39-1

inorganic

fungicide

developed to replace Bordeaux mixture

oral: medium to high (1,2)

immediate toxicity:

 fish: low (2)

 bees: “harmless to bees” (3)

water: “insoluble”

119 copper oxychloride

Atacamite; BASF-Grunkupfer; Blitox; Colloidox; Cop Tox; Cophamate; Cos; Coxysan; Cupravit; Cuprin; Cuprocaffaro; Cuprosan Blue; Ferncot; Fytolan; Kauritil; Kilex; Micropcop; Perecol; Recop; Rhodioacuivre

basic copper chloride;

basic cupric chloride;

copper (II) chloride oxide hydrate;

dicopper chloride trihydroxide;

oxychlorure de cuivre

CAS # 1332-40-7

inorganic

fungicide

oral: medium (1)

“irreversible eye damage” (2)

immediate toxicity:

 fish: high (3)

water: “insoluble”

copper oxychloride sulfate

Capro 57; Copro 53; Coxysul; CS-56

CAS # 8012-69-9

inorganic

fungicide

“causes substantial but temporary eye injury” (1)

immediate toxicity:

 bees: low to medium (2)

copper sulfate

Blue Copperas; Blue Vitriol; Bluestone; Copace-E; Copperfine-Zinc; Foltimil (with folpet); Neutrocrop; Nu-Cop; Phyton 27; Spray-Cop; Triangle*

basic copper sulfate;

copper sulfate monohydrate;

copper sulfate pentahydrate

*See Bordeaux mixture

CAS # 7758-98-7

inorganic

fungicide herbicide algacide

oral: medium to high (1,2)

dermal: low to medium (2)

inhalation: low to high (2)

mutagen (4,5) “bioaccumulates” (3)

immediate toxicity:

 fish: low to very high (1,2)

 bees: “toxic”

 crustaceans: low (2)

 molluscs: medium (2)

copper sulfate monohydrate

inorganic

fungicide

immediate toxicity:

 fish: “toxic to fish” (1)

copper tea complex

Algae-Rhap CU; K-Pool; K-Tea

copper triethanolamine complex

organic

algacide

herbicide

immediate toxicity:

 fish: medium (1)

water: soluble

copper zinc chromate

Crag Fungicide 658; Experimental Fungicide 658

inorganic

fungicide antibiotic

water: “practically insoluble”

cupric hydrazinium sulfate

Mathieson 466; Omazene; Omazine copper (II) dihydrazinium disulfate; bis(hydrazine)bis(hydrogensulf ato)copper; copper dihydrazine disulfate

CAS # 33271-65-7

organic

fungicide

oxine-copper

Bioquin; Copper 8; Copper Oxinate;

Cunilate 2472; Cuproquin; Dokirin;

Dormycin; Fruitdo; Milmer 1; Quinolate;

Quinolate 15; Quinolate 20; Quinolate AC, Fs, Quinolate AC Kara (with anthraquinone);

Quinolate MG SAFI (with endosulfan & lindane); Quinolate Triple Kara (with anthraquinon & lindane); Quinolate V 4 X AC, FS, DS (with anthraquinone & carboxin);

Quinolate V 4 X Triple (with lindane);

Tomo-oxiran

CAS # 10380-28-6

organic

fungicide wood preservative

oral: low to medium (1)

suspect mutagen (2)

immediate toxicity:

 fish: high (3)

water: “insoluble”

“non-volatile”

120 zinc coposil

BSZ; Citrusperse; Cop-O-Zinc

a combination of basic copper sulfate and basic zinc sulfate or zinc oxide

inorganic

fungicide

used as a safener with lead arsenate

immediate toxicity:

 fish: “toxic to fish” (1)

coumafuryl

Foumarin; Fumasol; Furmarin; furmarin (U.K., New Zealand); Kill-Ko-Rat; Krumkil; Lurat; Mouse Blues; Rat-A-Way; Ratafin; tomarin (Turkey)

3-(α-(2-acetonylfurfury)-4-hydroxycoumarin; 3-[1-(2-furanyl)-3-oxobutyl]-hydroxy-2H-1-benzopyran-2-one;

4-hydroxy-3-[3-oxo-1-(2-furyl)butyl]coumarin

CAS # 117-52-2

coumarin

rodenticide

?

oral: very high (1)

dermal: ?

inhalation: ?

?

water: “slightly soluble”

salt(s):

sodium salt of coumafuryl (Fumasol)

water: “very soluble”

coumaphos

Agridip; Asuntol; BAY 21/199; Baymix; Co-Ral; diolice; Meldane; Muscatox; Perizin; Resistox; Umbethion

O,O-diethyl O-3-chloro-4-methyl-2-oxo-2H-1-benzopyran-7-yl phosphorothioate

CAS # 56-72-4

organophosphate

insecticide

“do not use before or after the application of natural or synthetic pyrethrins or compounds used to synergize them”

?

oral: very high (1)

dermal: high (1)

inhalation: high (1)

?

immediate toxicity:

 birds: very high (3)

 fish: very high (4)

 aquatic insects: very high (4)

 crustaceans: very high (4)

long-term toxicity:

 birds: delayed neurotoxicity (5)

water:

slightly soluble

oil: “slightly soluble”

slightly volatile

4-CPA

Fruitone; Marks 4-CPA; PCPA; Tomato Fix; Tomato Hold; Tomatotone

(4-chlorophenoxy)acetic acid; (p-chlorophenoxy)acetic acid; parachlorophenoxyacetic acid

CAS # 122-88-3

organochlorine

plant growth regulator

non-pers (1)

oral: ?

dermal: ?

inhalation: ?

“chemically related to 2,4-D and exhibits similar acute toxicity in laboratory animals” (2)

?

immediate toxicity:

 fish: low (1)

water: “very soluble”

transformation product(s):

phenol

(see phenol)

credazine

H-722; Kusakira; SW-6701; SW-6721

(3-(2-methylphenoxy)pyridazine; 3-o-tolyloxypyridazine

CAS # 14491-59-9

miscellaneous

herbicide

“mod-pers” (1)

oral: medium (1)

dermal: low to medium (1)

inhalation: ?

?

immediate toxicity:

 fish: low (1)

water: soluble

121 creosote (coal tar)

brick oil; coal tar creosote; coal tar oil; creosote oil; creosotum; cresylic creosote; dead oil; naphthalene oil; tar oil

complex mixture of less volatile hydrocarbons, with up to 3% phenolic constituents, obtained from destructive distillation of coal. Over 300 components identified; composition highly variable, depending on coal source and process; most abundant constituent is napthalene: see napthalene

CAS # 8001-58-9

phenol

wood preservative

restricted USA, 1986

?

oral: ?

dermal: ?

inhalation: ?

carcinogen (1,2)

suspect mutagen (2)

lung and liver damage (3)

water: “practically insouble”

combustible

creosote (wood tar)

beach wood creosote; Creasote; wood creosote

mixture: contains chiefly guaiacol (o-methoxyphenol;

CAS # 90051) and creosol (2-methoxy-4-methylphenol;

CAS # 93-56-1) with little or no phenol or cresols obtained from destructive distillation of wood

CAS # 8021-39-4

phenol

wood preservative

restricted USA, 1986

?

oral: medium to very high (1)

dermal: very high (1)

inhalation: medium (1)

suspect mutagen (2)

long-term toxicity:

 fish: carcinogen (3)

water: “insoluble”

oil: “soluble”

cresylic acid

cresols; tricresol

mixture of cresols (methylphenols) obtained from coal tar; usually contains a few percents phenol, and other aromatic compounds depending on grade

CAS # 1319-77-3

phenol

insecticide

fungicide

antibiotic

?

oral: medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: low (2)

highly volatile

combustible

crotoxyphos

Cio-Vap; Ciodrin; Cypon EC; Decrotox; Duo-Kill

1-phenylethyl 3-(dimethoxyphosphinoyloxy)isocrotonate;

1-phenylethyl 3-(dimethoxyphosphinyloxy)isocrotonate;

dimethyl(E)-1-methyl-2-(1-phenylethoxycarbonyl) vinyl phosphate;

(E)-1-phenylethyl 3-[(dimethoxyphosphinyl)oxy]-2-butenoate; α-methylbenzyl(α)-3-hydroxycrotonate ester with dimethyl phosphate

CAS # 7700-17-6

organophosphate

insecticide

?

oral: high (1,2)

dermal: high to very high (1,2)

inhalation: ?

?

immediate toxicity:

 birds: medium to high (3)

 fish: medium to very high (4)

 crustaceans: very high (4)

 bees: high (5) water: soluble

slightly volatile

crufomate

Dowco 132; Kempak; Montrel; Ruelene

4-tert-butyl-2-chlorophenyl methyl methylphosphoramidate

CAS # 299-86-5

organophosphate

insecticide

?

oral: medium to high (1,2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: high (3)

water: “practically insoluble”

oil: “practically insoluble”

cryolite

Koyoside; Kryocide; Prokil

sodium fluoaluminate;

sodium aluminofluoride

CAS # 15096-52-3

metal/mineral

insecticide

?

oral: low (1)

dermal: very high (2)

inhalation: ?

fluoride accumulation in bones (3)

BIOCIDE

immediate toxicity:

 birds: low to medium (3)

 fish: low (4)

 crustaceans: medium (4) 

 bees: low (5)

 plant: damages some crops, especially peaches (6)

water: soluble

122 cyanazine

Bellater (with atrazine); Bladex; Bladotyl (with mecoprop); Blagal (with MCPA); Blazine (with atrazine); Conquest (with atrazine); DW 3418; Extrazine (with atrazine); Fortrol; Holtox (with atrazine); Scogal; SD 15417; Vega (with bentazon & dichlorprop); WL 19805

2-(4-chloro-6-ethyamino-s-triazin-2-ylamino)-

2-methylpropionitrile

CAS # 21725-46-2

triazine

herbicide

restricted USA, 1988

non-pers (1)

oral: high (1)

dermal: low to medium (1)

inhalation: low to medium (2)

teratogen (3)

immediate toxicity:

 birds: low to high (4)

 fish: low to medium (5)

 crustaceans: high (5)

 bees: low (6)

water: soluble

non-volatile

“nonflammable”

cyanophenphos

CYP; S-4087; Surecide

O-p-cyanophenyl O-ethyl phenyl phosphonothioate; O-(4-cyanophenyl) O-ethyl phenyl phosphonothioate

CAS # 13067-93-1

organophosphate

insecticide

?

oral: high to very high (1)

dermal: ?

inhalation: ?

liver damage (2)

immediate toxicity:

 bees: “toxic” (3)

long-term toxicity:

 birds: delayed neurotoxin (4)

water: slightly soluble

slightly volatile

cyanophos

Cyanox; CYAP; Cynock; S-4084

O-4-cyanophenyl O,O-dimethyl phosphorothioate;

4-dimethoxyphosphinothioyloxyl benzonitrile;

O-(4-cyanophenyl) O,O-dimethyl phosphorothioate;

O,O-dimethyl phosphorothioate O-ester with p-hydroxybenzonitrile

CAS # 2636-26-2

organophosphate

insecticide

?

oral: medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: medium (1)

 bees: “toxic to honeybees” (2)

long-term toxicity:

 birds: delayed neurotoxicity (3)

water: slightly soluble slightly volatile

cycloate

Eurex; hexylthiocarbam; R-2063; Ro-Neet; Ronit

S-ethylcyclohexylethylthiocarbamate;

S-ethylcyclohexylethylcarbamothioate;

S-ethyl-N-ethylthiocyclohexanecarbamate

CAS # 1134-23-2

thiocarbamate

herbicide

non-pers (1)

oral: medium (1)

dermal: low to medium (2)

inhalation: ?

?

immediate toxicity:

 birds: low to medium (3)

 fish: medium (1)

 bees: low to medium (4)

water: slightly soluble

volatile

combustible

cyclohexane

hexahydrobenzene;

hexamethylene;

hexanapthene

CAS # 110-82-7

miscellaneous

solvent

?

oral: ?

dermal: ?

inhalation: very high (1)

?

immediate toxicity:

 fungus: “slight fungicidal action”

water: slightly soluble

highly volatile

flammable

123 cyclohexanone

Anone; Hytrol O; Nadone

cyclohexanone; ketohexamethylene;

pimelic ketone

CAS # 108-94-1

miscellaneous

solvent

?

oral: medium (1)

dermal: ?

inhalation: ?

suspect mutagen (1)

water: very soluble

slightly volatile

combustible

cycloheximide

Acti-Aid; Acti-Dione; Acti-Dione BR Concentration; Acti-Dione PM; Acti-Dione RZ (with pentachloronitrobenzene); Acti-Dione TGF; Acti-Dione Thiram (with thiram); Actispray; Hizarocin; Kaken

3[2-(3,5-dimethyl-2-oxocyclohexyl)-2-hydroxyethyl]-glutarimide; naramycin

CAS # 66-81-9

amide

fungicide growth regulator

Acti-dione* voluntarily withdrawn from registration in Canada

non-pers (1)

oral: medium to very high (2,3)

dermal: very high (1)

inhalation: ?

suspect mutagen (4,5)

suspect teratogen (6,7)

immunotoxin (10)

immediate toxicity:

 birds: high to very high (1/8)

 fish: high (1)

 bees: low (9)

cycluron

3-cyclo-octyl-1, 1-dimethylurea

CAS # 2163-69-1

urea

herbicide

?

oral: medium (1)

dermal: ?

inhalation: ?

?

water: soluble

cyfluthrin

Baygon Spray (with dichlorvos & propoxur); Baythroid F (with omethoate); Baythroid TM (with acephate-met); Insectipen; Muscatox (with phoxim)

(RS)-α-cyano-4-fluo ro-3-[phenoxybenzyl (1RS)-cis,trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

CAS # 68359-37-5

pyrethroid

insecticide

non-pers to mod-pers (1)

oral: low to very high (2,3)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: high to very high (1,4)

 crustacean: very high (5)

 bees: high (6)

water: insoluble to slightly soluble

non-volatile to volatile flammable

λ-cyhalothrin

Icone; Karate; OMS 3021; PP 321

λ-cyhalothrin;

α-cyano-3-phenoxybenzyl 3-(2-chloro-3,3,3-trifluropropenyl)- 2,2-dimethylcyclopropanecarboxylate (1:1 mixture of (Z)-(1S,3S)-R-ester and (Z)-(1R,3R) S-ester

CAS # 91465-08-6

pyrethroid

insecticide

non-pers (1)

oral: high (1)

dermal: ?

inhalation: very high (1)

?

immediate toxicity:

 fish: very high (2)

water: insoluble

non-volatile

cymoxanil

Bayleton AN, Curzatem (with triadimefon); Fytospore (with mancozeb)

1-(2-cyano-2-methoxymino-acetyl)-3-ethylurea

urea

fungicide

not registered for use in U.S.

non-pers (1)

oral: medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: medium (1)

water: soluble

cypermethrin

Ammo; Arrivo; Barricade; Cymbush; Cymperator; Cypercopal; cypermethrine; Cyrux; Demon; Fenom; Flectron; Folcord; Imperator; Kafil Super; Nurelle; Polytrin; Ripcord; Siperin; Toppel; Ustaad; WL 43467 (RS)-α-cyano-3-phenoxybenzyl (1RS-cis,trans-3-9 2,2-dichlorovinyl)-2,2-dimethyl-cyclopropanecarboxylate

CAS # 52315-07-8

Pyrethroid

insecticide

non-pers (1)

oral: medium to high (2,3)

dermal: ?

inhalation: ?

mutagen (4,5) immunotoxin (6)

immediate toxicity:

 birds: low (7,8)

 fish: high to very high (1,9)

 crustaceans: very high (10)

 bees: “toxic” (2)

water: insoluble

oil: “lipophilic” non-volatile

124 cyprazine

Outfox; Prefox (with ethiolate); S-6115; S-9115

2-chloro-4-(cyclopropylamino)-6-(isopropylamino)-s-triazine; 6-chloro-N-cyclopropyl- N′-(1-methylethyl)-1,3,5-triazine-2,4-diamine

CAS # 22936-86-3

triazine

herbicide

cancelled USA

?

oral: low to medium (1,2)

dermal: medium (2)

inhalation: ?

lung damage (3)

immediate toxicity:

 birds: medium (6)

 fish: medium (4)

water: slightly soluble

combustible

cyromazine

Larvadex; Trigard

N-cyclopropyl-1,3,5-triazine-2,4,6-triamine

CAS # 66215-27-8

triazine

insect growth regulator

?

oral: medium (1)

dermal: ?

inhalation: medium (1)

suspect fetotoxin (2,3)

immediate toxicity:

 fish: low (1,4)

water: very soluble

slightly volatile

transformation product(s):

melamine

CAS # 108-78-1

oral: medium (1)

carcinogen (1) bladder stones (1)

cythioate

AC 26691; American Cyanamid Cl 26691; Cyflee; Proban*

* Proban is also a trade name for an herbicide, 1-(3,4-dichlorophenyl)-3-isopropyl-3-(2-propenyl)urea, not listed in this guide.

O,O-dimethyl O-p-sulfamoylphenyl phosphorothioate;

p-hydroxybenzenesulfonamide, O-ester with O,O-dimethyl phosphorothioate

CAS # 115-93-5

organophosphate

insecticide

pers (1)

oral: high (2)

dermal: ?

inhalation: ?

?

volatility: “negligible”

2,4-D

Agricorn D; Agrotect; Amidox; Cloroxone; College Brand Weed Killer; Ded-Weed Aero Ester; Demise; Dicotox; Dinoxol; Dymec; Esteron 44; Fersone; Green Cross Amine 80; Hormotox; Lawn-Keep; Lithane; Miracle; Niagara Am Sol; Plantgard; Raid Weed Killer; Weedone

2,4-dichlorophenoxyacetic acid

CAS # 94-75-7

phenoxy

herbicide

restricted USA

non-pers to mod-pers (1,2)

oral: medium to high (2,3)

dermal: high (4)

inhalation: medium to high (5)

carcinogen (6,7)

suspect mutagen (8,9)

teratogen (10,11)

suspect fetotoxin (12)

anorexia (12)

immunotoxin (13)

toxic injury to liver, kidney, & central nervous system (19)

immediate toxicity:

 birds: low to high (5,14)

 fish: low to very high (5,15)

 amphibians: low to medium (5)

 crustaceans: low to very high (5)

 molluscs: medium (11)

 non-target insect: low to high (11)

 bees: low to medium (16)

 soil organisms: low (17)

long-term toxicity:

 birds: can affect egg production (17)

 fish: cumulative (17)

 amphibians: inhibits frog egg development (17)

 crustaceans: may significantly reduce population (17)

 molluscs: reduction in population; cumulative (17)

 plants: leaf malformation (16)

 soil organisms: may inhibit growth (17)

 can favor growth of insects and pathogens (18) 125water: “insoluble” to soluble”

oil: “insoluble”

highly volatile

transformation product(s):

2,7-dichlorodibenzo-p-dioxin

dibenzo-dioxin

carcinogen (1)

slightly volatile

1,3,7-trichlorodibenzo-p-dioxin

(see dibenzodioxin class)

dibenzo-dioxin

1.3.6.8- tetrachlorodibenzo-p-dioxin

1.3.6.8-TCDD

dibenzo-dioxin

water: insoluble

1,3,7,9-tetrachlorodibenzo-dioxin

dibenzo-dioxin

TCDD

(see chloroneb)

2,4-dichlorophenol

dalapon

Basfapon; BH Dalapon; Dalapon-Na; Destral (with 2,4-D & diuron); Dowpon; Gramevin; Lignum (with atrazine); Radapon; Slam (with asulam); Target (with asulam); Unipon

2,2-dichloropropionic acid (and sodium salt)

CAS # 75-99-0

miscellaneous

herbicide

non-pers (1)

oral: low to medium (2)

dermal: low to medium (3)

inhalation: low (2)

?

immediate toxicity:

 birds: low (2)

 fish: low (4)

 bees: low to medium (5)

 crustaceans: medium (4)

 aquatic insects: low (4)

water: very soluble

volatility “negligible” “nonflammable”

daminozide

Alar; Alar-85; Aminozide; B-995; B-nine; DSMA; Kylar; Kylar-85; SAD-85

butanedioic acid mono (2,2-dimethyl hydrazide); succinic acid 2,2-dimethyl hydrazide

CAS # 1596-84-5

miscellaneous

plant growth regulator

cancelled for food crop uses, at request of producer, USA, Nov. 1989

“does not persist in soil” (3)

oral: low (1,2)

dermal: ?

inhalation: low 91)

carcinogen (3,4)

immediate toxicity:

 birds: low (1,2)

 fish: low (1)

 crustaceans: low (5)

 bees: low (6)

water: “soluble” to “slightly soluble” slightly volatile

transformation product(s):

unsymmetrical 1,1-dimethylhydrazine

dimazine; UMDH

asymmetrical dimethyl hydrazine;

1,1-dimethyl hydrazine;

N,N-dimethyl hydrazine

CAS # 57-14-7

miscellaneous

is also rocket-fuel

oral: high (1)

dermal: “corrosive to skin” (1)

carcinogen (2–4)

mutagen (5,6)

highly volatile

dazomet

Basamid; Crag Fungicide 974; Crag Nemacide; DMTT; Micro-Fume; Mylone; N-521; Preservit

126tetrahydro-3,5-dimethyl-2H-l,3, 5-thiadiazine-2-thione; 3,5-dimethyl-2H-l,3,5-thiadiazine-2-thione

CAS # 533-74-4

miscellaneous

herbicide

fungicide

nematocide

non-pers to mod-pers (1,2)

oral: medium to high (3)

dermal: ?

inhalation: medium (3)

liver and kidney damage (6)

immediate toxicity:

 fish: “toxic to fish” (4)

 bee: low to medium (5)

water: soluble

volatile

“nonflammable”

transformation product(s):

carbon disulfide

(see carbon disulfide)

methyl isothiocyanate

(see methyl isothiocyanate)

formaldehyde

(see formaldehyde)

hydrogen sulfide

(see calcium polysulfide)

2,4-DB

Butoxone (with 2,4-D & MCPA); Butoxone SB; Butyrac 118; Butyrac ester; Embutox; Ley-Cornox (with benazolin & MCPA); MB 2878

4-(2,4-dichlorophenoxy) butyric acid

CAS # 94-82-6

phenoxy

herbicide

non-pers (1)

oral: medium (1)

dermal: low to medium (2)

mutagen (2)

immediate toxicity:

 fish: medium (2)

 bees: low to medium (3)

water: slightly soluble

oil: “highly soluble”

salt(s):

2,4-DB sodium

CAS # 10433-59-7

oral: medium to high (1)

transformation product(s):

2,4-D

(see 2,4-D)

DBCP

BBC 1 2; CHA-KEM-CO; dibromochloropropane; Fumazone; Carden Fume; Green Light; Nemafume; Nemagon; Oxy DBCP

1, 2-dibromo-3-chloropropane

CAS #96-12-8

organochlorine

nematocide fumigant

cancelled, most uses, USA, 1977

?

oral: high (1)

dermal: high (1)

inhalation: ?

carcinogen (2,3)

suspect mutagen (4)

testicular damage (5,6)

kidney & liver damage (6)

immediate toxicity:

 birds: high (7)

 molluscs: “high” (7)

 earthworms: “high” (7)

 bees: low (8)

water: soluble

oil: “miscible in hydrocarbon oils”

highly volatile

combustible

DCPA

chlorthal dimethyl; DAC 893; Dacthal; Decimate (with propachlor)

dimethyl tetrachloroterephthalate; dimethyl 2,3,5,6-tetrachloro-1,4-benzenedicarboxylate

CAS # 1861-32-1

phthalate

herbicide

mod-pers (1)

oral: medium (1/2)

dermal: medium (1)

inhalation: ?

suspect carcinogen (3)

suspect mutagen (3)

suspect teratogen (3)

immediate toxicity:

 birds: low to medium (1)

 bees: low (4)

slightly volatile

“nonflammable”

contaminant(s):

TCDD

(see chloroneb)

hexachlorobenzene

(see hexachlorobenzene)

127 D-D

1.2-Dichloropropane with

1.3-dichloropropene

CAS # 8003-19-8

organochlorine

fungicide

herbicide

insecticide

nematocide

soil fumigant

non-pers (1)

oral: high (2) dermal: high (2) inhalation: ?

suspect carcinogen (1.3)

suspect mutagen (1.4)

liver and kidney damage (3,5)

immediate toxicity:

 fish: very high (1)

 crustaceans: very high (1)

water: soluble

highly volatile

flammable

DDD

Rhothane; TDE

dichloro diphenyl dichloroethane; 2,2-bis(p-chloropheny)-1,1-dichloroethane

CAS # 72-54-8

organochlorine

insecticide

cancelled USA,1971

pers; non-pers on plant surfaces (1)

oral: medium to high (2)

dermal: ?

inhalation: ?

cumulative (3)

suspect carcinogen (4,5)

mutagen (6)

atrophy of adrenal cortex (5)

immediate toxicity:

 birds: low to high (7)

 fish: very high

 (8)

 amphibians: very high (5)

 crustaceans: very high (8)

 bees: low (9)

 aquatic insects: very high (8)

water: “practically insoluble”

DDE

dichlorodiphenyl dichloroethylene; 1,1-dichloro-2,2-bis (p-chlorophenyl) ethylene

CAS # 72-55-9

organochlorine

insecticide

pers (1)

oral: medium (2) dermal: ? inhalation: ?

cumulative (3) carcinogen (4,5)

immediate toxicity:

 fish: very high (6)

 bees: low to medium (7)

long-term toxicity:

 birds: embryo mortality in ducks; cumulative (8,9); eggshell thinning (10)

water: insoluble oil: “fat soluble”

DDT

Anofex; Arkotine; Chlorophenothane; Dedelo; Diamekta 50%; Didimac; Dinocide; Genitox; Gesapon; Gesarex; Gyron; Ixodex; Kopsol; Neocidol; Pentachlorin; Pentech; Rukseam; Santobane; Tech DDT; Zerdane

dichloro diphenyl trichloroethane;

1,1,1,-trichloro-2,2,-bis(p-chlorophenyl) ethane

CAS # 50-29-3

organochlorine

insecticide

cancelled USA, 1972

pers (1)

oral: high (2)

dermal: medium to high (3)

inhalation: ?

cumulative (3)

carcinogen (4)

mutagen (5)

fetotoxin (5)

embryotoxin (3)

decreased fertility (3)

hormone changes (6)

aplastic anemia (6)

liver damage (7)

immunotoxin (8)

BIOCIDE

immediate toxicity:

 birds: low to medium

(9)

 fish: very high (10)

 amphibians: low to medium (9)

 crustaceans: very high

(10)

 bees: high (11) aquatic insect: very high (10)

aquatic worm: low (12) long-term toxicity:

 birds: diminished reproduction; eggshell thinning; cumulative (9,13)

 fish: affects reproduction (1)

snakes: much more toxic to egg-laying than to viviparous snakes (14) reduced photosynthesis by marine phytoplankton (15) bioaccumulates (16)

 molluscs: reduces shell growth (17)

water: insoluble

oil: “very soluble”

slightly volatile

128transformation product(s):

dicofol

(see dicofol)

DDE

(see DDE)

DDD

(see DDD)

DEET

Autan; Blockade; Chemform; Delphene; DET; Detamide; Dieltamid; diethyl toluamide; Flypel; M-DET; Metaldephene; MGK Diethyltoluamide; Off; Repel

N,N-diethyl-m-toluamide;

N,N-diethyl-3-methylbenzamide

CAS # 134-62-3

amide

insect repellent

?

oral: medium (1,2)

dermal: medium (2)

inhalation: ?

neurotoxin (3)

water: “insoluble”

DEF

butyphos; Chemagro B-1776; DEF defoliant; DeGreen; E-Z-off D; Fos-Fall “A”; Ortho Phosphate Defoliant; SST

S,S,S-tributylphosphorotrithioate

CAS # 78-48-8

organophosphate

herbicide defoliant

non-pers (1)

oral: high (2)

dermal: high to very high (3)

inhalation: ?

suspect delayed neurotoxin (4)

BIOCIDE

immediate toxicity:

 birds: medium to high (5)

 fish: very high (6)

 amphibians: high (7)

 aquatic insects: very high (6)

 crustaceans: very high (6)

 bees: low to medium (8)

long-term toxicity:

 birds: delayed neurotoxcity (9)

 fish: feeding behavior inhibited and swimming capacity affected (10)

“high potential for phytotoxicity” (11)

water: “insoluble”

deltamethrin

Butoss; Cislin; Crackdown; decamethrin; Decis; Decis Dan (with endosulfan & fenitrothion & profenfos); Delsekte; deltamethrine; Deltaphos (with triazophos); Detrans (with esbiothrin); K-O (with esbiothrin & piperonyl butoxide); K-Obiol (with piperonyl butoxide); K-Otek; K-Othrin; Kothrin; NRDC 161; OMS 1998; RU 22974

[1 R-[1 α(S*),3α]]-cyano(3-phenoxyphenyl) methyl 3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate

CAS # 52918-63-5

pyrethroid

insecticide

?

oral: medium to very high (1,2)

dermal: ?

inhalation: ?

?

water: insoluble

non-volatile

demeton

BAY 10756; Demox; E-1059; mercaptofos (USSR); Systemox; Systox

mixture of O,O-diethyl O-2-(ethylthio)ethyl phosphorothioate and O,O-diethyl S-2-(ethylthio)ethyl phosphorothioate

CAS # 8065-48-3

organophosphate

insecticide acaricide

non-pers (1)

oral: very high (2)

dermal: very high (3)

inhalation: ?

readily absorbed through the skin (4)

mutagen (5,6)

suspect teratogen (7)

embryotoxin (7)

immediate toxicity:

 birds: very high (8)

 fish: very high (9)

 amphibians: medium (8)

 crustaceans: very high (9)

 bees: high (10)

 toxic to some plants (4)

water: soluble

slightly volatile

129 demeton-methyl

BAY 15203; BAY 21/116; Duratox; Met-Systox; methyl demeton; Methylsystox

O,O-dimethyl O(and S)-2-(ethylthio)ethyl phosphorothioate

CAS # MX8022-00-2

organophosphate

insecticide acaricide

?

oral: very high (1)

dermal: high to very high (1)

inhalation: very high (2)

?

immediate toxicity:

 fish: low to medium (2)

long-term toxicity:

 birds: teratogenic (3)

 phytotoxic to some plants (4)

water: soluble

slightly volatile

desmedipham

Betanal 475; Betanal AM; Betanex;

Bethanol-475; EP-475; SN 38107

ethyl-m-hydroxycarbanilate carbanilate (ester);

3-ethoxycarbonylaminophenyl-N-phenylcarbamate;

ethyl [3-[[(phenylamino)carbonyl]oxy]-phenyl]carbamate

CAS # 13684-56-5

carbamate

herbicide

non-pers (1)

oral: low to medium (2,3)

dermal: medium (4)

inhalation: ?

?

immediate toxicity:

 fish: medium to high (2)

 bees: low to medium (5)

water: slightly soluble

non-volatile

combustible

desmetryn

desmetryne; G 34360; Samuron; Semeron; Topusyn

2-isopropylamino-4-methylamino- 6-methylthio-s-triazine

CAS # 1014-69-3

triazine

herbicide

non-pers (1)

oral: medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity: “negligible toxicity to wildlife” (2)

water: soluble

slightly volatile

dialifor

dialifos (except USA); dialiphor; Hercules 14503; Torak

S-(2-chloro-1-phthalimid oethyl) (O,O-diethyl phosphorodithioate;

S-[2-chloro-1 -(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)ethyl] O,O-diethyl phosphorodithioate

CAS # 10311-84-9

organophosphate

insecticide acaricide

non-pers (1)

oral: high to very high (2,3)

dermal: very high (3)

suspect teratogen (4)

immediate toxicity:

 bees: medium (5)

water: “insoluble”

diallate

2,3-DCDT; Avadex; CP 15336; DATC

S-2,3-dichloroallyl diisopropylthiocarbamate; S-2,3-dichloroallyl diisopropylthiolcarbamate

CAS # 2303-16-4

thiocarbamate

herbicide restricted USA,1982

non-pers (1)

oral: medium to high (1,2)

dermal: medium (1)

inhalation: ?

carcinogen (3,4)

suspect mutagen (3)

“testicular and ovarian effects” (5)

delayed neurotoxicity (3)

immediate toxicity:

 fish: medium (1)

 crustacean: medium (1)

 bees: low to medium (6)

water: slightly soluble

volatile

transformation product(s):

2-chloroacrolein

suspect mutagen (1)

diamidfos

Dowco-169; Nellite

phenyl N,N′-dimethyl phosphorodiamidate

CAS # 1754-58-1

organophosphate

nematocide

?

oral: high (1)

dermal: very high (1)

inhalation: ?

?

immediate toxicity:

 birds: very high (2)

water: very soluble

diatomaceous earth

Celatom; Celite; Fuller’s Earth; infusorial earth; Kenite; kieselguhr; Perma Guard*; silica; Super-Cel

130siliceous earth (composed of shells of diatoms);

silicon dioxide

*combined with pyrethrins

CAS # 61790-53-2

metal/mineral

silica

insecticide desiccant

perm

oral: ?

dermal: ?

inhalation: ?

lung damage (1)

immediate toxicity:

 bees: low (2)

diazinon

AG 500; Alfa-tox; Basudin; Dazzel; Diazajet; Diazatol; Diazide; Diazinon; Diazitol; Diazol; dimpylate; Dipofene; G 24480; Gardentox; Knox Out 2FM; Neocidol; Nipsan; Sarolex; Spectracide

O,O-diethyl O-(2-isopropyl-6-methyl-4-pyrimidinyl) phosphorothioate

CAS # 333-41-5

organophosphate

insecticide nematocide

banned from use on golf courses and turf farms in USA

non-pers (1,2)

oral: medium to high (3,4)

dermal: low to high (4)

inhalation: medium (3)

suspect mutagen (5,6)

fetotoxin (7)

suspect neurotoxin (8)

allergic dermatitis (9)

conjunctivitis (9) immunotoxin (10)

BIOCIDE

immediate toxicity:

 birds: very high (1,11)

 fish: very high (12)

 amphibians: very high (11)

 crustaceans: very high (12)

 bees: very high (13)

 aquatic insects: very high (14)

 aquatic worm: high (9)

 plants: toxic to some (15)

long-term toxicity:

 birds: teratogen (2)

water: slightly soluble

oil: very soluble

volatile

combustible

contaminant(s):

isodiazinon

porphyria (1)

transformation product(s):

sulfoTEPP

(see sulfoTEPP)

TEPP

(see TEPP)

dibutyl phthalate

DBP

di-n-butyl phthalate

CAS # 84-74-2

phthalate

insect repellent

?

oral: low (1) dermal: ? inhalation: ?

suspect mutagen (2)

suspect teratogen

(3)

testicular atrophy

(4)

water: soluble

volatile

flammable

dicamba

Banex; Banlene Solo (with ioxynil & dichlorporp); Banvel D; Banvel K (with 2.4-D); Banvell II; Bio Lawn Weedkiller (with 2.4-D & ioxynil); Brush Buster; Dianat; Docklene (with MCPA-sodium); Endox (with mecoprop); Fallow Master (with glyphosate); Fettel (with mecoprop & triclopyr); Herrisol (with MCPA-sodium); Lawnsman (with dichlorprop & MCPA); MDBA; Mediben; Nettle-Ban (with 2,4,5-T & 2,4-D); Super Trimec (with 2,4-D & dichlorprop); Trooper; Weedmaster (with 2,4-D)

3,6-dichloro-o-anisic acid;

2-methoxy-3,6-dichlorobenzoicacid

131CAS # 1918-00-9

organochlorine

herbicide

non-pers to mod-pers (1,2)

oral: medium (3,4)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: medium (2)

 fish: low (3,5)

 crustaceans: low to medium (2,5)

water: soluble

slightly volatile

“nonflammable”

transformation product(s):

2,7-dichlorodibenzo-p-dioxm

(see 2,4-D)

dimethylnitrosamine

CAS # 62-75-9

oral: very high (1/2)

carcinogen (3,4) mutagen (1,4)

water: “soluble”

“volatile”

“nonflammable”

dicapthon

AC 4124; American Cyanamid 4124; Captec; Di-Captan; Isomeric Chlorthion; OMS-214

O-2-chloro-4-nitrophenyl O,O-dimethyl phosphorothioate; p-nitro-o-chlorophenyl dimethyl thionophosphate

CAS # 2463-84-5

organophosphate

insecticide

non-pers to mod-pers (1)

oral: high (2)

dermal: high (3)

inhalation: ?

?

water: “practically insoluble”

dichlobenil

Barrier 2G; Barrier 50W; Casoron; Casoron G; Decabane; Du-Dusit (with bromacil); Dyclomec 4G; Dyclomec G2; Forte (with simazine); Fydulan G (with dalpon-sodium); Fydulex G (with dalpon-sodium); Fydusit (with bromacil); Norosac 4G; Norosac10 G; Prefix D; Silbenil

2,6-dichlorobenzonitrile

CAS # 1194-65-6

benzonitrile

herbicide

mod-pers (1)

oral: medium (1,2)

dermal: high (1)

inhalation: ?

suspect carcinogen (3)

immediate toxicity:

 fish: medium (1,2)

 crustaceans: medium (1)

 bees: low (4)

water: slightly soluble

slightly volatile

“nonflammable”

transformation product(s):

2,4-dichlorobenzamide

BAM

suspect neurotoxin (1)

dichlofenthion

Bromex; dichlorofenthion; diclofention; Hex-Nema; Mobilawn; Nemacide; Tri-VC-13; VC-13

O-2,4-dichlorophenyl O,O-diethyl phosphorothioate

CAS #97-17-6

organophosphate

insecticide nematocide

?

oral: high (1,2)

dermal: medium to high (3)

inhalation: ?

?

immediate toxicity:

 birds: high to very high (4)

 fish: very high (5)

 crustaceans: very high (5)

 aquatic insects: very high (5)

water: insoluble

oil: “miscible in kerosene”

dichlofluanid

BAY 47531; Cupro-Euparene (with copper oxychloride); dichlofluanide (France); Elvaren; Elvaron; Eparen; Euparen; Euparene; Euparin; KUE 13032c

N′-dichlorofluoromethylthio-N, N-dimethyl-N′-phenylsulfamide; 1,1-dichloro-N-[(dimethylamino)sulfonyl]-fluoro-N-phenylmethanesulfenamide

CAS # 1085-98-9

amide

fungicide

?

oral: low to medium (1,2)

dermal: low to medium (2)

inhalation: low to high (3)

?

immediate toxicity:

 fish: medium to high (3)

 bees: low to medium (4)

water: slightly soluble

slightly volatile

132 dichlone

Algistat; Compound 604; Kolo-100 (with sulfur); Phygon; Phygon Paste; Phygon Seed Protectant; Phygon XL; Sanquinon

dichloronapthoquinone;

2,3-dichloro-1,4-napthoquinone

CAS # 117-80-6

quinine

fungicide algacide

?

oral: medium (1)

dermal: ?

inhalation: ?

liver damage (2)

immediate toxicity:

 fish: high to very high (3)

 crustaceans: medium to very high (4)

 “insect predators”: “high” (3)

water: insoluble

dichloran

AL-50; Allisan; Botran; CNA; DCNA; dicloran; ditranil; Kiwi Luster; Resinan; U-2069

2,6-dichloro-4-nitroaniline

CAS # 99-30-9

dinitroaniline

fungicide

non-pers (1)

oral: low to medium (1)

dermal: ?

inhalation: low (1)

suspect mutagen (2)

liver & kidney damage (3)

cataracts (6)

immediate toxicity:

 birds: low to medium (4)

 fish: low to high (1)

 crustaceans: medium (1)

 bees: low (5)

water: slightly soluble

slightly volatile

dichlormid

Capsolane (with EPTC); Eradicane E (with EPTC); Eradicane G (with EPTC); Surpass (with vernolate); Sutan + (with butylate); Sutan + 10G (with butylate); Sutar 85E (with butylate); Sutazine (with butylate & atrazine)

N,N-dially-2,2-dichloroacetamide

CAS # 37764-25-3

amide

herbicide safener

non-pers (1)

oral: medium (2)

dermal: low to medium (2)

inhalation: medium (2)

immediate toxicity:

 birds: low (2)

 fish: low (2)

water: soluble

oil: very soluble

slightly volatile

combustible

dichloroethyl ether

Chlorex

bis (2-chloroethyl) ether; 2,2′-dichloroethyl ether

CAS # 111-44-4

miscellaneous

fumigant insecticide

?

oral: high (1,2)

dermal: ?

inhalation: ?

inhalation: “May cause liver damage if inhaled” (2)

carcinogen (3)

highly volatile

flammable to combustible

dichlorophen

antiphen; DDDM; DDM; dichlorophene (France); G-4; Prenetol GDC (alkaline solution); Preventol GD; Super Moxxtox

2,2′-methylene bis(4-chlorophenol); di-(5-chloro-2-hydroxyphenyl)methane

CAS # 97-23-4

phenol

fungicide

?

oral: medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: high (2)

 crustaceans: very high (3)

water: slightly soluble

non-volatile

1,2-dichloropropane

D-D (with dichloropropene); Nematox (with dichloropropene); propylene dichloride; Telone (with dichloropropene)

1.2-dichloropropane

CAS # 78-87-5

organochlorine

fungicide herbicide insecticide soil fumigant

mod-pers to pers (1,2)

oral: medium (1)

dermal: medium (1)

inhalation: low (1)

carcinogen (3)

suspect mutagen (1)

liver damage (1)

immediate toxicity:

 fish: low (1)

 crustaceans: low (1)

water: soluble

highly volatile

dichloropropene

D-D (with 1,2-dichloropropane); D-D92; DCP; Dedisol C; Dorlone II; Nematox (with 1.2-dichloropropane); Nematox II; Telone (with 1,2-dichloropropane); Telone II

1,3-dichloropropene;

1,3-dichloro-1-propene

CAS # 542-75-6

organochlorine

soil fumigant nematocide

“non-pers” (1)

oral: high (2)

dermal: high (2)

inhalation: ?

carcinogen (3,4)

suspect mutagen (1,5)

liver & kidney damage (1,5)

immediate toxicity:

 fish: medium to high (6,7)

 crustaceans: very high (7)

 bees: low to medium (8)

water: soluble

highly volatile

flammable

133 dichlorprop

2.4-DP; 2-(2,4-DP); Actril S (with bromoxynil & ioxynil & MCPA); Basagran Ultra (with ioxynil & bentazon); Clenecorn (with mecoprop); Cornoxynil (with bromoxynil); Desormone; Farmon (with MCPA); Hedonal DP; Hormatox; Kildip; Lawnsman (with dicamba & MCPA); Lontrel Plus (with mecoprop & clopyralid & MCPA); Minverva (with bromoxynil & ioxynil & MCPA); Polymone; Polytox; Seritox 50 (with MCPA); Tri-Cornox (with dicamba & benazolin); Ultima (with bentazon); Weedone DCP (with 2,4-D)

2-(2,4-dichlorophenoxy)propionic acid;

2-(2,4-dichlorphenoxy)propanoic acid;

s-(2,4-dichlorophenoxy)propionicacid

CAS # 120-36-5

phenoxy

herbicide

non-pers to mod-pers (1,2)

oral: medium to high (3,4)

dermal: high (5)

inhalation: low to medium (6)

suspect carcinogen (7)

suspect mutagen (8)

liver damage (9)

immediate toxicity:

 fish: low to high (2,10)

water: soluble

combustible

contaminant(s):

TCDD

(see chloroneb)

dichlorvos

Apavap; Atgard; Aygard V; Benfos; Brevinyl; Brevinyl E50; Canogard; DDVP; Dedevap; Devikol; Divipan; Equigel; Mafu Strip; No-Pest insecticide Strip; Raid Ant & Roach Killer; Raid Solid Insect Killer; SD 1750; Task; Unifos; Vaponite (in no-pest strips & some flea collars)

O,O-dimethyl-2,2-dichlorovinyl phosphate; 2,2-dichlorovinyl dimethyl phosphate

CAS # 62-73-7

organophosphate

insecticide

non-pers (1,2)

oral: high (3)

dermal: high to very high (4)

inhalation: high (3,5)

carcinogen (2,6)

mutagen (3,7)

suspect teratogen (2,3)

sperm and other reproductive abnormalities (3)

kills human white blood cells (8)

inhibits steroid synthesis (9)

indications of bone marrow damage and aplastic anemia (10)

immunotoxin (11)

immediate toxicity:

 birds: very high (12)

 fish: very high (13)

 bees: very high (1)

 crustaceans: very high (13)

 aquatic insects: very high (13)

long-term toxicity:

 birds: delayed neurotoxin (11)

water: soluble

oil: very soluble

highly volatile

combustible

diclofop-methyl

dichlofop-methyl; dichlorfop-methyl; diclofop; Hoegrass; Hoelon; Illoxan; One Shot (with bromoxynil & MCPA)

2-(4-(2,4-dichlorophenoxy)phenoxy)-propanoic acid methyl ester;

methyl 2-(4-(2,4-dichlorophenoxy)phenoxy)- propionate

CAS # 51338-27-3

phenoxy

herbicide

non-pers to mod-pers (1,2)

oral: medium (2,3)

dermal: medium to very high (2)

inhalation: ?

?

immediate toxicity:

 birds: low to medium (2)

 fish: medium to high (2)

water: slightly soluble to very soluble

slightly volatile to highly volatile

flammable

dicofol

Acarin; Acavers 35 (with methomyl); FW-293; Kelthane; Kethane Mixte (with methyl parathion); Mitigan; Mixte (with methyl parathion); Parasoufre Acaricide (with methyl parathion & sulfur); Tedane Extra (with dinocap & tetradiforn or mancozeb); Tuver Acaricide (with ethion & methyl parathion)

1,1-bis(p-chlorophenyl)-2,2,2-trichloroethanol; 4,4′-dichloro-or-α-(trichloromethyl)benzhydrol

CAS # 115-32-2

organochlorine

insecticide

acaricide

mod-pers (1)

oral: medium to high (2,3)

dermal: medium to very high (2,3)

inhalation: ?

carcinogen (4)

immediate toxicity:

 birds: medium to high (5)

 fish: very high (6)

 crustaceans: low (7)

 bees: low (8)

 aquatic insects: very high (6)

water: “insoluble” oil: “soluble” flammable

134contaminant(s):

DDT

(see DDT)

DDE

(see DDE)

DDD

(see DDD)

dicrotophos

Bidrin; C709; Carbicron; Diapadrin; Ektafos; SD 3562

dimethyl cis-2-dimethyl-carbamoyl-1-methylvinyl phosphate;

dimethyl phosphate ester of 3-hydroxy-N,N-dimethyl-cis-crotonamide;

3-dimethoxyphosphinyloxy-N, N-dimethylisocrotonamide

CAS # 141-66-2

organophosphate

insecticide

non-pers to mod-pers (1,2)

oral: very high (1,3)

dermal: high to very high (1)

inhalation: high to very high (1)

suspect mutagen (3,4)

“no organophosphate type delayed neurotoxicity” (3)

immediate toxicity:

 birds: very high (1,5)

 fish: low to medium (1,6)

 amphibians: medium (5)

 crustaceans: medium to high (6)

 aquatic insects: high (7)

slightly volatile

combustible

transformation product(s):

monocrotophos

(see monocrotophos)

Dicumarol

Dicoumarin; Dicoumarol; Dicumarin; Dicumarol; Melitoxin

bishydroxycoumarin;

3,3′-methylenebis (4-hydroxycoumarin)

CAS # 66-76-2

coumarin

rodenticide

?

oral: medium (1)

dermal: ?

inhalation: ?

?

water: “practically insoluble”

dieldrin

Alvit; Anter; Compound 497; dieldrine (France); Dielmoth; Dorytox; Dudubitoke; Eldrinol; HEOD (Canada); Hododrex; illoxol; Kyadrin; Octalox; Pestex; Red Shield

hexachloroepoxyoctahydro-endo-exo-dimethanonaphthalene and related compounds;

1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a,5,6,7,8,8a-octahydro 1,4-endo-exo-5, 8-dimethanonaphthalene and related compounds

CAS # 60-57-1

organochlorine

insecticide

cancelled USA,1971

pers (1)

oral: high to very high (2)

dermal: very high (2)

inhalation: very high (19)

cumulative (3,4)

suspect carcinogen (1,5,6)

suspect teratogen (7,8)

immunotoxin (9,10) abnormal brain waves, behavior changes (10,11)

BIOCIDE

immediate toxicity:

 birds: high to very high (12)

 fish: very high (13)

 amphibians: very high (1)

 crustaceans: very high (14)

 molluscs: very high (1)

 bees: very high (15)

 aquatic insects: very high (13)

 aquatic worms: medium (16)

 plankton: very high (14)

long-term toxicity:

 birds: damages reproduction, eggshell thinning (17,18)

water: insoluble

oil: very soluble

slightly volatile

“nonflammable”

transformation product(s):

photodieldrin

2a,2,2,4,5,5a-hexachlorodecahydro-2,4,6-metheno-2H-cychlopenta [4,5]pentaleno[1,2-]oxirene

CAS # 13366-73-9

“more toxic than dieldrin” (1)

135 dienochlor

HRS-16; Pentac

bis(pentachloro-2,4-cyclopentadiene-1-yl);

decachlorobis(2,4-cyclopentadiene-1-yl)

CAS # 2227-17-0

organochlorine

acaricide

non-pers (1)

oral: medium (2)

dermal: medium (2)

inhalation: high (3)

?

immediate toxicity:

 bird: low to medium (4)

 fish: medium to high (4)

 crustacean: high (5)

 plants: low (6)

water: insoluble

slightly volatile

toxic fumes if burned

transformation product(s):

chlorine

(see chlorine)

hydrogen chloride

hydrochloric acid

CAS # 7647-01-0

oral: low (1)

phosgene gas

(see carbon tetrachloride)

diethatyl

Barrix (with ethofumesate); H-22234; Hercules 22234

N-chloroacetyl-N-(2,6-diethylphenyl)glycine

CAS # 38727-55-8

amide

herbicide

mod-pers (1)

oral: medium (2)

dermal: low to medium (3)

inhalation: ?

?

immediate toxicity:

 birds: low (3)

 fish: medium (1)

water: soluble

slightly volatile

flammable

diethyl fumarate

2-butenedioc acid, diethyl ester

CAS # 623-91-6

miscellaneous

?

oral: medium

synergistic with malathion

?

?

difenacoum

Compo; Matrak; Neosorexa; Ramor; Rastop; Ratak; Ratrick; Silo; WBA 8107

3-(3-diphenyl-4-yl-1,2,3,4-tetrahydro-1-nephtryl)-4-hydroxycoumarin;

3-(3-(1,1′-biphenyl)-4-yl-1,2, 3,4-tetrahydro-1-napthalenyl)-4-hydroxy-2H-1-benzopyran-2-one

CAS # 5607-07-5

coumarin

rodenticide

?

oral: high to very high (1)

dermal: ?

inhalation: ?

?

water: slightly soluble

difenzoquat

AC 84777 Finaven; Avenge; Mataven; Supe raven

1,2-dimethyl-3,5-diphenyl-1 H-pyrazolium methyl sulfate

CAS # 49866-87-7

bypiridyl

herbicide

mod-pers (1,2)

oral: high to very high (1,2)

dermal: low to medium (2)

inhalation: low (2)

?

immediate toxicity:

 birds: “low toxicity to birds” (2)

 fish: low (1)

 crustaceans: high (3)

 bees: “nontoxic to bees” (4)

water: very soluble

oil: “insoluble”

slightly volatile

transformation product(s):

monomethyl pyrazole

“volatile”

136 diflubenzuron

deflubenzon; diflubenuron; difluron; Dimilin; Dimilin IG; Dimilin W-25; Micromite; OMS 1804; PH 60–40; TH 60–40; Vigilante

N-[[(4-chlorophenyl)amino] carbonyl]-2,6-difluorobenzamide

CAS # 35367-38-5

urea

insecticide

restricted use in USA

non-pers to mod pers (1–3)

oral: low (4)

dermal: low (4)

inhalation: low (4)

affects oxygen carrying capacity of red blood cells via methemoglobin emia and sulfemoglobine mia (3,5)

immediate toxicity:

 birds: low (4)

 fish: low (4)

 crustaceans: very high (4)

long-term toxicity:

 crustaceans: affects reproduction (6)

water: “soluble”

oil: “virtually insoluble”

transformation product(s):

4-chloroaniline

CAS # 10-64-7

carcinogen (1)

may cause methemoglobinemia and sulfhemoglobinemia (2)

dihydrosafrole

1,2-methylenedioxy-4-propylbenzene

CAS # 94-58-6

methylenedioxy

intermediate in the synthesis of piperonyl butoxide

?

oral: medium (1)

dermal: ?

inhalation: ?

carcinogen (1,2)

?

dikegulac sodium

Atrimmec; Atrinal; Cutlass

sodium salt of 2,3:4,6-di-O-isopropylidene- α-l-xylo-2-hexalofuranosonic acid

CAS # 52508-35-7

miscellaneous

plant growth regulator

?

oral: low (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: low (2)

 fish: low (1)

 bees: low (3)

water: very soluble

non-volatile

combustible

dimefox

Hanane; Terra-Sytam

bis(dimethylamino) fluorophosphine oxide

CAS # 115-26-4

organophosphate

insecticide acaricide

?

oral: very high (1)

dermal: very high (1)

inhalation: “vapor toxicity hazard is high” (1)

?

highly volatile

dimethirimol

Milcurb

5-n-butyl-2-dimethylamino-4-hydroxy-6-methylpyrimidine

CAS # 5221-53-4

pyrimidine

fungicide

mod-pers (1)

oral: low to medium (2,3)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: medium (1)

 fish: low (2)

 bees: “nontoxic to bees” (2)

water: soluble

slightly volatile

dimethoate

Bio Long Last (with permethrin); Bio Systemic insecticide; Cyanotril (with flucythrinate); Cygon; Cykuthoate; Daphene; Devigon; Dimet; Dimethogen; Flutrin (with flucythrinate); fosfamid (USSR); Fostion MM; Mikantop (with fenvalerate); Perfekthion; Rogor; Roxion; Salut (with chlorpyrifos); Trimetion; Turbair Systemic insecticide; Vitex

O,O-dimethyl S-(N-methylcarbamoylmethyl) phosphorodithioate; 2-dimethoxyphosphinothioylthio-N-methylacetamide

CAS # 60-15-5

organophosphate

insecticide acaricide

cancelled, most products, USA,1981

non-pers (1,2)

oral: high to very high (2,3)

dermal: high to very high (1,2)

inhalation: ?

suspect carcinogen (4)

mutagen (2,5)

suspect teratogen (2,6)

blood damage (7)

testicular atrophy (4)

kidney damage (4)

immunotoxin (8)

immediate toxicity:

 birds: high to very high (1/2)

 fish: low to high (1,2)

 crustaceans: high to very high (2,9)

 bees: very high (10)

 aquatic insects: very high (2)

water: very soluble

slightly volatile

flammable to combustible

137transformation product(s):

omethoate

(see omethoate)

dimethrin

dimethrine (France)

2,4-dimethylbenzyl (RS)-cis,trans-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate

CAS # 70-38-2

pyrethroid

insecticide

?

oral: high (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: high to very high (2,3)

dimethylamine

dimethylamine aqueous solution; DMA

CAS # 124-40-3

miscellaneous

insect attractant

?

oral: ?

dermal: ?

inhalation: ?

?

water: “very soluble”

transformation product(s):

dimethylnitrosamine

CAS # 62-75-9

oral: very high (1,2)

carcinogen (3,4)

mutagen (1,4)

water: “soluble”

“volatile”

“nonflammable”

dimethyl phthalate

DMP; NTM

dimethyl 1,2-benzenedicarboxylate

CAS # 131-11-3

phthalate

insect repellent

?

oral: low (1)

dermal: ?

inhalation: very high (2)

suspect mutagen (3,4)

water: soluble

oil: “soluble”

volatile

combustible

dimethyl sulfoxide

DMSO

sulfinylbis[methane]

CAS # 67-68-5

metal/mineral sulfur

solvent

?

oral: low (1)

dermal: ?

inhalation: ?

suspect mutagen (2)

immediate toxicity:

 birds: high (3)

water: “soluble”

combustible

dinex

dinitrocyclohexylphenol; DN Dust No. 12; DN-111; DN-75; DNOCHP; Dowspray 17; Dynone-II; pedinex (France) 2-cyclohexyl-4,6-dinitrophenol; dicyclohexylamine salt; 4,6-dinitro-o-cyclohexyl phenol

CAS # 131-89-5

phenol

insecticide acaricide

?

oral: high (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 bees: low (2)

 aquatic worms: very high (3)

dinitramine

Cobex; Cobexo; diethamine; dinitroamine; USB-3584

N 3,N 3-diethyl-2,4-dinitro-6-trifluoro-ethyl-m-phenylenediamine;

N 4 N 4-diethyl-α,α,α-trifluoro-3,5-dinitrotoluene-2,4-diamine;

N 3,N 3-2,4-dinitro-6-(trifluoromethyl)-1,3-benzendiamine

CAS # 29091-05-2

dinitroaniline

herbicide

mod-pers (1)

oral: medium (2)

dermal: medium (2)

inhalation: ?

?

immediate toxicity:

 birds: low (1)

 fish: medium to very high (1,3)

water: slightly soluble

oil: very soluble

slightly volatile

flammable

dinitrocresol

Antinonnin; Capsine; Chemosect DNOC; Dekrysil; Detal; Ditrosol; DNOC; Effusan; Elgetol 30; Gioallolio; Ibertox Pasta; Jackyl S; Krenite; Lipan; Nitrador; Prokarbol; Sandolin A; Sinox; Triacide; Trifrina 4,6-dinitro-o-cresol; 2-methyl-4,6-dinitrophenol

CAS # 534-52-1

phenol

defoliant

herbicide

fungicide

insecticide

non-pers (1)

oral: high to very high (2)

cumulative (2,3)

immediate toxicity:

 birds: very high (4)

 fish: high to very high (5)

 crustaceans: high (5)

 molluscs: high (1)

 aquatic insects: high (5) water: soluble

slightly volatile

138 dinitrophenol

Chemox PE; Nitro Kleenup

2,4-dinitrophenol;

α-dinitrophenol

CAS # 51-28-5

phenol

insecticide acaricide fungicide

?

oral: very high (1)

dermal: ?

inhalation: ?

“readily absorbed through intact skin” (2)

brain, liver and kidney damage (3)

immediate toxicity:

 birds: very high (4)

 plants: “phytotoxic to green plants (1)

dinobuton

Acarelte; Acarelte Forte; Acrex; Dessin; Dinofen; Drawinol; MC 1053; P-1053; Systol; Sytasol; Talan; UC 19786

1-methylethyl 2-(1-methylpropyl)-4,6-dinitrophenyl carbonate; 2-sec-butyl-4,6-dinitrophenyl isopropyl carbonate

CAS # 973-21-7

nitro

acaricide

fungicide

?

oral: medium to high (1,2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: “toxic” (2)

 bird: high (3)

 bees: “toxic” (2)

water: “practically insoluble”

dinocap

Acarthane (with dicofol); Arathane; Cakucap; Crotothane; Iscothane; Karathane; Mildane; Mildex; Sialite; Tedane Extra (with dicofol & tetradiforn or w/mancozeb)

2-(1-methylheptyl)-4,6-dinitrophenocrotonate

CAS # 39300-45-3

phenol

fungicide

acaricide

restricted USA, 1989

non-pers to mod-pers (1,2)

oral: medium (1)

dermal: ?

inhalation: high (1)

teratogen (3,4)

immediate toxicity:

 fish: very high (5)

 bees: medium (6)

water: insoluble

highly volatile

dinoseb

Dinitrall; dinitro; Dinitro Weed-Killer; dinitrobutyl phenol; dinosebe (France); DN-289; DNBP; DNOSBP; Dow General Weedkiller; Dow Selective Weedkiller; Elgetol 318; Gebutox; Kilseb; Knoxweed; Nitropone C; Premerge; Sinox General Subitex; Unicrop DNBP; Vertac Dinitro Weedkiller

2-sec-butyl-4,6-dinitrophenol;

4,6-dinitro-o-sec-butyl phenol;

2,4-dinitro-6-sec-butylphenol

CAS # 88-85-7

phenol

herbicide

fungicide

insecticide

dessicant

cancelled USA, 1988

non-pers to mod-pers (1,2)

oral: high to very high (3,4)

dermal: high to very high (1,5)

inhalation: ?

teratogen (6,7)

male sterility (7)

immediate toxicity:

 fish: medium to high (8)

  bird: very high (9)

water: soluble

oil: “soluble”

transformation product(s):

nitrosamines

suspect carcinogen (1)

dinoterb

DNTBP; Herbogil; Herbogil Liquid D;

Nixone

2-tert-butyl-4,6-dinitrophenol

other salts:

 dinoterb-ammonium

 dinoterb-diolamine

 dinoterb-sodium

 dinoterb-dimethylammonium

CAS # 1420-07-1

phenol

herbicide

?

oral: very high (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: very high (1)

water: slightly soluble

139 dinoterb acetate

MC1108

2-tert-butyl-4,6-dinitrophenol acetate

CAS # 3204-27-1

phenol

herbicide

nematocide

?

oral; high (1)

dermal: low to medium (1)

inhalation: ?

?

water: “almost insoluble”

dioxabenzofos

Salithion

2-methoxy-4H-1,2,3-benzo-dioxaphosphorin-2-sulfide

CAS # 38260-54-7

organophosphate

insecticide

?

oral: high (1)

dermal: high (2) inhalation: ?

?

immediate toxicity:

 fish: medium (1)

long-term toxicity:

 birds: delayed neurotoxicity (3)

water: slightly soluble volatile

dioxacarb

Elocron; Famid; Flocron; Gamid; Ulvair

2-(1,3-dioxolan-2-yl)phenyl methylcarbamate

CAS # 6988-21-2

carbamate

insecticide

non-pers (1)

oral: high (1,2)

dermal: medium to high (2)

inhalation: very high (1)

?

immediate toxicity:

 birds: “slightly toxic” (1)

 fish: low (1)

 bees: high (3)

water: soluble

slightly volatile

dioxathion

Delnav; Deltic; Hercules AC 528; Navadel; Ruphos

2,3-p-dioxanedithiol S,S-bis(O,O-diethyl phosphorodithioate)

CAS # 78-34-2

organophosphate

insecticide

acaricide

“mod-pers” (1)

oral: very high (2)

dermal: high (2)

inhalation: high (3)

suspect mutagen (4)

immediate toxicity:

 birds: high (1)

 fish: very high (5)

 crustaceans: very high (5)

 bees: medium (6)

water: “practically insoluble”

diphacinone

diphacin (Turkey); Diphacinon; diphenadione; Gold Crest; Kill-Ko Rat Killer; Promar; Ramik

2-(diphenylacetyl)-1H-indene-1,3(2H)-dione;

2-diphenylacetyl-1,3-indandione

CAS # 82-66-6

indandione

rodenticide

“maintains a long persistence” (1)

oral: very high (2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: medium (2)

 fish: medium (2)

water: slightly soluble

non-volatile

diphenamid

Dymid; Enide; Rideon

N,N-dimethyl-2,2-diphenylacetamide

CAS # 957-51-7

amide

herbicide

mod-pers (1)

oral: medium to high (1)

dermal: “no toxicity” (1)

inhalation: “no toxicity” (1)

?

immediate toxicity:

 birds: “very low toxicity” (2)

 fish: low (3)

 crustaceans: low (3)

 bees: low (4)

water: soluble “nonflammable”

diphenyl

biphenyl; Lemonene; Phenador-X; phenylbenzene; PHPH

CAS # 34987-38-7

aromatic hydrocarbon

fungicide

?

oral: medium (1)

dermal: ?

inhalation: ?

kidney, liver, & brain damage (2)

water: “insoluble”

highly volatile

diphenylamine

Big Dipper; Coraza; Deccoscald 282; DPA; No Scald; Scaldip; Shield DPA

N-phenylbenzenamine

CAS # 122-39-4

miscellaneous

fungicide

?

oral: medium to high (1)

dermal: ?

inhalation: ?

?

water: “insoluble”

combustible

140 dipropetryn

Cotodon (with metolachlor); Cotofor; GS-16068; Sancap

2-ethylthio-4,6-bis(isopropylamino)-s-triazine; 6-(ethylthio)-N, N′-bis(1-methylethyl)- 1,3,5-triazine-2,4-diamine

CAS #4147-51-7

triazine

herbicide

mod-pers (1)

oral: low to medium (1,2)

dermal: low to medium (2)

inhalation: low (3)

?

immediate toxicity:

 fish: medium to high (1)

water: slightly soluble

slightly volatile

“nonflammable”

diquat

Actor (with paraquat); Aquacide; Cleansweep (with paraquat); Cyclone (with paraquat); Dextrone (with paraquat dichloride); Groundhog (with paraquat & amitrole & simazine); Midstream; Parable (with paraquat); Pardi Weedol (with paraquat); Pathclear (with paraquat & amitrole & simazine); Preglone (with paraquat); Priglone (with paraquat); Reglex; Reglone; Seccatutto (with paraquat); Soltair (with paraquat & simazine); Spraygrow (with paraquat); Spraytop (with paraquat); Torpedo; Weedtrine-D

6,7-dihydropyrido[1,2-a:2′,1′-c] pyrazinediium;

1,1′-ethylene-2,2′-dipyridyldiylium

CAS # 2764-72-9

bypiridyl

herbicide dessicant

non-pers (1)

oral: high (2)

dermal: high to very high (2,3)

inhalation: ?

suspect mutagen (3)

suspect teratogen (4)

suspect fetotoxin (3)

suspect embroytoxin (6)

liver damage (5)

cataracts (7)

immediate toxicity:

 birds: medium (8)

 fish: low (9)

 crustaceans: low (9)

 bees: medium (1)

water: very soluble

non-volatile

“nonflammable”

contaminant(s):

ethylene dibromide

(see ethylene dibromide)

diram

ammonium dimethyl-dithiocarbamate

CAS # 3226-36-6

carbamate

fungicide

?

oral: medium to high (1)

dermal: ?

inhalation: ?

?

disparlure

Hereon Disrupt Gypsy Moth; Hereon Luretape Gypsy Moth; Kisparmone; Pherocon GM

cis-7,8-epoxy-2-methyloctadecane

CAS # 29804-22-6

biological

attractant

?

oral: low (1)

dermal: ?

inhalation: ?

?

disulfoton

BAY 19639; Disyston; Disyston O (with isofenphos); Dithiodemeton; Dithiosystox; Doubledown (with fonofos); Ekanon; Ekatin TD; Ethimeton; Frumin G; Frumin-Al; Insyst-D; Knave; M-74 (USSR); S276; Solvigran; Solvirex; Twinspan O,O-diethyl S-2-(ethylthio)ethyl phosphorodithioate

CAS # 298-04-4

organophosphate

insecticide acaricide

non-pers (1,2)

oral: very high

(3)

dermal: very high (3)

inhalation: high

(4)

suspect mutagen (5)

immediate toxicity:

 birds: very high (6)

 fish: medium to very high (7)

 crustaceans: very high (7)

 aquatic insects: very high (7)

water: slightly soluble

oil: “soluble”

volatile

combustible

ditalimfos

Dowco 199; Laptran; Plondrel

O,O-diethyl phthalmide phosphonothioate

CAS # 5131-24-8

organophosphate

fungicide

?

oral: low to medium (1)

dermal: medium to high (1)

inhalation: ?

?

immediate toxicity:

 birds: medium (2)

water: soluble

slightly volatile

141 diuron

Cekiuron; Dailon; DCMU; Destral (with dalapon & 2,4-D); Di-on; Diurex; DMU; Dynex; Gramixel (with paraquat); Gramuron (with paraquat); Karmex; Krater (with asulam); Marmer; Paracol (with paraquat); Rassapron (with atrazine & amitrole); Surefire (with paraquat); Totacol (with paraquat); Weed-Free g (with bromacil)

3-(3,4-dichlorophenyl)-1,1-dimethylurea

CAS # 330-54-1

urea

herbicide

mod-pers to pers (1,2)

oral: medium (3)

dermal: low to medium (4)

inhalation: ?

poisoning potential increased with protein-deficient diet (5)

suspect mutagen (6)

suspect teratogen (7)

growth inhibition (5)

anemia (5)

BIOCIDE

immediate toxicity:

 birds: low to medium (8)

 fish: medium to high (9)

 crustaceans: medium to high (9)

 bees: low (10)

 aquatic insects: high (9)

 phytoplankton: “very high” (2)

long-term toxicity:

 fish: gill damage, inhibits reproduction (2)

 molluscs: shell growth inhibited (2)

 can reduce oxygen content of ponds (2) water: slightly soluble

oil: soluble non-volatile “nonflammable”

160contaminant(s):

TCAB

TCAB

3,4,3′,4′-tetrachloroazobenzene structure is analogous to TCDD (see under 2,4,5-T)

CAS # 14047-09-7

also a component of diuron

suspect mutagen (1,2)

chloracne & hyperkeratosis (3)

DMPA

Dow 1329; Dow Crabgrass Killer; Dowco 118; Zytron

O-2,4-dichlorophenyl

O′-methyl isopropylphosphoroamidothioate; (1-methylethyl) phosphoramidothoic acid O-(2,4-dichlorphenyl) O-2,4-(dichlorphenyl) O-methyl ester;

dimethylolpropionic acid

CAS # 299-85-4

organophosphate

herbicide plant growth regulator

?

oral: medium to high (1,2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: medium (2)

long-term toxicity:

 birds: neurotoxin (3)

water: slightly soluble

dodine

AC 5223; Carpene; Curitan; Cyprex; Cyprex 65W; dodin; dodine acetate; doguadine (France); Efuzin; Melprex; Mexprex; Syllit; Triododine; tsitrex (USSR); Venturol; Vondodine

dodecylguanidine acetate;

laurylguanidine acetate

CAS # 2439-10-3

miscellaneous

fungicide

herbicide

?

oral: medium (1)

dermal: low to high (1)

inhalation: high (2)

?

immediate toxicity:

 birds: medium (3)

 fish: high (3)

 bees: low to medium (4) insect predators: “toxic to some” (5)

water: soluble

volatile

drazoxolon

Ganocide; Mil-Col; Primicid (with pirimiphos-ethyl); SAIsan F; Sporacol

4-(2-chlorophenylhydrazono)-3-methyl-1,2-oxazol-5(4H)-one;

4-(2-chlorophenylhydrazono)-3-methylisoxazol-5(4H)-one

CAS # 5707-69-7

miscellaneous

fungicide

?

oral: high to very high (1,2)

dermal: ?

inhalation: ?

neurotoxin (2,3)

heart damage (2)

immediate toxicity:

 birds: high to very high (2,4)

 fish: high (1)

water: “insoluble”

slightly volatile

142 edifenphos

BAY 78418; ediphenphos; Hinosan; SRA 7847

O-ethyl-S,S-diphenyl phosphorodithioate

CAS # 17109-49-8

organophosphate

fungicide

non-pers (1)

oral: high (2)

dermal: ?

inhalation: high (2)

?

immediate toxicity:

 birds: medium (2)

 fish: high (2)

water: “practically insoluble”

volatile

endod

derived from plant species Phytolacca dodecandra

botanical

molluscicide

?

oral: medium to high (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: high (2)

 plants: medium to high (1)

endosulfan

benzoepin; Beosit; Chlorthiepin; Cyclodan; Endocel; FMC 5462; Hoe 2671; Insectophene; Kop-Thiodan; Malic; Malix; NIZ 5462; Quinolate MG SAFI (with oxine-copper & lindane); Rogodan (with dimethoate); Thifor; Thimul; thiodan (Iran, USSR); Thionex; Tiovel

hexachlorohexhydromethano-2,4, 3-benzodioxathiepin oxide;

6,7,8,9,10,10-hexachloro-1,5,5α,6,9,9α-hexahydro-6,9-methano-2,4,3-benzodioxathiepin 3-oxide;

5-norbornene-2,3-dimethanol-1,4,5,6,7,7-hexachlorocyclic sulfite

CAS # 115-29-7

organochlorine

insecticide

mod-pers (1)

oral: very high (2)

dermal: very high (2)

inhalation: very high (2)

suspect carcinogen (4)

mutagen (5,6)

kidney damage (4)

eye damage (7)

suppression of immune responses (8)

red blood cell damage (9)

BIOCIDE

immediate toxicity:

 birds: high to very high (10)

 fish: very high (11)

 crustaceans: very high (11)

 bees: very high (12)

 amphibians: very high (13)

 molluscs: very high (14)

long-term toxicity:

 fish: ovary damage (15,16)

 crustaceans: cumulative (18)

can inhibit fungal growth (17)

 damages some plants: some flowers, grapes, and birches (19)

water: insoluble

slightly volatile

“nonflammable”

endothall

Accelerate; Aquathol; Des-i-cate; Endothal; endothal (Europe, except Italy); Herbicide 273; Herbicide 282; Hydout; Hydrothal 47; Hydrothol 191; Niagrathal; Ripenthol; Tri-Endothal

3,6-endoxohexahydrophthalic acid; 7-oxabicyclo(2,2,1) heptane-2,3-dicarboxylic acid

also the following salts:

 dipotassium

 disodium

 dihydroxyaluminum

 mono (N, N-dimethyltridecylamine)

 di(N,N-dimethyltridecylamine)

 mono(N,N-dimethylcocoamine)

 di(N,N-dimethylcocoamine)

CAS # 129-67-9

phthalate

herbicide

non-pers (1)

oral: high to very high (2,3)

dermal: ?

inhalation: low to medium (4)

?

immediate toxicity: fish (salts-disodium, dimethyl amine, cocoamine): low to high (5) fish (acid): low to high (6)

crustaceans (dipotassium salts): low (7) crustaceans (acid): high (7)

aquatic insects (amine salts): medium (5)

long-term toxicity:

 fish (amine salt): damage to liver & testes (8)

 bioaccumulates in pond bottom arthopods (7)

water: very soluble

“nonflammable”

143 endrin

Accelerate; Agrine; Compound 269; Drinafog; Endrex; Endricol; Endrotox; Enpar; Envel; Hexadrin; Insectrin; Mendrin; Multitox; nendrin (India & So. Africa); Oktonex; OMS-197; Palmarol; SD 3419

hexachloroepoxyoctahydro-endo-endo-dimethanonapthalene;

1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a,5,6,7,8,8a-octa- hydro-1,4-endo,endo-5,8-dimethanonapthalene

CAS # 722-20-8

organochlorine

insecticide

cancelled USA, 1979

pers (1)

oral: very high (2)

dermal: very high (2)

inhalation: ?

suspect carcinogen (3,4)

tertatogen (5,6)

suspect neurotoxin(7)

BIOCIDE

immediate toxicity:

 birds: very high (8)

 fish: very high (9)

 amphibians: high to very high (10)

 crustaceans: very high (9)

 bees: high (11)

 aquatic insects: very high (9)

 plants: toxic to some plants (1)

 algae: high to very high (12)

long-term toxicity:

 birds: reproductive damage (13,14)

 bioaccumulates in fish and molluscs (1) water: “insoluble” slightly volatile “nonflammable”

transformation product(s):

12-ketoendrin

five times as toxic as endrin (1)

epichlorohydrin

1-chloro-2,3-epoxypropane

CAS # 106-89-8

organochlorine

insecticide

fumigant

?

oral: high

dermal: ?

inhalation: ?

carcinogen (1,2)

mutagen (3,4)

kidney damage (2)

decreased sperm motility (5,6)

water: “insoluble”

flammable

EPN

Meidon 15 Dust (with carbaryl)

O-ethyl O-p-nitrophenyl phenyl phosphonothioate;

ethyl p-nitrophenyl thionobenzenephosphonate

CAS # 2104-64-5

organophosphate

insecticide acaricide

cancelled USA,1983

mod-pers (1)

oral: very high (1)

dermal: high (1)

inhalation: very high (1)

fetotoxin (2)

delayed neurotoxin (3)

immediate toxicity:

 birds: very high (4)

 fish: high to very high (5)

 crustaceans: very high (1)

 bees: very high (6)

 toxic to some plants (7)

water: “slightly soluble”

slightly volatile

EPTC

Alirox; Anclirox; Capsolane (with dichlormid); Eptam; Eradicane E (with dichlormid); Eradicane G (with dichlormid); Witox

S-ethyl dipropylthiolcarbamate;

S-ethyl dipropylthiocarbamate

CAS # 759-94-4

thiocarbamate

herbicide

non-pers (1)

oral: medium (2)

dermal: low to medium (3)

inhalation: ?

?

immediate toxicity:

 birds: high (4)

 fish: low to medium (2)

 crustaceans: low (5)

water: soluble volatile

flammable

contaminant(s):

N-nitrosodipropylamine

CAS # 621-64-7

oral: high (1)

carcinogen (1)

transformation product(s):

ethyl mercaptan

CAS # 75-08-1

oral: medium (1) dermal: low (1)

144 erborn

Baron; Erbon R; Novege; Novon

2-(2,4,5-trichlorophenoxy)ethyl 2,2,-dichloroproprionate

CAS # 136-25-4

phenoxy

herbicide

cancelled USA, 1980

?

oral: medium (1)

dermal: ? inhalation: ?

?

immediate toxicity:

 birds: medium (2)

 bees: low to medium (3)

water: “insoluble”

oil: “soluble”

“very low volatility”

“nonflammable”

transformation product(s):

dalapon

(see dalapon)

ethalfluralin

Edge; EL-161; Grindor (with atrazine); Maizor (with atrazine); Somilan; Sonalan

N-ethyl-N-(2-methyl-2-propenyl)-2,6-dinitro-4-(trifluoromethyl)benzeneamine; 2,6-dinitro-N-ethyl-N-(2-methyl-2-propenyl)- α,α,α trifluoro-p-toluidine

CAS # 55283-68-6

dinitroaniline

herbicide

non-pers (1)

oral: low to high (1)

dermal: low to medium (2)

inhalation: low (2)

carcinogen (3) teratogen (3)

immediate toxicity:

 birds: medium (3)

 fish: very high (1)

 crustaceans: very high (3)

water: insoluble

slightly volatile

“not flammable”

ethephon

Arvest; Bromaflor; Cagro; Cepha; Cerone; Composan; Etheverse; Ethrel; Fiordimex; Florel; Prep; Terpal C (with chlormequat chloride); Terpal M (with chlormequat chloride & mepiquat chloride)

2-(chloroethyl)phosphonic acid

CAS # 16672-87-0

organophosphate

plant growth regulator

non-pers (1)

oral: medium (1,2)

dermal: medium (2)

inhalation: ?

?

immediate toxicity:

 birds: medium (1)

 fish: low (2)

 bees: low to medium (3)

 crustaceans: low (4)

water: soluble

oil: “insoluble” “nonflammable”

ethiofencarb

Croneton; ethiofencarp; ethiophencarp; Hox 1901

2-ethyl-mercaptomethyl-phenyl- N-methylcarbamate;

2-[(ethylthio)methyl]phenyl methylcarbamate; α-ethylthio-o-tolyl methylcarbamate

CAS # 29973-13-5

carbamate

insecticide

?

oral: high (1)

dermal: ?

inhalation: high (1)

?

immediate toxicity:

 birds: high (1)

 fish: low to medium (1)

water: slightly soluble

slightly volatile

ethiolate

Prefox (with cyprazine); S 6176; S-15076

S-ethyl diethylthiocarbamate;

S-ethyl diethylcarbamothioate

CAS # 2941-55-1

thiocarbamate

herbicide

“non-pers” (1)

oral: medium to high (1)

dermal: high (1)

inhalation: ?

?

immediate toxicity:

 birds: medium (1)

water: soluble

volatile

combustible

ethion

Acarfor (with dicofol); diethion (France, India, So. Africa); Embathion; Ethanox; Ethiol; Ethodon; FMC 1240; Hylemox; Itopaz; Kwit; NIA 1240; Niagara 1240; Nialate;

Rhodiacide; Rhodocide; RP-Thion; Tuver Acaricide (with dicofol & methyl parathion); Vegfru Fosmite

O,O,O′,O-tetraethyl S,S′-methylene bisphosphorodithioate;

S′,S′-methylene O,O,O′,O-tetraethyl di(phosphorodithioate);

S′,S′-methylene bis(O,O-diethyl phosphorodithioate)

CAS # 563-12-2

organophosphate

insecticide acaricide

non-pers to mod-pers (1)

oral: high to very high (3,4)

dermal: high to very high (1,4)

inhalation: medium to high (4,5)

?

immediate toxicity:

 birds: low to medium (6)

 fish: medium to high (7)

 crustaceans: medium to high (7)

 bees: medium (8)

 aquatic insects: medium (7)

long-term toxicity:

 birds: teratogen (9)

water: slightly soluble oil: “soluble” slightly volatile “nonflammable”

145 ethiozin

BAY SMY 1500; Lektran; Tycor

4-amino-6-tert-butyl-3-ethylthio-

1,2,4-triazin-5(4H)-one;

4-amino-6-(1,1-dimethylethyl)-3-(ethylthio)-1,2,4-triazin5(4H)-one; 3-ethylthio-4-amino-6-tert-butyl-1,2,4-triazine-5-one

CAS # 64529-56-2

triazine

herbicide

?

oral: medium (1)

dermal: low to medium (1)

inhalation: ?

?

water: soluble

slightly volatile

“nonflammable”

ethirimol

Milcurb Super; Milgo E; Milstem

5-butyl-2-ethylamino-6-methylpyrimidin-4-ol;

5-butyl-2-(ethylamino)-6-methyl- 4(1H)-pyrimidinone; 5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinol

CAS # 23947-60-6

pyrimidine

fungicide

mod-pers (1)

oral: low to medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: medium (1)

 fish: low (1)

water: soluble

slightly volatile

ethofumesate

Barrix (with diethatyl-ethyl); Betanal Perfekt (with phenmedipham); Betanal Progress (with phenmedipham & desmedipham); Betanal Tandem (with phenmedipham); Betaron (with phenmedipham); Magnum; Morlex (with chlorpropham & fenuron & propham); NC 8438; Nortron; Tramat

2-ethoxy-2,3-dihydro-3,3-dimethyl-5-benzofuranyl methanosulphonate

CAS # 26225-79-6

miscellaneous

herbicide

non-pers

oral: low (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: low to medium (2)

 fish: low (2)

 crustaceans: low (2)

water: soluble

slightly volatile

ethoprop

ethoprophos; Jolt; Mocap; prophos; V-C-9-104

0-ethyl S,S-dipropyl phosphorodithioate

CAS # 13194-48-4

organophosphate

insecticide, nematocide

mod-pers (1)

oral: high to very high (1,2)

dermal: very high (2)

inhalation: very high (2)

suspect mutagen (2)

immediate toxicity:

 birds: high to very high (3)

 fish: medium to very high (2)

 crustaceans: very high (2)

volatile

ethoxyquin

ethoxyquine (France); Nix-Scald; Santoquin; Stop-Scald

6-ethoxy-1,2-dihydro-2,2,4-trimethylquinoline;

1,2-dihydro-6-ethoxy-2,2,4-trimethylquinoline

CAS #91-53-2

miscellaneous

fungicide

?

oral: medium (1)

dermal: ?

inhalation: ?

suspect carcinogen (2,3)

suspect mutagen (4)

combustible

ethyl formate

ethyl methanoate

CAS # 109-94-4

alcohol

fumigant

?

oral: medium (1)

dermal: ?

inhalation: low (2)

?

immediate toxicity:

 bees: low to medium (3)

water: slightly soluble flammable

ethyl hexanediol

6-12 Repellent; ethohexadiol; Rutgers 612; Tantoo Bomb

2-ethyl-1,3-hexanediol

CAS # 94-96-2

alcohol

insect repellent

?

oral: low to medium (1,2)

dermal: medium (2)

inhalation: ?

?

water: soluble

volatile

combustible

146 ethylan

Perthane; Q-137; Raid Mothproofer

1,1-dichloro-2,2-bis(p-ethylphenyl)ethane; diethyl diphenyl dichloroethane

CAS # 72-56-0

organochlorine

insecticide

cancelled, most uses, USA, 1980

“mod-pers” (1)

oral: low (2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: very high (3)

 crustaceans: very high (3)

 bees: high (4)

water: “practically insoluble”

oil: “soluble”

ethylene dibromide

Aadibroom; Agrogas; Bromofume; Carboxide; Cartox; Celmide; DM23 Forte; Dowfume EDB; E-D-Bee; EDB; Edesol; Fumo-Gas; Granosan; Iscobrome D; Nemtosol; Nephis; Soilbrom 40; Soilbrom-90EC; Tradiafume; Unifume

1,2-dibromoethane

CAS # 106-93-4

miscellaneous

fumigant insecticide

cancelled, USA, 1989

non-pers to pers (1,2)

oral: high (3)

dermal: high (4)

inhalation: ?

carcinogen (5)

mutagen (2,6)

suspect teratogen (7,8)

liver, kidney, heart, & spleen damage (9)

sperm & egg damage (5)

disulfiram enhances toxic effects of EDB (5)

immediate toxicity:

 birds: high (10)

 fish: medium (11)

long-term toxicity:

 fish: liver & kidney damage (12)

 plants: mutagen (13) bioaccumulates (3)

water: soluble

highly volatile

“nonflammable”

ethylene dichloride

Borer-sol; Brocide; Chlorasol; Destruxol; Di-Chlor-Mulsion; Dutch Liquid; EDC; ethylene chloride

1,2-dichloroethane;

α,β-dichloroethane

CAS # 107-06-2

organochlorine

insect fumigant

?

oral: medium (1) dermal: ? inhalation: ?

carcinogen (2)

suspect mutagen (2,3)

liver and kidney damage (2,4,5)

water: soluble

highly volatile

flammable

ethylene oxide

Anprolene; Carboxide; Cartox (W. Germany); ETC); Etox; Oxirane; Oxyfume; Oxyfume 12; T-Gas

1,2-epoxyethane

CAS # 75-21-8

fumigant fungicide

?

oral: high (1)

dermal: ?

inhalation: ?

carcinogen (2,3)

suspect mutagen (4,5)

nerve damage (6)

testicular atrophy (7)

long-term toxicity:

 plants: mutagen (2)

water: “soluble”

highly volatile

“flammable”

etridiazole

AAterra; Ban-rot (with thiophanate-methyl); Dwell; ethazol; ethazole; Koban; Pansoil; Terra-Coat L 205 (with PCNB); Terra-Coat L21; Terradactyl (with chlorothalonil); Terrazole; Truban

ethyl 3-trichloromethyl-1,2,4-thiadiazol-5-yl ether;

5-ethoxy-3-trichloromethyl-1,2,4-thiadiazole

CAS # 2593-15-9

miscellaneous

fungicide

mod-pers (1)

oral: low to medium (1,2)

dermal: high (3)

inhalation: ?

?

immediate toxicity:

 birds: medium (1)

 fish: low to medium (1)

water: slightly soluble

slightly volatile

flammable

etrimfos

Ekamet; Ekamet ULV; Satisfar

O-6-ethoxy-2-ethylpyrimidin-4-yl O,O-dimethyl phosphorothioate;

O-(6-ethoxy-2-ethyl-4-pyrimidinyl) O,O-dimethyl phosphorothioate

CAS # 38260-54-7

organophosphate

insecticide

non-pers (1)

oral: medium to high (2)

dermal: medium to high (3)

inhalation: low (4)

?

immediate toxicity:

 fish: medium (4)

water: slightly soluble

slightly volatile

EXD

DEX; Herbisan #5; Sulfasan diethyl dithiobis(thioformate); di[ethoxy(thiocarbonyl)] disulfide

CAS # 502-55-6

miscellaneous

herbicide

“non-pers” (1)

oral: medium (2)

dermal: ? inhalation: ?

?

water: insoluble

147 famphur

American Cyanamid 28023; Bo-Ana; Dovip; Famfos; Famophos; Warbex

O,O-dimethyl

  O-[p(dimethylsulfamoyl)phenyl] phosphorothioate

CAS # 52-85-7

organophosphate

insecticide

?

oral: high to very high (1)

dermal: medium to high (1)

inhalation: ?

?

immediate toxicity:

 birds: very high (2)

 secondary poisoning possible (3,4)

fenac

ACPM-673-A; Fenatrol; Kanepar; TCPA; Tri-Fen; Tri-Fene; Trifene

2,3,6-trichlorophenylaceticacid (and sodium salt)

CAS # 85-34-7

organochlorine

herbicide

pers (1)

oral: medium (1)

dermal: low to medium (1)

inhalation: ?

?

immediate toxicity:

 fish: low to medium (2)

 crustaceans: low (2)

 aquatic insects: low (2)

water: soluble

volatile

“nonflammable”

fenaminosulf

BAY 22555; BAY 5072; DAPA; Dexon; diazoben; Lesan; Nemacur O (with isofenphos)

sodium [4-(dimethylamino)phenyl]diazene sulfonate;

sodium p-(dimethylamino) benzendiazosulfonate

CAS # 140-56-7

sulfur

fungicide

registration withdrawn in Canada 1990

mod-pers (1)

oral: high to very high (2,3)

dermal: very high (2)

inhalation: ?

mutagen (4,5)

kidney damage (6)

immediate toxicity:

 birds: very high (7)

 fish: low (8)

 crustaceans: medium (8)

 aquatic insects: low to medium (8)

 bees: low (9)

water: very soluble

oil: “insoluble”

“non-volatile”

fenamiphos

BAY 68138; Inemacury; Nemacur; Nemacur P; phenamiphos

ethyl 3-methyl-4-(methylthio)phenyl (1-methylethyl)phosphoramidate; ethyl 4-methylthio-m-tolyl isopropylphosphoramidate

CAS # 22224-92-6

organophosphate

nematocide

mod-pers (1)

oral: high to very high (2)

dermal: very high (2)

inhalation: ?

?

immediate toxicity:

 birds: very high (2)

 fish: medium to very high (3)

 bees: high (4)

water: soluble

slightly volatile flammable

fenanmol

Bloc; EL-222; Fenzol; Rimidin; Rimidine Plus (with carbendazim & maneb); Rubigan; Transflo

2,4′-dichloro-α-(pyrimidin-5-yl) benzhydryl alcohol;

3-(2-chlorophenyl)-3-(4-chloro- phenyl)-5-pyrimidinemethanol

CAS # 60168-88-9

miscellaneous

fungicide

mod-pers (1)

oral: medium (2)

dermal: ?

inhalation: ?

suspect carcinogen (3)

teratogen (4)

decreased male fertility (5)

immediate toxicity:

 fish: high (1)

water: slightly soluble slightly volatile

fenitrothion

Accothion; Agrothion; BAY 41831; Cyfen; Cytel; Danathion; Debucol; Dicontal Neu (with trichlorfon); Docofen; Fenitox; Fenstan; Folithion; MEP; Novathion; Nuvanol; Pesguard ANS (with tetramethrin); S 5660; Sumimix (with fenpropathrin); Verthion

O,O-dimethyl O-(4-nitro-m-tolyl) phosphorothioate

CAS # 122-14-5

organophosphate

insecticide acaricide

non-pers (1)

oral: medium to high (2)

dermal: high (2)

inhalation: ?

suspect mutagen (3)

suspect viral enhancer, implicated in Reye’s syndrome (4)

behavioral deficits in newborn (5)

immunotoxin (6)

immediate toxicity:

 birds: medium to very high (7)

 fish: medium (8)

 crustaceans: very high (8)

 aquatic insects: very high (8)

 bees: very high (9)

 aquatic worms: medium (10)

water: “practically insoluble” slightly volatile

148contammant(s):

p-nitro-m-cresol

O,O,S-trimethyl phosphorothioate

oral: high (1)

delayed toxicity (1)

O,S,S-trimethyl phosphorodithiote

oral: very high (1)

immunotoxin (1)

fenoxaprop-ethyl

Acclaim; Excel; Furore; Option; Whip

(±)-ethyl 2-[4-[(6-chloro-2-benoxazolyl) oxy]phenoxy] propanoate

CAS # 66441-23-4

miscellaneous

herbicide

non-pers (1,2)

oral: low to medium (3,4)

dermal: ?

inhalation: high (3)

teratogen (5)

immediate toxicity:

 birds: low to medium (2)

 fish: medium to high (3)

 crustaceans: medium (3)

water: insoluble

non-volatile

“flammable”

fenpropathrin

Danitol; fenpropathrine; Herald; Kilumal; Meothrin; Ortho Danitol; Rody; S-3206; SD 41706; Sumimik; Sumimix (with fenitrothion); Viktor (with clofentizine); WL 41706; XE 938

(RS)-α-cyano-3-phenoxybenzyl 2,2,3,3-tetramethylcyclopropanecarboxylate

CAS # 64257-84-7

pyrethroid

insecticide

non-pers (1,2)

oral: high (3)

dermal: ?

inhalation: ?

immunotoxin (4)

immediate toxicity:

 birds: medium (3)

 fish: very high (3)

water: insoluble

slightly volatile

fensulfothion

BAY 25141; Dasanit; DMSP; S 767; Terracur; Terracur P

O,O-diethyl O-[p-methylsulfinyl)phenyl] phosphorothioate

CAS # 115-90-2

organophosphate

insecticide

mod-pers (1)

oral: very high (2)

dermal: very high (1)

inhalation: ?

?

immediate toxicity:

 birds: very high (3)

 fish: medium to very high (4,5)

 bees: very high (6)

water: soluble

fenthion

BAY 29493; Baycid; Bayer 4895; Baytex; DMPT; Ekalux; Entex; Lebaycid; mercaptophos; Quelatox; Queletox; S 1752; Spotton; Talodex; Tiguvon

O,O-dimethyl-O-[4-methylthio]-m-tolyl phosphorothioate; phosphorothioic acid O,O-dimethyl O-3-methyl-4-(methylthio)phenyl

CAS # 55-38-9

organophosphate

insecticide acaricide avicide

restricted use, USA

non-pers (1,2)

oral: medium to high (3)

dermal: high (4)

inhalation: ?

suspect carcinogen (5)

delayed neurotoxin (6)

suspect embryotoxin (7)

neuromuscular dysfunction (8)

eye damage (9,10)

immediate toxicity:

 birds: very high (11)

 fish: medium (3,12)

 crustaceans: high to very high (12)

 bees: very high (14)

 aquatic insects: very high (13)

water: slightly soluble slightly volatile

transformation product(s): sulfoxide analogue of fenthion

oral: high (1)

sulfone analogue of fenthion

oral: high (1)

thirty-six times more toxic than fenthion (2)

fenuron

Beet Kleen (with propham & chlorpropham); Croptex Chrome; Croptex Ruby; Dozer; Dybar; Falisilvan; Fenidim; fenidin (USSR); Fenulon; fenulon (with So. Africa); Gold; Herbon Yellow (with chlorpropham); Karmex FP; Morlex (with chlorpropham & ethofumesate & propham); PDU; PDV; Premalox; Quintex; Urab 1,1-dimethyl-3-phenylurea; 3-phenyl-1,1-dimethylurea

CAS # 101-42-8

urea

herbicide

?

oral: low to medium (1)

dermal: ?

inhalation: ?

suspect mutagen (2)

immediate toxicity:

 fish: low (3)

water: soluble

slightly volatile

149 fenvalerate

Ectrin; Extrin; Fenkill; fenvalethrin; Mikantop (with dimethoate); Moscade; OMS 2000; Pydrin; Pyrid; S-5602; Sanmarton; Sumibac; Sumicidin; Sumicombi (with fenitrothion); Sumifleece; Sumifly; Sumitomo (with fenitrothion); Sumittick; Tirade; WL 43775

(RS)-α-cyano-3-phenoxybenzyl (RS)-2-(4-chlorophenyl)-3-methylbutyrate

CAS # 51630-58-1

pyrethroid

insecticide

mod-pers (1)

oral: ?

dermal: ?

inhalation: ?

cumulative (2)

suspect mutagen (3)

immediate toxicity:

 birds: low (1)

 fish: low to very high (1,4)

marine invertebrates: high to very high (1)

long-term toxicity:

 fish: adverse effects in gill structure (5)

water: insoluble

non-volatile to slightly volatile

ferbam

Black Fungicide; Carbamate; Coromate; ferbame (France); Ferbert; Fermate; Fermocide; Ferradow; Green Cross kerbam; Hexaferb; Karbam Black; Knockmate; Miller Blue Mold Dust; New Leaf Black Fungicide; Niagar Carbamate; Planters Blue Mold Dust; Sup’r-Flo Ferbam Flowable; Trifungol; Vancide FE 95

iron tris(dimethyldithiocarbamate); ferric dimethyldithiocarbamate

CAS # 14484-64-1

thiocarbamate

fungicide

non-pers (1)

oral: low to medium (2)

dermal: ?

inhalation: ?

suspect mutagen (3,4) suspect fetotoxin (4,6) kidney damage (5)

sperm damage (7)

immediate toxicity:

 fish: medium to high (1)

 bees: low to medium (8)

long-term toxicity:

 birds: affects fertility (9)

 fish: blindness and fin erosion (1); embryotoxic (10)

 molluscs: “inhibits shell growth” (1)

 plants: inhibits germination of pollen in some plants (10)

water: soluble

non-volatile to slightly volatile

transformation product(s):

carbon disulfide

(see carbon disulfide)

N-nitrosodimethylamine

oral: very high (1)

carcinogen (2,3) mutagen (1,3) liver damage (1)

long-term toxicity:

 molluscs: may cause reproductive & gastrointestinal damage (4)

 water: “soluble” oil: “soluble”

“volatile”

“nonflammable”

ferrous sulfate

Aitkens Lawn Sand Plus (with chloroxuron); Ashlade D-Moss (with chloroxuron); copperas; green vitriol; iron protosulfate; iron vitriol; SHL Turf Feed & Weed (with dichlorprop & MCPA)

iron(II) sulfate;

iron(2+)sulfate

CAS # 7720-78-7

metal/mineral

herbicide wood preservative

?

oral: medium (1)

dermal: ?

inhalation: ?

?

water: soluble

flamprop-isopropyl

Barnon Plus; Commando; Effix; flamprop-M-isopropyl; Lancer; Mataven; Suffix BW; Super Barnon; Supper Suffix; WL 28651; WL 43423; WL 43425

isopropyl N-benzoyl-N-(3-chloro-4-fluorophenyl)-d-alanine

CAS # 63782-90-1

miscellaneous

herbicide

?

oral: low to medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: low (1)

 fish: medium (1)

 bees: “nontoxic” (1)

water: slightly soluble

slightly volatile

150 fluazifop-butyl

Fusilade; Fusilade 2000; Fusilade Five; Fusilade Super; Grass-B-Gone; Hache Uno Super; Onecide; PP009; Tornado (with fomesafen); TS-7236

butyl 2-[4-[[5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]propananoate; 2-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy] propionic acid

CAS # 69806-50-4

phenoxy

herbicide

non-pers to mod-pers (1,2)

oral: medium (3,4)

dermal: low to medium (4)

inhalation: ?

?

immediate toxicity:

 birds: low (4)

 fish: high (4)

water: slightly soluble

slightly volatile

“nonflammable”

fluchloralin

BAS-392-H; Basalin

N-(2-chloroethyl)-α,α,α-trifluoro-2,6-dinitro- N-propyl-p-toluidine;

N-(2-chloroethyl)-2,6-dinitro-N-propyl-4-(trifluoromethyl)aniline;

N-(2-chloroethyl)-2,6-dinitro-N-propyl-4-(trifluoromethyl)benzenamine

CAS # 33245-39-5

dinitroaniline

herbicide

?

oral: low to medium (1,2)

dermal: ?

inhalation: medium (2)

?

immediate toxicity:

 birds: low to medium (2)

 fish: very high (2)

water: slightly soluble

slightly volatile to volatile

flammable

flucythrinate

AC 222,705; AI3 29391; Cyanotril (with dimethoate); Cybolt; Cythrin; Flutrin (with dimethoate); Kiedex; Lepister (with chlorpyrifos); OMS 2007; Pay-Off M (with methomyl)

(RS)-α-cyano-3-phenoxybenzyl

(S)-2-(4-difluoromethoxyphenyl)-3-methylbutyrate

CAS # 70124-77-5

pyrethroid

insecticide

non-pers to mod-pers (1,2)

oral: high (3)

dermal: high (3)

inhalation: very high (4)

?

immediate toxicity:

 fish: very high (5)

 crustaceans: very high (1)

water: insoluble non-volatile

fluenethyl

Flu; Fluenyl; Lambrol; M 2060

2-fluoroethyl (4-biphenyl)acetate; 2-fluoroethyl 4-biphenylacetate;

2-fluoroethyl [1,1′-biphenyl]-4-acetate

CAS # 4301-50-2

miscellaneous

insecticide acaricide

not registered, USA

?

oral: high to very high (1,2)

dermal: very high (2)

inhalation: ?

?

immediate toxicity:

 bees: medium (3)

transformation product(s):

monofluoroacetic acid

the active principle in sodium fluoroacetate (see chart for details)

CAS # 144-49-0

flufenoxuron

Cascade; WL 115110

1-[4-(2-chloro-α,α,α-trifluoro-p-tolyloxy)-2-fluorophenyl]-3-(2,6-difluorobenzoyl)urea;

N-[[[4-(2-chloro-4-(trifluoromethyl)phenoxy]-2-fluorophenyl]amino]carbonyl]-2,6-difluorobenzamide

CAS # 101463-69-8

urea

insecticide

non-pers to mod-pers (1)

oral: low to medium (1)

dermal: low to medium (2)

inhalation: medium (1)

?

immediate toxicity:

 birds: low to medium (1)

 fish: low (1)

water: insoluble non-volatile

151 fluometuron

C-2059; Ciba 2059; Cotogard (with prometryn); Cotoran multi (with metolachlor); Cotoran Multi 50WP; Cottonex; Croak (with MSMA); Higalcoton; Lanex; Meuturon 4L; Pakhtaran; Zorial

1,1-dimethyl-3-(α,α,α-trifluoro-m-tolyl)urea; 3-(m-trifluoromethylphenyl)-1,1-dimethyl ureal

CAS # 2164-17-2

urea

herbicide

non-pers to mod-pers (1,2)

oral: low to medium (1,2)

dermal: ?

inhalation: ?

spleen damage (3)

blood damage (4)

immediate toxicity:

 fish: low (1,2)

 bees: low (5)

water: slightly soluble to soluble

slightly volatile

“nonflammable”

fluoroacetamide

1081; Baran; Compound 1081; Fluorakil 100; Fussol (with; Megatox; Yanock

2-fluoroacetamide

CAS # 640-19-7

fluoroacetate

rodenticide

cancelled USA, 1989

?

oral: very high (1)

dermal: very high (1)

inhalation: ?

less toxic than fluoroacetate (1)

?

immediate toxicity:

 birds: high (2)

long-term toxicity: secondary poisoning in some species (1)

water: “very soluble”

transformation product(s):

fluorocitrate

transformation product of fluoroacetate

L-erythro-fluoro-citrate causes the toxicity (1)

kidney damage (2)

inhibits essential enzymes in energy (ATP) production; leads to organ & system failures (3,4)

fluorodifen

C-6989; fluorodiphen; Preforan; Soyex

p-nitrophenyl α,α,α-trifluoro-2-nitro-p-tolyl ether;

2-nitro-1-(4-nitrophenoxy)-4-(trifluoromethyl) benzene

CAS # 15457-05-3

phenol

herbicide

non-pers to mod-pers (1)

oral: low (2)

dermal: low to medium (2)

inhalation: ?

?

immediate toxicity:

 bees: low (3)

water: slightly soluble

non-volatile

flurecol-butyl

Aniten (with MCPA); Florencol; flurecol-n-butylester (USA, Great Britain, So. Africa); flurenol; flurenol-n-butylester; IT-3223

n-butyl 9-hydroxyfluorene-9-carboxylate;

9-hydroxyfluorene-9-carboxylic acid butyl ester

CAS # 467-69-6

miscellaneous

herbicide

?

oral: low (1)

dermal: low to medium (2)

inhalation: ?

?

immediate toxicity:

 fish: medium (3)

water: slightly soluble

oil: soluble

slightly volatile

fluridone

Brake; Compel; E1-171; Pride; Sonar; Sonar 5P; Sonar A5

1-methyl-3-phenyl-5-(trifluoro-m-tolyl)-4-pyridone

CAS # 59756-60-4

miscellaneous

herbicide

non-pers to mod-pers (1,2)

oral: low (3)

dermal: ?

inhalation: medium (2)

?

immediate toxicity:

 birds: medium (2)

 fish: low to medium (2)

 crustaceans: medium (2)

water: slightly soluble

non-volatile

transformation product(s):

monomethylformamide

n-monomethylformamide

CAS # 123-39-7

teratogen (1)

152 flusilazole

DPX-H 6573; Nustar; Olymp; Punch (with carbendazim); Start (with pyrazophos)

bis(4-flurophenyl)(methyl)(1 H-1,2,4-triazol-]- ylmethyl]silane;

1-[[bis(4-flurophenyl)(methyl) silyl]methyl]-1 H-1,2,4-triazole

CAS # 85509-19-9

triazole

fungicide

?

oral: medium (1)

dermal: low to medium (2)

inhalation: low to medium (1)

?

water: slightly soluble to soluble

volatile

fluvalinate

Klartan; Mavrik; Spur

(RS)-α-cyano-3-phenoxybenzyl (R-2-(2-chloro-α,α,α-trifluoro-p-toluidino)-3-methylbutyrate

CAS # 69409-94-5

pyrethroid

insecticide acaricide

non-pers to mod-pers (1)

oral: high

(2) dermal: low (2)

inhalation: ?

?

immediate toxicity:

 birds: low (1)

 fish: medium to high (1)

 freshwater invertebrates: low to medium (1)

water: insoluble

non-volatile to slightly volatile

t -fluvalinate

Amalux (with quinalphos); Apistan; Klartan; Mavrik 2E; Mavrik 2F; Mavrik HR; Spur; Torero (with clofentezine)

(RS)-α-cyano-3-phenoxybenzyl N-(2-chloro-α, α,α trifluoro-p-tolyl-d-valinate

CAS # 102851-06-9

pyrethroid

insecticide

non-pers (1)

oral: ?

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: very high (1)

 crustaceans: very high (1)

folpet

Folnit; Folpan; Folplan; Folprame (with copper oxychloride); Folsystem; Foltan; Foltapet (with captafol); Foltazip; Foltene; Foltimil (with copper sulphate)

trichloromethylthiophthalimide;

N-(trichloromethylthio)phthalimide

CAS # 133-07-3

phthalate

fungicide

?

oral: low (1)

dermal: low to medium (2)

inhalation: medium to high 92)

carcinogen (2) suspect mutagen (2)

teratogen (3,4)

immediate toxicity:

 birds: low to medium(5)

 fish: high to very high (6)

 crustaceans: medium (6)

 bees: low to medium (7)

 phytoplankton: high (8)

 plants: may be toxic to some (9)

long-term toxicity:

 birds: teratogen (8)

water: slightly soluble

slightly volatile

fomesafen

Dardo; Flex; PP 021; Reflex; Reflex T (with terbutryn); Tornado (with fluazifop-butyl)

5-(2-chloro-α,α,α-trifluro-p-tolyloxy)- N-mesyl-2-nitrobenzamide; 5-(2-chloro-α,α,α-trifluro-p-tolyloxy)-N-methylsulfonyl-2-nitro benzamide;

5-[2-chloro-4-(trifluromethyl) phenoxy]-N-(methylsulfonyl)-2-nitrobenzamide

CAS # 72178-02-0

amide

herbicide

non-pers to mod-pers (1)

oral: low to medium (1,2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: low (3)

 fish: low (1)

water: slightly soluble

slightly volatile

“nonflammable”

fonofos

Admiral; Capfos; Cudgel; Doubledown (with disulfoton); Dyfonate; Metro; N-2790

O-ethyl S-phenyl (RS)-ethyl phosphonodithioate;

O-ethyl S-phenyl ethylphosphonodithioate

CAS # 944-22-9

organophosphate

insecticide

non-pers to mod-pers (1,2)

oral: very high (2,3)

dermal: high to very high (1,2)

inhalation: high (4)

?

immediate toxicity:

 birds: high to very high (4)

 fish: very high (4)

water: slightly soluble

slightly volatile

153 formaldehyde

BFV; D&P 77 Dust; Dyna-Form; Formalin; Formalina; formic aldehyde; Karsan; methanal; methylene oxide; oxomethane; oxymethylene; Victoria

methyl aldehyde

CAS # 50-00-0

aldehyde

fungicide herbicide

?

oral: medium (1)

dermal: low to medium (2)

inhalation: high (1)

carcinogen (2,3)

suspect mutagen (2,4)

liver damage (5)

water: “very soluble”

“flammable”

transformation product(s):

formic acid

CAS #64-18-6

eye damage (1)

paraformaldehyde

(see paraformaldehyde)

formetanate hydrochloride

Carzol; Dicarzol; EP 332; Fundal Forte (with chlordimeform); Schering 36056; SN 36056

N,N-dimethyl-N′-[3-[[(methylamino)carbonyl]oxy] phenyl]methanimidamide;

(3-dimethylamino-(methyleneiminophenyl)- N-methylcarbamate hydrochloride

CAS # 23422-53-9

carbamate

acaricide insecticide

non-pers (1,2)

oral: very high (1)

dermal: low to medium (2)

inhalation: medium to high (1)

?

immediate toxicity:

 birds: very high (1)

 fish: low to medium (1)

 crustaceans: very high (1)

 bees: medium (3)

water: very soluble

non-volatile

fosamine ammonium

DPX 1108; Krenite Brush Control Agent; Krenite S

ammonium ethyl carbamoyl phosphonate

CAS # 25954-13-6

carbamate

herbicide

non-pers to mod-pers (1,2)

oral: low to medium (3)

dermal: ?

inhalation: low (1)

?

immediate toxicity:

 birds: low to medium (1)

 fish: low (1)

long-term toxicity:

 birds: teratogen (4)

water: very soluble

slightly volatile

combustible

fosetyl-al

Aliette; Aliette Extra (with captan & thiabendazole); Mikal (with folpet); Rhodex (with mancozeb)

aluminum tris (o-ethylphosphonate)

CAS # 39148-24-8

organophosphate

fungicide

more persistent on foliage than in soil (1)

oral: low (1)

dermal: ?

inhalation: ?

suspect carcinogen (1)

degenerative effecst on testes (1)

delayed fetal development (1)

changes in urinary tract development (1)

immediate toxicity:

 birds: low (2)

 fish: low (2)

 bees: low (1)

water: soluble non-volatile

GC 6506

GC 6506

O,O-dimethyl O-(4-methylmercaptophenyl)phosphate; dimethyl p-(methylthio)phenyl phosphate

CAS # 3254-63-5

organophosphate

insecticide acaricide

?

oral: very high (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 bees: “highly toxic to bees” (1)

154 glyphosate

CP67573; Fallow Master (with dicamba); Landmaster (with 2,4-D); Mon 0573

N-(phosphonomethyl)glycine

CAS # 1071-83-6

miscellaneous

herbicide

mod-pers (1,2)

oral: medium (3,4)

dermal: medium (3)

inhalation: ?

suspect carcinogen (4)

suspect mutagen (5)

immediate toxicity:

 birds: low (6)

 fish: low to medium (6)

 crustaceans: low to medium (7)

 bees: low (6)

long-term toxicity:

 plants: mutagen (8)

water: soluble

oil: insoluble

non-volatile

salt(s):

glyphosate trimesium

Touchdown

CAS # 81591-81-3

isopropylamine salt of glyphosate

Pondmaster; Rattler; Rodeo; Roundup; Roundup L&G; Shackle; Shacklet C; Spasor; Sting; Vision

N-(phosphomethyl)glycine, isopropylamine salt

CAS # 38641-94-0

sodium salt of glyphosate

Polado

N-(phophonomethyl)glycine, sodium salt

CAS # 70393-85-0

transformation product(s):

formaldehyde

(see formaldehyde)

N-nitrosoglyphosate

(in contact with nitric acid)

mod-pers (1)

suspect carcinogen (1)

suspect mutagen (1)

surfactant:

polyoxyethyleneamine

”LD50 of POEA is less than 1/3 that of…. (glyphosate)” (1)

immediate toxicity:

 fish: medium to high (2,3)

contaminant of surfactant:

1,4-dioxane

p-dioxane

CAS # 123-91-1

carcinogen (1)

155 heptachlor

Drinox H-34; E-3314; heptachlore (France); Heptagran; Heptamul; Termide; Velsicol 104

heptachlorotetrahydro-4,7-methanoindene; 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a- tetrahydro-4,7-methanoindene

CAS # 76-44-8

organochlorine

insecticide

1984: only use of chlordane/heptachlor permitted in US is fire ant control in power transformers

mod-pers to pers

oral: high

dermal: high to very high

inhalation: low to high

more toxic than chlordane in animals (see chlordane)

readily absorbed through skin

carcinogen liver damage

may cause cataracts

immediate toxicity:

 fish: high to very high

 amphibians: high

 crustaceans: high to very high

 bees: very high

 aquatic insects: very high

long-term toxicity:

 sea urchins: embryotoxin

water: insoluble

slightly volatile to volatile

transformation product(s):

heptachlor epoxide

Compounds 53-CS-17; Velsicol

2,3,4,5,6,7,7-heptachloro-1a,1b,5,5a,6,6a-hexahydro-2,5-methano-2H-

indeno[1,2-b]oxirene

CAS # 1024-57-3

?

oral: high

dermal: ?

inhalation: ?

more toxic than heptachlor

cumulative carcinogen

water: insoluble

oil: “lipophilic”

hydrogen chloride

(see dienochlor)

carbon monoxide

(see methylene chloride)

hexachlorobenzene

Anti-Carie; Anticarie; HCB; No Bunt; perchlorobenzene

1,2,3,4,5,6-hexachlorobenzene

CAS # 118-74-1

organochlorine

fungicide insecticide

cancelled in USA

pers (1,2)

oral: medium (7)

dermal: ?

inhalation: ?

cumulative (3,4)

carcinogen (1,5)

teratogen (6)

fetotoxin (1)

liver damage (3,7)

nerve damage (8,9)

thyroid damage (10,11)

immunotoxin (12,13)

porphyria cutanea tarda (7)

crosses placenta (6)

immediate toxicity:

 fish: low to medium (14)

long-term toxicity:

biomagnification (15)

 birds: reduced hatchability, reproductive damage, liver damage (2,6)

 fish: cumulative, liver & kidney damage (2,14)

 crustaceans: cumulative (14)

water: insoluble

oil: “lipophilic”

slightly volatile to volatile

pentachlorobenzene

CAS # 608-93-5

oral: high (1)

octachlorodibenzo-p-dioxin

OCDD

octachlorodibenzo-p-dioxin

CAS # 3268-87-9

dibenzo-dioxin

non-pers to mod-pers (1)

cumulative (1)

acne (2)

water: insoluble

non-volatile

transformation product(s):

pentachlorophenol

(see pentachlorophenol)

pentachlorobenzene

CAS # 608-93-5

oral: high (1)

156 hexachlorophene

Hexide; Nabac; Seribak

2,2′-methylene bis(3,4,6-trichlorphenol); dihydroxy hexachlorodiphenyl methane

CAS # 70-30-4

organochlorine

fungicide antibiotic acaricide

cancelled, all products, USA, 1983

?

oral: high (1)

dermal: ?

inhalation: ?

suspect teratogen (2,3)

neurotoxin (4,5)

immediate toxicity:

 birds: medium (6)

water: insoluble oil: “soluble”

contaminant(s):

TCDD

(see chloroneb)

hexazinone

Velpar; Velpar Gridmall; Velpar K (with diuron)

3-cychlohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4-(1H,3H)-dione;

3-cyclohexyl-6-(dimethylamino)-1-methyl-5-triazine-2,4(1H,3H)-dione

CAS # 51235-04-2

triazine

herbicide

non-pers to mod-pers (1,2)

oral: medium (2)

dermal: low to medium (3)

inhalation: low to medium (4)

suspect teratogen (4)

immediate toxicity:

 birds: medium (4)

 fish: low (4)

 crustaceans: low (4)

water: very soluble

slightly volatile

“nonflammable”

hydramethylnon

Amdro; Arinosu-Korori; Blatex; Combat; Cyaforce; Cyclon; Impact; Matox; Maxforce; pyrimidinone; Wipeout

tetrahydro-5,5-dimethyl-2(1 H)- pyrimidinone[3-[4-(trifluoromethyl)phenyl]-

1-[2-[4-(trifluoromethyl)phenyl]ethenyl]-

2-propenylidene]hydrazone; 5,5-dimethylperhydropyrimidin-2-one 4-trifluoromethyl-α-(4-trifluoromethylstyryl) cinnamylidenehydrazone

CAS # 67485-29-4

miscellaneous

insecticide

non-pers (1)

oral: medium (2)

dermal: ?

inhalation: ?

suspect carcinogen (3)

immediate toxicity:

 fish: high to very high (1)

water: insoluble combustible

hydrogen cyanide

Cyclon; HCN; prussic acid

hydrocyanic acid

CAS # 74-90-8

cyanide

fumigant insecticide

restricted use, USA

?

oral: very high (1)

dermal: “extremely toxic” (2)

inhalation: “intensely poisonous” (3)

?

water: “soluble” flammable

salt(s):

calcium cyanide

A-Dust; Cyanogas; Degesch Calcium Cyanide A-Dust

CAS # 592-01-8

organic

fumigant insecticide rodenticide

restricted use, USA

oral: very high (1)

sodium cyanide

(see sodium cyanide)

imazamethabenz

Assert; Dagger

(+)-2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1 H- imidazol-2-yl]-4-methyl benzoic acid(ii) with (+)-2-2[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1 H- imidazol-2-yl]-5-methylbenzoicacid (i)

CAS # 100728-84-5

miscellaneous

herbicide

non-pers to mod-pers (1)

oral: low (1)

dermal: ?

inhalation: low to medium (1)

?

immediate toxicity:

 birds: medium (1)

 fish: low (1)

 crustaceans: low (1)

water: slightly soluble

non-volatile

combustible

157 imazapyr

Arsenal; Assault; Chopper; Contain

2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)nicotinicacid

CAS # 81334-34-1

miscellaneous

herbicide

mod-pers to pers (1,2)

oral: low to medium (1,2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: low to medium (1)

 fish: low (1)

 crustaceans: low (1)

water: “soluble”

combustible

salt(s):

ammonium salt of imazapyr

2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)nicotinic acid, ammonium salt

CAS #81510-83-0

imidazolinone

herbicide

?

oral: low (1)

dermal: ?

inhalation: ?

?

water: very soluble

ioxynil

ACP-63303; Actril; Actril DS (with 2,4-D); Actril S (with bromoxynil & dichlorprop & MCPA); Axall (with bromoxynil & mecoprop); Banlene Solo (with dicamba & dichlorprop); Bantrol; Basagran Ultra (with bentazon & dichlorprop); Bentrol; Bio Lawn Weedkiller (with 2,4-D & dicamba); Brittox (with bromoxynil & mecoprop); Certrol; Dantril (with bromoxynil & dichlorprop); MB-8873; Oxytril 4 (with dichlorprop & bromoxynil & MCPA); Oxytril CM (with bromoxynil); Oxytril P (with dichlorprop & bromoxynil); Totril; toxynil (Europe)

4-hydroxy-3,5-diiodobenzonitrile;

3,5-diiodo-4-hydroxybenzonitrile

CAS # 1689-83-4

benzonitrile

herbicide

not registered for use in U.S.A.

non-pers (1)

oral: high (1)

dermal: high (2)

inhalation: ?

?

immediate toxicity:

 birds: high (1)

 fish: medium (1)

water: slightly soluble

“nonflammable”

iprodione

Chipco-26019; glycophene; Kidan; Rovral

3-(3,5-dichlorophenyl)-N-(1-methylethyl)-2,4-dioxo-1-imidazolidine carboxamide

CAS # 36734-19-7

amide

fungicide

mod-pers (1)

oral: medium (1)

dermal: low to medium (2)

inhalation: low to medium (1)

?

immediate toxicity:

 birds: low to medium (3)

 fish: medium (2)

 crustaceans: low to high

(4)

water: slightly soluble

non-volatile to slightly volatile

combustible

isazophos

CGA-12223; Miral; Triumph

O-(5-chlro-1-methylethyl)-1 H-1,2,4-triazol-3-yl O,O-diethyl phosphorothioate

CAS # 42509-80-8

organophosphate

insecticide nematocide

?

oral: high to very high (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: high (1)

water: soluble

isofenphos

Amaze; BAY 9214; BAY SRA 12869; Carma (with carbofuran); Disyston O (with disulfoton); Nemacur O (with fenaminophos); Oftanol; Oftanol Combi (with phoxim); Oftanol T (with thiram)

1-methylethyl 2-[ethoxy[(1-methylethyl) amino]phosphinothioyl]oxy]benzoate

CAS # 2531 1-71-1

organophosphate

insecticide

mod-pers (1)

oral: high to very high (2)

dermal: high to very high (3)

inhalation: high (2)

delayed neurotoxicity, irreversible demyelination, paralysis (4,5)

immediate toxicity:

 birds: very high (6)

 fish: high (2)

long-term toxicity:

 birds: delayed neurotoxicity (7)

water: slightly soluble

slightly volatile

158 isopropalin

4-isopropyl-2,6-dinitro-N, N

dipropylanihne; 4-(1-methylethyl)-2,6-dinitro-

N,N-dipropylbenzanamine

CAS # 33820-53-0

dinitroaniline

herbicide

?

oral: low (1)

dermal: low to medium (2)

inhalation: ?

?

immediate toxicity:

 fish: very high (3)

water: insoluble

slightly volatile

flammable

contaminant(s):

dipropylmtrosamine

carcinogen (1)

isoxaben

AZ 500; Cent-7; Combat; Elset; Flexidor; Gallery; Knock Out; Ratio; Snapshot 80 (with oryzalin); X-Pand

N-[3-(1-ethyl-1-methylpropyl)-5-isoxazolyl]-2,6-dimethoxybenzamide

CAS # 82558-50-7

amide

herbicide

pers (1)

oral: low (1)

dermal: ?

inhalation: ?

carcinogen (1)

long-term toxicity:

 birds: reduces hatchability of eggs (1)

 fish: bioaccumulates (1)

water: slightly soluble

slightly volatile

“nonflammable”

kadethrin

AI3-29 117; Kadethrin; RU 15 525; Spray-Tox

5-benzyl-3-furylmethyl (E-(1R)-cis-2,2-dimethyl-3-(2-oxothiolan-3-ylidenemethyl)cyclopropanecarboxylate;

[1R-[1α,3α(E)]]-[5-(phenylmethyl)-3-furany]methyl 3-[(dihydro-2-oxo-3(2H)-thienylidene)methyl-2,2-dimethyl cyclopropanecarboxylate

CAS # 58769-20-3

pyrethroid

insecticide

?

oral: medium (1)

dermal: ?

inhalation: ?

?

?

leptophos

Abar; Lepton; Phosvel; VCS-506

O-(4-bromo-2,5-dichlorophenyl) O-methylphenylphosphonothioate

CAS # 21609-90-5

organophosphate

insecticide

?

oral: high to very high (1,2)

dermal: high to very high (2)

inhalation: ?

delayed neurotoxin (1)

immediate toxicity:

 birds: medium (1)

 fish: very high (3)

 bees: high (4)

long-term toxicity:

 birds: delayed neurotoxin (1)

water: slightly soluble

transformation product(s):

desbromoleptophos

more neurotoxic than leptophos (1)

d-limonene

Aacess Penetrator; cajeputene; cinene; Dipentene; kautschin

1-methyl-4-(1-methylethenyl) cyclohexene

CAS # 5989-27-5

miscellaneous

insecticide

?

oral: low (5)

dermal: ?

inhalation: ?

suspect carcinogen (1)

suspect teratogen (2,3)

immunotoxin (4)

kidney damage (3)

water: “practically insoluble”

159 lindane

Aficide; Agrocide; Asparasin; BBH; Bexol; Borer Kill; Detox 25; Forlin; gamma isomer of BHC; gamma-BHC; gamma-HCH (Gr. Britain); Gammaspra; Gammcide; Gexane; Isotox; Jacutin; Kwell; Lindagam; Lindaterra; Lintox

gamma isomer of benzene hexachloride;

1,2,3,4,5,6-hexachlorocyclohexane

CAS # 58-89-9

organochlorine

insecticide

cancelled, most uses, USA, 1983

pers (1)

oral: high to very high (2)

dermal: high (2)

inhalation: ?

cumulative (2,3)

carcinogen (4,5)

suspect mutagen (2)

teratogen (2)

hormone damage (6)

testicular damage (7)

immunotoxin (2,8)

neurotoxin (9,10)

aplastic anemia (11)

bone marrow damage (12)

BIOCIDE

immediate toxicity:

 birds: medium to high (13)

 fish: very high (14)

 amphibians: medium(15)

 crustaceans: very high(14)

 earthworms: low (15)

 aquatic worms: high(16)

 bees: very high (17)

 toxic to some plants and phytoplankton (15)

long-term toxicity:

 birds: reduced egg production; eggshell thinning (19)

 fish: liver damage, behavioral changes (20)

 amphibians: teratogen (21)

 plants: mutagen (18)

water: slightly soluble

oil: “slightly soluble” slightly volatile combustible

transformation product(s):

hydrogen chloride

hydrochloric acid

hydrogen chloride

CAS # 7647-01-0

oral: low (1)

2,4,6-trichlorophenol

(see 2,4,6-trichlorophenol)

benzene

(see benzene)

pentachlorobenzene

CAS # 608-93-5

oral: high (1)

cumulative (1)

pentachlorophenol

(see pentachlorophenol)

phosgene gas

(see carbon tetrachloride)

linuron

Gemini (with chlorimuron); Hoe 2810; Lextra (with trifluralin); Linurex; Lorox; Sarclex

3-(3,4-dichlorophenyl)-1-methoxy- 1-methylurea;

N-(3,4-dichlorophenyl)-N′-methoxy-N′-methylurea

CAS # 330-55-2

urea

herbicide

mod-pers (1)

oral: medium (1)

dermal: ?

inhalation: ?

suspect carcinogen (2)

immediate toxicity:

 fish: medium (1)

 bees: low (3)

long-term toxicity:

 plants: mutagen (4)

water: slightly soluble

slightly volatile

“nonflammable”

transformation product(s):

TCAB

TCAB

3,4,3′,4′-tetrachloroazobenzen e structure is analogous to TCDD (see under 2,4,5-T)

CAS # 14047-09-7

also a component of diuron

suspect mutagen (1,2)

chloracne & hyperkeratosis (3)

magnesium phosphide

Detiaphos Pellets; Magtoxin Round Tablets; Phostoxin Plates

magnesium phosphide

CAS # 12057-74-8

metal/mineral

magnesium

fumigant

restricted use, USA

?

oral: ?

dermal: ?

inhalation: ?

?

water: “sparingly soluble”

“spontaneously flammable in oil”

transformation product(s):

phosphine gas

(see aluminum phosphide)

malathion

AC 4049; Carbofos; Cythion; Cyuthion; EmmatosAC 4049; For-Mal; Fyfanon; Kop-Thion; Kypfos; Malagram; Malakill; Malamar; Malaphos; Malatal; Malathiozoo; Malaude; Maimed; mercaptothion (South Africa); MLT; Zithiol

O,O-dimethyl S-(1,2-dicarbethoxyethyl) dithiophosphate;

O,O-dimethyl dithiophosphate of diethyl mercaptosuccinate

CAS # 121-75-5

organophosphate

insecticide

non-pers (1)

oral: medium to high (2)

dermal: medium to high (2)

inhalation: medium (2)

suspect mutagen(3)

suspect teratogen (4)

delayed

neurotoxin (5)

allergic reactions (6)

behavior effects (5)

ulcers,

 gastrointestinal inflammation (7)

damage to eyesight (8)

abnormal brain waves (9)

immunosuppression (10)

BIOCIDE

immediate toxicity:

 birds: medium to high (11)

 fish: medium to high (12)

 bees: very high; nectar of treated plants toxic (13)

 amphibians: very high (12)

 crustaceans: medium to very high (12)

 aquatic worms: medium (13)

 earthworms: high (12)

 aquatic insects: very high (12)

water: soluble

oil: “limited solubility in petroleum oils”

slightly volatile to volatile flammable

ester(s):

diethyl fumarate

2-butenedioc acid, diethyl ester

CAS # 623-91-6

oral: medium (1)

synergistic with malathion

transformation product(s):

malaoxon

dimethoxyphosphinylthiodiethyl ester of butandioic acid

CAS # 1634-78-2

non-pers (1)

carcinogen (2)

ulcers (3)

O,O,S-trimethyl phosphorothioate

oral: high (1)

delayed toxicity (1)

161 mancozeb

Acarie; Blecar MN; Crittox MZ; Delsene MX 200 (with carbendazim); Dithane M-45; Fore; FT 2M (with Bordeaux mixture); Fubol (with metalaxyl); Furado; Galben (with benalaxyl); Galben M (with benalaxyl); Mancobleu (with copper oxychloride); Manzate 200; manzeb; Manzin; Mycodifol MZ (with folpet); Rhodex (with fosetyl-al); Tedane Extra (with dicofol & dinocap); Turbair Dicamate (with zineb); Vondozeb

zinc ion & manganese ethylene bisdithiocarbamate

CAS # 8018-01-7

thiocarbamate

fungicide

cancelled, most products, USA

non-pers to mod-pers (1,2)

oral: low (1)

dermal: low to medium (3)

inhalation: ?

?

immediate toxicity:

 birds: low to medium (2)

 bees: low (4)

 fish: high to very high (2)

long-term toxicity:

 plants: inhibits germination of pollen in some plants (5)

water: slightly soluble

combustible

transformation product(s):

ethylene thiourea

(see amobam)

maneb

Bolda (with sulfur & carbendazim); Chem-Neb; Clortosip (with chlorothalonil & copper oxychloride); CR-3029; Delsene M (with carbendazim); Dithane M-22; Kypman 80; Lonocol M; M-Diphar; Maneba; manebe (France); Manebgan; Manebza; Manesan; Manex; Manzate; Manzati; Manzin; MEB; MnEBD; Remasan; Rimidine Plus (with carbendazim & fenarimol); Ronilan M (with vinclozolin); Sopranebe; Stannophus; Sup’R Flo; Tersan LSR; Tersane LSR; Trimangol; Tubothane; Turf Fungicide; Unicrop; Vancide; Zyban

manganese ethylenebisdithiocarbamate

CAS # 12427-38-2

thiocarbamate

fungicide

cancelled, most products, USA

mod-pers (1,2)

oral: low to medium (3,4)

dermal: ?

inhalation: low to medium (5)

suspect teratogen (6,7)

immediate toxicity:

 bees: low to medium (8)

water: soluble

transformation product(s):

carbon disulfide

(see carbon disulfide)

ethylene thiourea

(see amobam)

MBT

Captax; Dermacid; Mertax; Niocides; Sulfadene; Thiotax; Vancide 51 (with sodium dimethyldithiocarbamate)

2-mercaptobenzothiazole;

2-benzothiazolethiol

CAS # 149-30-4

miscellaneous

fungicide

?

oral: medium (1)

dermal: ?

inhalation: ?

liver damage (2)

water: “insoluble”

MCPA

Agroxone; Bordermaster; Extra; Hormotuho; Kilsem; Legumex; Lontrel Plus; Mephanac; metaxon; Methoxane; Rhomene; Rhonox; Shamrox; Springcorn Extra (with dicamba); Springcorn Plus (with dichlorprop); Tetralex-Plus (with dicamba & mecoprop); Tetroxone M (with dichlorprop & bromoxynil & ioxynil); Weed-Rhap LV-4D; Zelan

(4-chloro-2-methylphenoxy)acetic acid;

[(4-chloro-o-tolyl-oxy]acetic acid

CAS # 94-74-6

phenoxy

herbicide

non-pers to mod pers (1,2)

oral: medium (1,2)

dermal: ?

inhalation: ?

suspect teratogen (3)

immediate toxicity:

 birds: low (2)

 fish: low (2)

 fresh water invertebrates: low (2)

 bees: medium (4)

water: soluble

162 mecoprop

Brittox (with bromoxynil & ioxynil); Chipco Turf Fungicide MCPP; CMPP; Compitox; Cornox-Plus; Fettel (with dicamba & triclopyr); Herrifex DS; Hymec; Iso-Cornox; Kilprop; Liranox; MCPP; Mecomec; Mecoper; Mecopex; Mepro; Propenex-Plus; Ronstar (with 2,4-D); Trimec (with dicamba & 2,4-D); Vipex

2-(2-methyl-4-chlorophenoxy)propionic acid;

2-(4-chloro-2-methylphenoxy)propionic acid

CAS # 7085-19-0

phenoxy

herbicide

non-pers (1)

oral: medium (2)

dermal: high (1)

inhalation: low to medium (3)

mutagen (2)

teratogen (2)

immediate toxicity:

 birds: medium (2)

 fish: low (2)

 bees: low to medium (4)

water: very soluble “nonflammable”

mercury

inorganic forms transpose readily into organic forms, in the body or in the environment, organic forms have high toxicity.

CAS # 7439-97-6

metal/mineral

mercury

fungicide

cancelled, most products, USA

perm

oral: very high (1)

dermal: ?

inhalation: ?

organic forms more toxic than inorganic forms

cumulative (2)

brain, kidney, heart colon and lung damage (2)

neurotoxin (3)

decreased hormone levels (4)

acrodynia syndrome (5)

BIOCIDE

immediate toxicity:

 birds: high to very high (1)

 fish: medium to very high (1)

 amphibians: very high (1)

 molluscs: very high (1)  

 crustaceans: very high (1)

long-term toxicity:

 birds: immunotoxin (6)

bioaccumulates (1)

water: “insoluble” volatile

compound(s):

mercuric chloride

Bical (with mercurous chloride); Calgo-gran (with mercurous chloride); corrosive sublimate; Fungchex (wtih mercurous chloride); mercury chloride; Merfusan; Mersil (with mercurous chloride); Wood Ridge Corrosive Sublimate; Wood Ridge Mixture 21 (with mercurous chloride)

mercury (II) chloride

CAS # 7487-94-7

inorganic

fungicide

oral: very high (1,2)

carcinogen (3)

mutagen (4,5)

teratogen (6,7)

fetotoxin (7)

neurotoxin (8,9)

kidney damage (10,11)

autoimmune disease (12,13)

immediate toxicity:

 birds: high (14,15)

water: soluble

slightly volatile

mercurous chloride

Bical (with mercuric chloride); Calgo-gran (with mercuric chloride); Calo-clor (with mercuric chloride); Calogreen; Calomel; Chlorure; Cyclosan; Fungchex (with mercuric chloride); Mersil (with mercuric chloride)

mercurous chloride;

mercury monochloride

subchloride of mercury

CAS # 7546-30-7

inorganic

insecticide, fungicide

neurotoxin (1)

long-term toxicity:

 plants: “phytotoxic” (2)

water: slightly soluble

163 metalaxyl

Apron; Fubol (with mancozeb); Proturf; Ridomil; Ridomil Plus (with copper oxychloride); Subdue

N-(2,6-dimethylphenyl)-N-(methoxyacetyl)-alanine methyl ester;

N-(2-methoxyacetyl)-N -(2,6-xylyl)-dl-alaninate

CAS # 57837-19-1

fungicide

mod-pers (1)

oral: medium (2)

dermal: low to medium (3)

inhalation: ?

?

immediate toxicity:

 fish: low (2)

water: soluble

metaldehyde

Antimilace; Ariotox; Bug-geta; Cekumeta; Corry’s Slug Death; Halizam; Helarion; Meta; metason; Mifaslug; Namekil; Slug Pellets; Snarol Meal

metacetaldehyde; r-2,c-4,c-6,c-8-tetramethyl-1,3,5,7-tetroxocane; polymer of acetaldehyde

CAS # 108-62-3

aldehyde

molluscicide

restricted USA, 1974

non-pers (1)

oral: medium (2)

dermal: ?

inhalation: ?

spinal damage leading to paralysis in hindquarters (3)

water: soluble

flammable

metam-sodium

A7-Vapam; Carbam; Karbation; Maposol; Soil-Prep

sodium N-methyldithiocarbamate

CAS # 137-42-8

thiocarbamate

fungicide herbicide insecticide nematocide

non-pers (1)

oral: medium to high (2)

dermal: high (2)

inhalation: ?

“may be fatal if swallowed, inhaled, or absorbed through skin” (3)

“inhalation must be prevented” (3)

teratogen (4)

fetotoxin (5)

immediate toxicity:

 birds: medium (3)

 fish: “toxic” (3)

 bees: “nontoxic” (3)

water: very soluble

“non-volatile“

“nonflammable”

transformation product(s):

carbon disulfide

(see carbon disulfide)

methyl isocyanate

(see bendiocarb)

methidathion

GS 13005; Supracide; Utlracide

O,O-diemthylS-[2-methoxy-1,3,4-thiadiazol- 5(4H-onyl-(4)-methyl]phosphorodithioate;

O,O-dimethyl phosphorodithioate, S-ester with 4-(mercaptomethyl)-2-methoxy ∆2-1,3,4-thiodiazolin-5-one

CAS # 950-37-8

organophosphate

insecticide acaricide

non-pers (1)

oral: high to very high (2)

dermal: high (3)

inhalation: ?

suspect mutagen (4,5)

immediate toxicity:

 birds: high to very high (1)

 fish: very high (2)

 bees: very high (6)

water: slightly soluble

slightly volatile

methiocarb

BAY 37344; BAY H-321; Draza; Grandslam; mercaptodimethur; Mesurol; metmercapturon; Ortho Slug-Geta; Slug-M

4-(methylthio)-3,5-xylyl methylcarbamate; 3,5-dimethyl-4-(methylthio)phenol methylcarbmate

CAS # 2032-65-7

carbamate

acaricide insecticide molluscicide bird repellent

non-pers (1)

oral: high to very high (2)

dermal: low to high (2)

inhalation: low to high (3)

?

immediate toxicity:

 birds: high to very high (1)

 fish: medium to high (3)

 aquatic invertebrates: very high (4)

 bees: very high (5)

water: slightly soluble highly volatile

transformation product(s): N-hydroxymethyl methiocarb sulfoxide

oral: low to high (1)

methiocarb sulfoxide

oral: very high (1)

164 methomyl

S-methyl N-[(methylcarbamoyl)oxy] thioacetimidate

CAS # 16752-77-5

carbamate

insecticide nematocide

some formulations restricted, USA

non-pers to mod-pers (1)

oral: high to very high (2)

dermal: medium(3)

inhalation: high(4)

mutagen (5)

anemia, respiratory damage, hypersensitivity (6)

blood damage (6)

liver, kidney, spleen, & bone marrow damage (7)

immediate toxicity:

 birds: very high (8)

 fish: medium to high (9)

 crustaceans: high (9)

 bees: high (10)

 aquatic insects: very high (9)

water: very soluble

slightly volatile

transformation product(s):

acetonitrile

oral: medium (1)

teratogen (2)

flammable

methoprene

Altosand; Altosid; Altosid Briquet; Apex 5E; Diacon; Dianex; Insect & Mite Houseplant Mist; Kabat; Pharoid; Precor; Precor Residual Fogger with Adulticide

isopropyl (2E,4E)-11-methoxy-

3,7,11 -trimethyl-2,4-dodecadienoate; (E,E-1-methylethyl-11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate; isopropyl (E,E-11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate

CAS # 40596-69-8

miscellaneous

insect growth regulator

non-pers (1)

oral: low (2)

dermal: low to medium (3)

inhalation: low (3)

?

immediate toxicity:

 birds: low to medium (4)

 fish: low to high (5)

 crustaceans: “very highly toxic” (6)

 amphibians: very high (7)

water: slightly soluble

slightly volatile

methoxychlor

dianisyltrichloroethane; Dimethoxy-DT; DMDT; Maralate; Marlate; Methoxide; Methoxo; Methoxy-DDT; Moxie; Smo-Cloud Bug Killer

2,2-bis (p-methoxyphenyl)-1,1,1-trichloroethane;

1,1,1-trichloro-2,2-bis

(p-methoxyphenyl)ethane

CAS # 72-43-5

organochlorine

insecticide

pers (1)

oral: medium (2)

dermal: medium (3)

inhalation: ?

cumulative (3)

suspect carcinogen (3,4)

fetotoxin (3,5)

kidney & liver damage (6)

interferes with development of male reproductive system (7,8)

reproduction reduced in original & next generation (9)

estrogen-like effects (9)

immediate toxicity:

 birds: low to medium (10)

 fish: very high (11)

 amphibians: high (12)

 crustaceans: very high (11)

 bees: medium (13)

 aquatic insects: very high (11)

long-term toxicity:

 fish &

 molluscs:

 cumulative (12)

water: insoluble

methyl bromide

Bedfume; Brom-O-Gas; Brozone; Celfume; Dowfume; Embafume; Fumigant-1; Iscobrome; Kayafume; MeBr; Meth-O-Gas; Pestmaster; Profume; Rotox; Terr-O-Gas (with chloropicrin); Weed Fume

bromoethane;

monobromomethane

CAS # 74-83-9

miscellaneous

fumigant

non-pers (1,2)

oral: high (3)

dermal: ?

inhalation: ?

mutagen (4)

neurotoxin (5,6)

liver & kidney damage (7)

brain damage (8)

water: soluble

highly volatile

nonflammable

methyl isothiocyanate

Trapex; Xindex

isothiocyanatomethane; methyl mustard oil

CAS # 556-61-6

fumigant nematicide

?

oral: high (1,2)

dermal: very high (2)

inhalation: ?

?

water: “slightly soluble”

“flammable”

165 methyl parathion

Bladen Extra (with parathion); Cekumethion; Defithion; Folimat Combi (with omethoate); Fostox Metil; Gearphos; Kelthane; Kethane Mixte (with dicofol); metafos; Metaphos; Methyl-bladen; Mixte (with dicofol); Neutrion (with tetradifon); Paralindex (with lindane); Parasoufre Acaricide (with dicofol + sulfur); parathion methyl; Partron M; Sylan Methyl (with endosulfan); Taxylone (with phosalone); Tuver Acaricide (with dicofol & ethion); Verfor; Veromite; Viticarb; Wofatox

O, O-dimethyl O-p-nitrophenyl phosphorothioate

CAS # 298-00-0

organophosphate

insecticide

some uses restricted, USA

mod-pers to pers (1,2)

oral: very high (3)

dermal: high to very high (3)

inhalation: very high (3)

mutagen (4,5)

fetotoxin (6)

retinal & sciatic nerve damage (3)

reduced protein synthesis in fetus (7)

immunotoxin (8)

BIOCIDE

immediate toxicity:

 birds: very high (9)

 fish: medium (3)

 bees: very high (10)

 crustaceans: very high (3)

long-term toxicity:

 birds: changes breeding behavior, may reduce reproductive capacity (3,11)

 fish: reduction in sex hormone, may affect reproduction (12);

inhibits feeding behavior (13)

 plants: chromosome damage (14)

water: slightly soluble oil: “slightly [soluble] in petroleum oils” slightly volatile

transformation product(s):

para-nitrophenol

p-nitrophenol

CAS # 100-02-7

oral: medium to high (1)

dermal: high (2)

water: “moderately soluble”

methylene chloride

dichloromethane

CAS # 75-09-2

organochlorine

fumigant

solvent in aerosol pesticides

mod-pers (1)

oral: medium (2)

dermal: ?

inhalation: low (2)

carcinogen (4,5)

mutagen (4)

brain damage (6)

liver and kidney damage (7)

may cause loss of memory, disturbed sleep, hallucinations, & changes in heart beat (8,9)

decreased ability to learn (3)

alters learning ability (3)

immediate toxicity:

 fish: low (10)

 crustaceans: low (10)

long-term toxicity:

 plants: mutagen (5)

water: very soluble

highly volatile

“nonflammable”

transformation product(s):

phosgene gas

(see carbon tetrachloride)

carbon monoxide

can potentiate cardiovascular stress in diseased heart (1,2)

brain damage (3)

metiram

Carbatene; Ethisul; FMC 9102; NIA 9102; Polyram; Polyram-Combi; Thioneb; Trioneb; Zinc Metiram; zineb-ethylene thiuram disulfide adduct

mixture of (ethylenebis(dithiocarbamate)) zinc with ethylenebis(dithiocarbamic acid), bimolecular and trimolecular cyclic anhydrosulfides and disulfides

CAS # 9006-42-2

thiocarbamate

fungicide

?

oral: low (1)

dermal: low to medium (2)

inhalation: low to medium (1)

suspect mutagen (3)

immediate toxicity:

 fish: medium (1)

 bees: low (4)

water: “practically insoluble”

non-volatile

166transformation product(s):

ethylene thiourea

(see amobam)

metolachlor

Bicep (with atrazine); Codal (with prometryn); Cotodon (with dipropetryn); Cotoran multi (with fluometuron); Dual; Milocep (with propazine); Pennant; Primagram & Primextra (with atrazine); Primagram (with atrazine); Primextra (with atrazine); Turbo (with metribuzine)

2-chloro-6′-ethyl-N-(2-methoxy-1-methylethyl)acet-o-toluidide

CAS # 51218-45-2

amide

herbicide

non-pers (1)

oral: medium (2)

dermal: low to medium (2)

inhalation: low to high (2)

suspect

 carcinogen (4)

testicular atrophy (4)

immediate toxicity:

 birds: low to medium (3)

 fish: medium (2)

water: soluble

slightly volatile

transformation product(s):

nitrosamines

(see dinoseb)

metribuzin

BAY 6159H; BAY 94337; Canopy (with chlorimuron); DIC-1468; Lexone Sencor; Salute (with trifluralin); Sencoral (France); Sencorer; Sencorex (Gr. Britain); Turbo (with metolachlor)

4-amino-6-tert-butyl-3-(methylthio)-as-triazin- 5(4H)-one

CAS # 21087-64-9

triazine

herbicide

non-pers to mod-pers (1)

oral: medium (1)

dermal: low (2)

inhalation: ?

liver & kidney damage (3)

immediate toxicity:

 birds: high (4)

 fish: low (4)

 bees: low to medium (5)

water: soluble

slightly volatile

“nonflammable”

mevinphos

Apavinfos; Duraphos; Menite; Mevinox; OS-2046; Phosdrin; Phosfene

methyl 3-(dimethoxyphosphinoloxy)but-2-enoate;

2-methoxycarbonyl-1-methylvinyl dimethyl phosphate

CAS # 26718-65-0

organophosphate

insecticide acaricide

restricted use, USA

non-pers (1)

oral: high to very high (2,3)

dermal: very high (2)

inhalation: medium (2)

eye damage (4)

immediate toxicity:

 birds: very high (5)

 fish: very high (6)

 crustaceans: very high (6)

 bees: very high (7)

 aquatic insects: medium (6)

water: “soluble”

oil: slightly soluble slightly volatile flammable

mexacarbate

Dowco 139; Zectran

4-(dimethylamino)-3,5-xylyl methylcarbamate

CAS # 315-17-4

carbamate

insecticide acaricide molluscicide

non-pers (1)

oral: very high (2)

dermal: high (1)

inhalation: ?

?

immediate toxicity:

 birds: very high (3)

 fish: medium (4)

 amphibians: medium (3)

 crustaceans: very high (4)

 aquatic insects: very high (4)

 bees: very high (5)

water: soluble

oil: soluble

slightly volatile

MGK R11

R 11

2,3,4,5-bis(2-butylene) tetrahydro-2-furaldehyde

CAS # 126-15-8

aldehyde

insect repellent

voluntary cancellation, USA 1990

?

oral: medium (1)

dermal: ?

inhalation: ?

suspect carcinogen (2)

teratogen (2)

ovarian atrophy (2)

immediate toxicity:

 fish: low to medium (1)

water: “practically insoluble”

167 milky spore disease

Doom; Grub Attack; Japidemic; Japonex; Milky Spore Powder; milky white disease

Bacillus popillae or Bacillus lentimorbus (former most frequently used)

biological

insecticide

“pers” (1)

oral: low (2)

dermal: low (2)

inhalation: low (2)

?

immediate toxicity:

 toxic only to Japanese

beetle grubs (larvae) and to other soil-feeding beetle grubs (2)

“nonflammable”

mirex

Dechlorane; ferriamide; GC 1293

dodecachlorooctahydro-1,3,4-metheno-2H-cyclobuta[c,d]pentalene

CAS # 2385-85-5

organochlorine

insecticide

cancelled USA, 1976

pers (1)

oral: medium to high (2,3)

dermal: high (3)

inhalation: ?

cumulative (4,5)

carcinogen (11)

heart damage (6)

immediate toxicity:

 birds: low to medium (7)

 fish: low (8)

 bees: high (9)

long-term toxicity: bioaccumulates (10)

water: “insoluble”

oil: “lipophilic”

transformation product(s):

chlordecone

(see chlordecone)

monocrotophos

Azodrin; Bilobran; C 1414; Crisodrin; Monocron; Nuvacron; Plantdrin; SD or Shell SD 9129; Susvin; Ulvair

dimethyl phosphate of 3-hydroxy-N-methyl-cis-crotonamide

CAS # 919-44-8

organophosphate

insecticide

cancelled USA, 1988

non-pers (1)

oral: very high (2)

dermal: high (1)

inhalation: very high (2)

mutagen (3,4)

immediate toxicity:

 birds: very high (5)

 fish: low to medium (2)

 bees: very high (6)

long-term toxicity:

 crustaceans: reproductive damage (7)

water: very soluble

oil: “slightly soluble” slightly volatile

monolinuron

Afesin; Aresin; Arresin; Gramonol (with paraquat dichloride); Hoe 2727; Premalin

3-(p-chlorophenyl)-1-methoxy-1-methyl urea; 3-(4-chlorophenyl)-1-methyoxy-1-methyl urea

CAS # 1746-18-2

urea

herbicide

non-pers (1)

oral: medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: low to medium (1)

 fish: low to medium (1)

slightly volatile

combustible

monuron

Chlorfenidim; CMU; Karmex Monuron Herbicide; Monurex; Monurox; Monuruon; Rosuran; Telvar; Telvar Monuron Weedkiller

3-(p-chlorophenyl)-1,1-dimethylurea

CAS # 150-68-5

urea

herbicide

cancelled, most uses, USA, 1977

mod-pers (1)

oral: medium (2)

dermal: ?

inhalation: ?

carcinogen (3) liver, kidney and spleen damage (4)

immediate toxicity:

 fish: low to medium (5)

 bees: low (6)

 phytoplankton: very high (5)

long-term toxicity:

 inhibits soil nitrification causing accumulation of nitrite in soil (4)

water: soluble

oil: soluble

slightly soluble “nonflammable”

salt(s):

monuron TCA

Telvar; Urox

3-(4-chlorophenyl)-1,dimethyluronium trichloroacetate (salt of monuron)

CAS # 140-41-0

168 nabam

Chem Bam; Dithane-40 or D-14; DSE; Kaybam; nabame (France); Parzate; Spring-Bak

disodium ethylene-1,2-bisdithiocarbamate

CAS # 142-59-6

thiocarbamate

fungicide

cancelled, most products, USA

non-pers (1)

oral: high (2,3)

dermal: ?

inhalation: high (4)

?

immediate toxicity:

 birds: medium (5)

 amphibians: high (5)

long-term toxicity:

 amphibians: teratogen (6)

water: soluble

transformation product(s):

carbon disulfide

(see carbon disulfide)

ethylene thiourea

(see amobam)

naled

bromchlophos (So. Africa); Bromex (with chlorbromuron); Dibrom; Hibrom; Ortho 4355; RE 4355

1,2-dibromo-2,2-dichloroethyl dimethylphosphate

CAS # 300-76-5

organophosphate

insecticide acaricide

?

oral: high (1)

dermal: high (2)

inhalation: ?

suspect mutagen (3)

immediate toxicity:

 birds: high to very high(4)

 fish: medium to very high (5)

 amphibians: medium (6)

 crustaceans: very high (5)

 bees: very high (7)

 aquatic insects: very high (5)

water: “practically insoluble”

slightly volatile

transformation product(s):

dichlorvos

(see dichlorvos)

naphthalene

camphor tar; moth balls; moth flakes; naphthalin; tar camphor; white tar

naphthalene

the main constituent of coal tar

CAS # 91-20-3

phenol

insecticide fumigant repellent

non-pers (1)

oral: medium (2)

dermal: low to medium (3)

inhalation: “toxic” (4)

dermal exposure most dangerous to newborns (4)

cataracts (3)

corneal damage (4)

transported across the placenta blood damage (1)

liver, kidney damage (1)

immediate toxicity:

 crustaceans: medium (5)

long-term toxicity:

 fish: cumulative (6)

 crustaceans: decreased oxygen uptake (5)

water: slightly soluble

oil: “very soluble”

volatile

combustible

transformation product(s):

1-naphthol

(see carbaryl)

naphthaleneacetic acid

Fruitone-N; Keriroot (with captan); NAA-800; Phymone; Planofix; Rhizopon B; Tipoff; Tre-Hold Sprout Inhibitor; Tre-Hold Wound Dressing

2-(1-naphthyl)acetic acid

CAS # 86-87-3

miscellaneous

plant growth regulator

?

oral: medium (1)

dermal: medium (2)

inhalation: ?

liver damage (3)

immediate toxicity:

 birds: low to medium (3)

water: soluble oil: “slightly soluble”

ester(s):

ethyl ester

oral: medium (1)

dermal: low to medium (1)

169 naptalam

Alanap-L; Dyanap (with dinoseb); Rescue (with dinoseb)

N-1-naphtylphthalamic acid (1)

CAS # 132-66-1

miscellaneous

herbicide

non-pers (1)

oral: low (1)

dermal: ?

inhalation: low to medium (2)

eye damage (3)

immediate toxicity:

 bees: low (4)

long-term toxicity:

 plants: mutagen (5)

water: soluble

salt(s):

sodium salt

oral: medium (1)

water: very soluble

niclosamide

Aten; Atenase; Bayluscid; Bayluscide; Bayluscit; Cestacide; Clonitralid; Clonitralide; Copharten; Fenasal; Grandal; Helmiantin; lometan; Kontal; Lintex; Manosil; Mato; Molluscicide Bayer 73; Molutox; Yomesan

2′,5-dichloro-4′-nitrosalicylanilide 2-aminoethanol salt;

2′,5-dichloro-4′-nitrosalicylanilide, ethanolamine salt;

5-chloro-N-(2-chloro-4-nitrophenyl)- 2-hydroxybenazmide, 2-aminoethanol salt

CAS # 1420-04-8

amide

molluscicide

non-pers (1)

oral: low to medium (1)

dermal: ?

inhalation: low (1)

suspect mutagen (2)

sperm damage (3)

water: soluble

oil: “lipophilic” slightly volatile

nicotine

Black Leaf 40 (nicotine sulfate); Destruxol Orchid Spray; Emo-Nik; Fumetobac; Mach-Nic; Niagara P.A. Dust; Nic-Dust; Nic-Sal; Nico-Fume; Nicocide; Ortho N-4 & N-5 Dusts; Tendust

1,3-(1-methyl-2-pyrrolidinyl) pyridine

CAS #54-11-5

botanical

insecticide

?

oral: high (1)

dermal: high (2)

inhalation: ?

?

immediate toxicity:

 birds: medium (3)

long-term toxicity:

 birds: teratogen (4)

water: “soluble”

highly volatile

transformation product(s):

N-nitrosonornicotine

carcinogen (1)

nitrapyrin

N-Serve; nitrapyrine

2-chloro-6-trichloromethylpyridine

CAS # 1929-82-4

miscellaneous

antibiotic

non-pers (1)

oral: medium (2)

dermal: medium (2)

inhalation: ?

fetotoxin (3)

immediate toxicity:

 birds: high (2)

 fish: medium (2)

long-term toxicity:

 fish: cumulative (1)

water: slightly soluble

slightly volatile

nitrofen

FW-925; niclofen; NIP; nitrofene (France); nitrophen; TOK; TOK E-25; TOK-2

2,4-dichlorophenyl p-nitrophenyl ether;

2,4-dichloro-1-(4-nitrophenoxy)benzene

CAS # 1836-75-5

miscellaneous

herbicide

not made or sold in USA

non-pers to mod-pers (1)

oral: medium (2)

dermal: medium (3)

inhalation: low (3)

cumulative (4)

carcinogen (5)

suspect mutagen (5)

teratogen (6)

liver damage (3)

kidney damage (7)

blood damage (4)

water: slightly soluble

slightly volatile

170 norflurazon

Evital; Solicam; Telok (with simazine); Zorial

4-chloro-5-methylamino-2-(α,α,α-trifluro-m-tolyl)pyridazin-3(2 H)-one

CAS # 27314-13-2

miscellaneous

herbicide

non-pers to mod-pers (1)

oral: low (2)

dermal: low (1)

inhalation: ?

liver damage (3)

thyroid damage (3)

immediate toxicity:

 birds: low to medium (2)

 fish: low (2)

water: slightly soluble

non-volatile

“nonflammable”

nuclear polyhedrosis virus

Biotrol VHZ; Elcar; Heliothis NPV, (Elcar); Lymantria dispar NVP (Gypcheck); Orgyia pseudotsugata NPV (TM Biocontrol-1)

CAS # 240194-80-1

biological

insecticide

“no adverse effects were observed in any acute oral, dermal, inhalation, and intravenous test” (1)

immediate toxicity:

 “NPV poses a minimal to non-existent risk to nontarget wildlife” (1)

O-benzyl-p-chlorophenol

Clorophene; Santophen 1; Septiphene

4-chloro-2-(phenylmethyl)phenol;

4-chloro-α-phenyl-o-cresol;

 2-benzen-4-chlorophenol;

 5-chloro-2-hydroxydiphenylmethane;

o-benzyl-p-chlorophenol

CAS # 120-32-1

phenol

antibiotic

?

oral: medium (1)

dermal: ?

inhalation: ?

?

?

omethoate

BAY 45432; Baythroid F (with cyfluthrin); dimethoate-met; dimethoxon; Folimat Combi (with methyl parathion); Folimat T (with tetrad ifon)

dimethyl S-(N-methylcarbamoylmethyl) phosphorothioate;

O,O-dimethyl S-[2-(methylamine)-2-oxoethyl]phosphorothioate

CAS #1113-02-6

organophosphate

insecticide

non-pers (1)

oral: high (1)

dermal: high (2)

inhalation: high (1)

suspect mutagen (3)

immediate toxicity:

 fish: low to medium (1)

 bees: “toxic” (2)

water: very soluble

oil: “almost insoluble”

non-volatile

oryzalin

Dirimal; Dirimal Extra (with diuron); EL-119; Rycelan; Ryzelan; Snapshot 80 (with isoxaben); Surflan

3,5-dinitro-N 4 N 4-dipropylsulfaniliamide;

4-(dipropylamino)-3,5-dinitro-benzenesulfonamide

CAS # 19044-88-3

dinitroaniline

herbicide

mod-pers (1)

oral: low to medium (2,3)

dermal: low to medium (2)

inhalation: low to high (2)

suspect carcinogen (4)

immediate toxicity:

 birds: low to medium (2)

 fish: medium (3)

water: slightly soluble

non-volatile “flammable”

oxadiazon

Ronstar; RP 17623

2-tert-butyl-4-(2,4-dichloro-5-isopropoxyphenyl)-∆2 1,3,4-oxadiazoline-5-one;

3-[2,4-dichloro-5-(1-methylethoxy) phenyl]-5-(1,1-dimethylethyl-1,3,4-oxadizol-2(3H)-one

CAS # 19666-30-9

miscellaneous

herbicide

mod-pers (1)

oral: low to medium (2,3)

dermal: medium (3)

inhalation: low to medium (3,4)

suspect

carcinogen(4,5)

immediate toxicity:

 birds: low to medium (3)

 fish: low to medium (3)

 bees: low to medium (6)

 crustaceans: medium to high (7)

water: insoluble

slightly volatile combustible

171 oxamyl

Vydate-G; Vydate-L

N,N-dimethyl-2-methylcaaramoyloxyimino-2-(methylthio) acetamide;

S-methyl N′,N′-dimethyl-N-(methylcarbamoyloxy)-1-thio-oxamimidate (l)

CAS # 23135-22-0

carbamate

insecticide

some uses restricted, USA

non-pers (1)

oral: very high (1)

dermal: medium (2)

inhalation: very high (1)

eye damage (3)

immediate toxicity:

 birds: high to very high (1)

 fish: medium (1)

 crustaceans: medium to high (4)

 bees: medium (5)

water: very soluble

slightly volatile

oxydemeton-methyl

Croneton MR; Dipterex MR; Ecombi (with parathion); Metasystox R

S-2-ethylsulfinylethyl O, O-dimethylphosphorothiote

CAS # 301-12-2

organophosphate

insecticide

non-pers (1)

oral: very high (2)

dermal: very high (3)

inhalation: high (2)

mutagen (4)

suspect teratogen (5,6)

sperm damage (6)

immediate toxicity:

 birds: high to very high (7)

 fish: low to medium (8)

 crustaceans: high (8)

 bees: high (9)

 aquatic insects: high (10)

water: miscible

oil: sparingly soluble

slightly volatile

oxyfluorfen

Goal; Koltar; RH-2915

2-chloro-α,α,α-trifluro-p-tolyl 3-ethoxy-4-nitrophenyl ether

CAS # 42874-03-3

miscellaneous

herbicide

cancelled, most products, USA 1982

non-pers (1)

oral: low (1)

dermal: low to medium (2)

inhalation: ?

suspect mutagen (4)

blood, kidney, liver, and thyroid damage (4)

immediate toxicity:

 birds: low to medium (3)

 fish: high (3)

water: insoluble

slightly volatile

contaminant(s):

perchloroethylene

CAS # 1 27-84-4

carcinogen (1)

suspect fetotoxin (1)

oxytetracycline hydrochloride

Biosolomycin; Hydrocyclin; Liquamycin; Otetryn; Oxlopar; terramicin; terramitsin; Terramycin Hydrochloride

2-Naphthacene carboxamide,

 4(dimethylamino)-1,4,4a,5,5a,6,

 11,12a-octahydroxy-6-methyl-1,

 11-dioxo-monohydrochloride

CAS # 2058-46-0

biological

antibiotic

?

oral: low (1)

dermal: ?

inhalation: ?

carcinogen (2)

water: soluble

oil: “insoluble”

paradichlorobenzene

Di-chloride; Para Crystals; Para Nuggets; Paracide; Paradow; Paramoth

1,4-dichlorobenzene; p-dichlorobenzene

CAS # 106-46-7

organochlorine

fumigant

?

oral: medium (1)

dermal: ? inhalation: ?

suspect carcinogen (2)

suspect mutagen (3)

liver & kidney damage (2,3)

lung damage (2)

anemia (2)

immediate toxicity:

 fish: medium (4)

long-term toxicity:

 plants: mutagen (3)

water: slightly soluble

oil: “lipophilic” highly volatile

paraformaldehyde

Formagene; Paraform

polyoxymethylene;

polymerized formaldehyde

CAS # 30525-89-4

aldehyde

fungicide

?

oral: low to medium (1)

dermal: low to medium (1)

inhalation: medium (1)

?

?

transformation product(s):

formaldehyde

(see formaldehyde)

172 paraquat

Actor (with diquat); Cyclone (with diquat); Dexuron (with diuron); Farmon PDQ (with diquat); Gramazine (with simazine); Gramixel (with diuron); Gramuron (with diuron); Groundhog (with amitrole & diquat & simazine); methyl viologen; Pardi-Weedol (with diquat); Pathclear (with amitrole & diquat & simazine); Preglone (with diquat); Reglox (with diquat); Soltair (with diquat & simazine); Spraygrow (with diquat); Sprayseed (with diquat); Spraytop (with diquat); Surefire (with diuron); Talent (with asulam); Totacol (with diuron)

1,1′-dimethyl-4,4′-bipyridiniu m

CAS # 4685-14-7

bypiridyl

herbicide

voluntary withdrawal from market, Norway, 1981

banned in Sweden, 1983

Banned in Netherlands, 1989

non-pers (1,2)

oral: high to very high (3)

dermal: very high (3)

inhalation: high (3)

suspect mutagen (4)

suspect teratogen (5)

suspect neurotoxin (6)

fingernail loss (7)

liver, kidney, pancreas, gastrointestinal tract, adrenal, nerve, brain, heart, muscle and eye damage (6,8)

irreversible lung injury within hours of ingestion (7)

implicated in Parkinson’s disease (9,10)

immediate toxicity:

 birds: high

 fish: low to medium (2,11)

 amphibians: low (2)

 crustaceans: low to medium (2)

 aquatic insects: low (11)

 microorganisms: toxic to some (12)

long-term toxicity:

 birds: embryotoxin (13);

 growth rate, adverse effects; blood damage (14,15)

 amphibians: clinical syndrome of Parkinson’s disease (9)

blue-green algae: mutagen (16)

water: “soluble”

related compound(s):

emetic

(formulated into technical paraquat in case of ingestion)

heart damage (1)

transformation product(s):

formaldehyde

(see formaldehyde)

paraquat dichloride

Dextrone (with diquat); Galgo-quat; Gramonol (with monolinuron); Gramoxone (with MCPA); Gramoxone Special; Liro-paraquat; Longlife Plus; Ortho paraquat; Prelude; Protex; R-Bix; Radex; Scythe; Sipquat; Speedway; Sweep; Terraklene (with simazine); Violan

1,1′-dimethyl-4,4′-bypiridinium dichloride

CAS # 1910-42-5

bypiridyl

herbicide dessicant defoliant plant growth regulator

?

oral: high to very high (1,2)

dermal: high (3)

inhalation: very high (4)

many long-term symptoms may begin immediately from single or minimal exposure (see long-term toxicity)

suspect carcinogen (4)

suspect mutagen (4)

brain damage (5)

immediate toxicity:

 birds: medium to high (6)

 fish: low to medium (1)

 crustaceans: medium to high (4)

long-term toxicity:

 birds: egg hatchability, adverse effects (3)

 amphibians: teratogen (7)

water: “soluble”

“non-volatile”

transformation product(s):

QINA

parathion

Alkron; Alleron; Bladen Extra (with methyl parathion); Corothion; Folidol E-65; Genthion; Geofos; Lethalaire; Malatox (with malathion); Niran; Orthophos; Paradusto; Paraspra; Penncap-E; Sopragram (with lindane); Stathion; Tamaron (with acephate-met); thiophos (USSR); Vapophos

O,O-diethyl O-p-nitrophenyl phosphorothioate

CAS # 56-38-2

organophosphate

insecticide

restricted use: USA uses withdrawn 1991, USA

mod-pers (1)

oral: very high (2)

dermal: very high (2)

inhalation: very high (2)

suspect carcinogen (2)

suspect mutagen (2)

suspect teratogen(3)

retinal degeneration (2)

neurotoxin (2)

limited immunotoxin(4)

BIOCIDE

immediate toxicity:

 birds: very high (5)

 fish: medium to very high (6)

 bees: very high (8)

 amphibians: high (7)

 aquatic worms: very high (9)

 crustaceans: very high (6)

 aquatic insects: very high (6)

173long-term toxicity:

 birds: disrupts incubation behavior (10); reduction in sex hormones, possibly impairing reproduction(11); embryotoxin (12)

 fish: reduced sex hormone and ovarian activity (13)

 bioconcentrates in fish, molluscs and amphibians (14)

water: slightly soluble

slightly volatile

transformation product(s):

para-nitrophenol

p-nitrophenol

CAS # 100-02-7

oral: medium to high (1)

dermal: high (2)

water: “moderately soluble”

paraoxon

diethyl p-nitrophenol ester of phosphoric acid

CAS # 311-45-5

oral: very high (1)

dermal: very high (1)

inhalation: ?

water: very soluble

PCBs

Arochlor; Chlophen; Chlorextrol; Clophen; Dykanol; Fenchlor; Inerteen; Kanechlor; Noflamol; Phenochlor; Pyralene; Pyranol; Sentotherm; Therminol

polychlorinated biphenyls chlorinated biphenyls chlorinated diphenyls

The total number of PCB’s is over 200 half of which are commonly found among the commericial preparations.

CAS # 1336-36-3

organochlorine

formerly used to reduce vapor pressure and prolong residual activity of pesticides

cancelled, all products, USA,1970

pers (1)

oral: low to medium (2)

cumulative (3)

carcinogen (4)

immunotoxin (5)

liver damage (2)

neurotoxin (6)

decreased homoglobin (1)

chloracne (2)

reduced fertility (7)

BIOCIDE

immediate toxicity:

 fish: low to high (8)

 crustaceans: medium to very high (8)

 bees: low to medium (9)

long-term toxicity:

 birds: behavioral defecits; reduced egg shell thickness. (10,11)

 biomagnification (1)

water: insoluble

oil: soluble

slightly volatile to volatile

“nonflammable”

contaminant(s):

pentachlorodibenzofuran

dibenzofuran

chlorinated naphthalenes

chloracne (1)

liver damage (1)

hyperkeratosis (1)

tetrachlorodibenzofuran

dibenzofuran

174 PCNB

Avicol; Botrilex; Brassicol; Earthcide; Folosan; Kobu; Kobutol; Pentagen; PKhNB (USSR); quintozene; Terrachlor; terraclor (Turkey); Tilcarex; Tri-PCNB; Tritisan

pentachloronitrobenzene

CAS # 82-68-8

organochlorine

fungicide

cancelled, most products, USA,1982

mod-pers (1)

oral: medium (1)

dermal: medium to high (2)

inhalation: ?

suspect mutagen (4)

immediate toxicity:

 birds: medium (5)

 fish: very high (1)

water: insoluble

volatile

contaminant(s):

pentachlorobenzene

CAS # 608-93-5

oral: high (1)

cumulative (1)

hexachlorobenzene

(see hexachlorobenzene)

transformation product(s):

pentachloroanilne

PCA

cumulative (1)

pentachlorophenylmethylsulfide

PCMS

cumulative (1)

pendimethalin

AC 92553; Accotab; Go-Go-San; Herbadox; Horbadox; Prowl; Sipaxol; Squadron (with imazaquin); Stomp; Way Up

2,6-dinitro-3,4-xylidine

CAS # 40487-42-1

dinitroaniline

herbicide

non-pers to mod-pers (1)

oral: medium (2,3)

dermal: low to medium (3)

inhalation: low (3)

?

immediate toxicity:

 fish: high (4)

 birds: low (2)

 crustaceans: high (4)

water: insoluble

oil: very soluble

slightly volatile

flammable

transformation product(s):

N-nitrosopendimethalin

N-(1-ethylpropyl)-N-nitroso-3,4-dimethyl-2,6-dinitrobenzamine

mod-pers (1)

oral: ?

dermal: ?

inhalation: ?

pentachlorophenol

Acutox; Chem-Penta; Chemtrol; chlorophen; Cryptogil ol; Dow Pentachlorophenol DP-2 Antimicrobial; Dowicide 7; Durotox; EP 30; Fungifen; Fungol; Grundier Arbezol; Lauxtol A; Moosuran; Ontrack WE-1; PCP; Penta Plus 40; Santobri; Term-i-Trol; Weed-Beads

2,3,4,5,6-pentachlorophenol

CAS # 87-86-5

organochlorine

insecticide fungicide herbicide defoliant wood preservative molluscicide

cancelled, USA, 1984

non-pers to pers (1,2)

oral: high to very high (3)

dermal: high to very high (4)

inhalation: ?

toxic by all portals of entry (5)

carcinogen (6)

teratogen (7)

fetotoxin (7)

embryotoxin (8)

immunotoxin (1,9)

porphyria (1)

aplastic anemia (1)

chloracne (1)

nerve & liver damage (1)

most chronic toxic effects associated with PCP are due to the presence of contaminants (see below) (1)

BIOCIDE

immediate toxicity:

 birds: medium to high (11)

 fish: medium to very high (3)

 amphibians: high to very high (12)

 crustaceans: medium to very high (11,13)

 bees: low to medium (14)

 aquatic insects: high to very high (11)

 aquatic worms: high to very high (11)

technical grade PCP significantly more toxic than pure PCP to aquatic organisms (11)

long-term toxicity:

 biomagnification (1)

 birds: suspect immunutoxin (15,16);

 fish: inhibited growth 175(12); increases vulnerability to predation (17); delayed egg hatchability (18)

water: slightly soluble

volatile

“flammable”

contaminant(s):

2,4,5-trichlorophenol

(see 2,4,5-trichlorophenol)

hexachlorobenzene

(see hexachlorobenzene)

heptachlorodibenzo-p-dioxin

HCDD; HpCDD heptachlorodibenzo-p-dioxin

CAS # 35822-46-9

dibenzo-dioxin

suspect immunotoxin(1)

hexachlorodibenzofuran

dibenzo-furan

mod-pers (1)

oral: very high (1)

suspect carcinogen (2)

teratogen (3)

thymus, liver, and spleen damage (2)

octachlorodibenzo-p-dioxin

OCDD

octachlorodibenzo-p-dioxin

CAS # 3268-87-9

dibenzo-dioxin

non-pers to mod-pers (1)

cumulative (1)

acne (2)

water: insoluble

non-volatile

hexachlorodibenzo-p-dioxin

HCDD; HxCDD

hexachlorodibenzo-p-dioxin

CAS # 34465-46-8

dibenzo-dioxin

oral: very high (1,2)

carcinogen (3)

suspect teratogen(2,3)

suspect fetotoxin (2,3)

immunotoxin (4)

acnegenic (2)

thymus, liver, kidney, & spleen damage (2)

water: insoluble

tetrachlorophenol

CAS # 25167-83-3

phenol

fungicide

oral: high (1)

TCDD

(see chloroneb)

transformation product(s):

tetrachlorocatechol

tetrachloropyrocatechol; tetrachloro-1,2-benzenediol; 3,4,5,6-tetrachloro-1,2-benzenediol

CAS # 1198-55-6

oral: high

suspect mutagen

tetrachlorohydroquinone

CAS # 87-87-6

oral: high (1)

suspect mutagen (2)

water: slightly soluble

tetrachlorophenol

CAS # 25167-83-3

phenol

fungicide

oral: high (1)

176 perfluidone

Destun; MBR-825; perfluoridone

1,1,1-trifluoro-N-[2-methyl-4-(phenylsulfonyl)phenyl] methane sulfonamide

CAS # 37924-13-3

amide

herbicide

non-pers to mod-pers (1,2)

oral: medium (3)

dermal: low to medium (4)

inhalation: medium (5)

liver damage (6)

immediate toxicity:

 fish: low (3)

water: slightly soluble

non-volatile to slightly volatile

“nonflammable”

permethrin

Ambush; Atroban; Bio Flydown; Corsair; Dragon; Ectiban; Expar; Gard-Star; Hard-Hitter; Insectiban; Jureong; Kafil; Nix; Over-Time; Permectrin; Pounce; Quamlin; Rondo; Stockade; Tornade; Torpedo

3-phenoxybenzyl (1 RS)-cis,trans-3-(2,2-dichlorovinyl)-2,2-dimethyl- cyclopropanecarboxylate

CAS # 52645-53-1

pyrethroid

insecticide acaricide

non-pers (1)

oral: low to high (2)

dermal: ?

inhalation: low to high (3)

blood damage (4)

immediate toxicity:

 fish: very high (5)

 birds: “practically non-toxic” (2)

marine invertebrates: very high (6)

 bees: “toxic” (7)

water: insoluble to slightly slightly soluble

non-volatile

combustible

petroleum oils

arranged from most volatile to least volatile-each product may have a range of components and volatility

oils

compound(s):

fuel oil

diesel oil

long-term toxicity:

 birds: embryotoxin & teratogen when are exposed to eggs (1)

kerosene

CAS # 8008-20-6

oral: high (1)

inhalation: low (1)

suspect mutagen (2)

lung damage(3)

neurotoxin (2)

mineral oil

carcinogen (1,2)

mineral spirits

(overlaps naphtha)

CAS # 8032-32-4

“jeopardize survival of test animals”

immediate toxicity:

flash point varies within range

naphtha

petroleum naphtha

CAS # 64741-64-6 8030-30-6 8002-05-9

solvent

oral: medium (6)

carcinogen (1)

suspect mutagen (2)

anemia (3)

liver damage (3)

heart, lung damage, from more volatile reactions (5)

immediate toxicity:

 fish: medium (4)

 crustaceans: medium (4)

water: “insoluble” flammable

stoddard solvents

CAS # 8052-41-3

oral: low (1)

phenmedipham

Betaflow; Betamix (with desmedipham); Betanal; Betanal E; Betanal Perfekt (with ethofumesate); Betanal Plus; Betanal Progress (with ethofumesate & desmedipham); Betanal Tandem (with ethofumesate); Betaron (with ethofumesate); Campaign (with clopyralid); Goliath; Gusto; Pistol-400; Protrum K; Spin-aid; Vangard 177methyl 3-(3-methylcarbaniloyloxy)carbanilate; 3-methoxycarbonylaminophenyl 3′-methylcarbanilate

CAS # 13684-63-4

carbamate

herbicide

non-pers to mod-pers (1)

oral: “low” (1)

dermal: medium (1)

inhalation: ?

?

immediate toxicity:

 birds: “very low” (1)

 fish: medium to high (1)

 bees: “very low” (1)

water: slightly soluble

phenol

carbolic acid

hydroxybenzene; monohydroxybenzene; phenic acid; phenyl alcohol; phenyl hydroxide; phenylphenol

CAS # 108-95-2; CAS # 90-43-7

phenol

fungicide

antibiotic

?

oral: medium (1)

dermal: ?

inhalation: ?

suspect carcinogen (2)

immediate toxicity:

 fish: medium (3)

water: very soluble

oil: “almost insoluble”

highly volatile

combustible

phenothrin

d-phenothrin; fenothrin; Multicide Concentrate F-2271; Neo-Pynamin 5/1/30 (with allethrin & piperonyl butoxide); Neo-Pynamin Forte Aerosol (with tetramethrin); OMS 1810; Pesguard (with allethrin & piperonyl butoxide); Pesguard FS (with tetramethrin); Pesguard Insect Killer (with tetramethrin); Pesguard NX; Pesguard Plant Spray (with tetramethrin); phenothrine; S-2539; Sumithrin; Sumithrin A Plus (with tetramethrin); Sumithrin B Plus (with tetramethrin); Sumithrin Plus (with allethrin) 3-phenoxybenzyl (±)-cis,trans-chrysanthemate

CAS # 26002-80-2

pyrethroid

insecticide

“more stable to photolysis than other pyrethoids” (1)

oral: low (2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: “very low” (3)

 fish: very high (3)

 crustaceans: low (3)

water: slightly soluble

slightly volatile

phorate

AAstar (with flucythrinate); Corliss (with terbufos); Cygard (with terbufos); Geomet; Granutox; Thimet

O,O-diethyl S-ethylthiomethyl phosphorodithiote

CAS # 298-02-2

organophosphate

insecticide

restricted use, USA

non-pers (1)

oral: very high (2)

dermal: very high (2)

inhalation: very high (1)

mutagen (3)

immediate toxicity:

 birds: very high (4)

 fish: very high (5)

 amphibians: high (4)

 crustaceans: very high (5)

 bees: medium (6)

 aquatic insects: very high (5)

water: slightly soluble volatile

phosalone

Azofene; Benzphos; Fozalon; NIA-9241; NPH-1091; phosalon; Ranbeck (with dichlorvos); Ransbeck (with dichlorvos); RP 11974; Rubitox; Taxylone (with methyl parathion); Zolone; Zolone Flo; Zolone Liquid

S-6-chloro-2,3-dihydro-2-oxo-1,3-benzoxazol-3-yl methyl O,O-diethyl phosphorodithioate

CAS # 2310-17-0

organophosphate

insecticide acaricide

non-pers (1)

oral: high (2)

dermal: high (2)

inhalation: ?

?

immediate toxicity:

 birds: high (1)

 fish: high to very high (3)

 crustaceans: very high (4)

 bees: high (5) oil: “insoluble” non-volatile

phosmet

Imidan; Prolate

N-(mercaptomethy)phthalimide-S-(O,O-

dimethylphosphorodithioate)

CAS # 732-11-6

organophosphate

acaricide insecticide

non-pers (1)

oral: high to very high (1)

dermal: medium to high (1)

inhalation: very high (1)

suspect carcinogen (1)

suspect teratogen (2)

suspect fetotoxin (2)

immediate toxicity:

 birds: medium to high (1)

 fish: very high (1)

 bees: very high (1)

 crustaceans: very high (1)

 aquatic insects: very high (1)

water: slightly soluble volatile

178 phosphamidon

Apamidon; Dimecron

2-chloro-2-diethylcarbamoyl-1-methylvinyl dimethyl phosphate;

2-chloro-3-dimethoxyphosphinoyloxy- N,N-diethylbut-2-enamide

CAS # 13171-21-6

organophosphate

insecticide, acaricide

restricted use, USA

?

oral: very high (1)

dermal: very high (1)

inhalation: high (2)

mutagen (3)

embryotoxin (4)

testicular damage (5)

liver damage (6)

BIOCIDE

immediate toxicity:

 birds: very high (7) 

 fish: medium to high (8)

 crustaceans: very high (8)

 aquatic insects: very high (8)

long-term toxicity:

 birds: “teratogenic” (9)

water: very soluble

slightly volatile

phoxim

Baythion; Muscatox (with cyfluthrin); Oftanol Combi (with isofenphos); Omnicur (with carbofuran); Volaton

diethoxyphosphinothioyloxyimino (phenyl)acetonitrile;

2-(diethoxyphosphinothioloxyimino)-2-phenylacetonitrile

CAS # 14816-18-3

organophosphate

insecticide

?

oral: high (1)

dermal: high (1)

inhalation: ?

suspect mutagen (2)

immediate toxicity:

 birds: high to very high (3)

 fish: medium to high (4)

 bees: very high (5)

water: slightly soluble

transformation product(s):

TEPP

(see TEPP)

picloram

Amdon; Borolin; Debroussaillant 4323 DP (with dichlorprop); Hydon (with bromacil); K Pin; piclorame; Printazol N (with 2,4-D & MCPA); Printazol Total (with 2,4-D & MCPA & mecoprop); Spica 66; Tordon; Tordon 101 Mixture (with 2,4-D); Tordon 10K & 22K; Tordon RTU; Torgal

4-amino-3,5,6-trichloropyridine-2-carboxylic acid

CAS # 1918-02-1

miscellaneous

herbicide

restricted use, USA

non-pers to mod-pers (1,2)

oral: low to medium (1)

dermal: medium (3)

inhalation: high (2)

suspect carcinogen (4) teratogen (5)

liver damage (6)

kidney damage (4)

testicular atrophy (4)

immediate toxicity:

 birds: low to medium (7)

 fish: low to high (8)

 crustaceans: very high (8)

 aquatic insects: low to very high (8)

 bees: low to medium (9)

water: soluble

oil: slightly soluble

slightly volatile flammable

contaminant(s):

nitrosamines

suspect carcinogen (1)

hexachlorobenzene

(see hexachlorobenzene)

piperonyl butoxide

Butacide; Derringer (with resmethrin); Detrans (with esbiothrin); Duracide 15 (with tetramethrin); FMC 5273; K-O (with deltamethrin & esbiothrin); K-Obiol (with deltamethrin); Kefil (with permethrin & bioallethrin); Neo-Pynamin 5/1/30 (with phenothrin & allethrin); Pesguard (with allethrin & phenothrin); Pesguard NSB (with tetramethrin & fenitrothion); Pyrenone; Vapona Flyki11er (with permethrin & bioallethrin)

(butylcarbityl) (6-propylpiperonyl) ether; α-[2-(2-butoxyethyoxy)ethoxy] 4,5-(methylenedioxy)-2-propyltoluene

derived from safrole via dihydrosafrole

CAS # 51-03-6

methylene dioxy phenyl

synergist with insecticides

?

oral: low (1)

dermal: high (2)

inhalation: ?

can reduce ability of body to detoxify other toxins (neurotoxins, carcinogens, etc.) (3,4)

kidney, liver, & adrenal damage (5)

anorexia (5)

immediate toxicity:

 fish: very high (6)

 amphibians: high (7)

 crustaceans: very high

(6)

water: “slightly soluble”

oil: “soluble”

slightly volatile

combustible

179 pirimiphos-ethyl

Fernex; Primicid (with drazoxolon)

O-2-diethylamino-6-methylpyrimidin-4-yl O,O-diethyl phosphorothiote

CAS # 23505-41-1

organophosphate

insecticide, acaricide

non pers to mod pers (1)

oral: high to very high (1)

dermal: high (1)

inhalation: very high (2)

suspect mutagen (3)

immediate toxicity:

 birds: very high (2)

 fish: very high (2)

 bees: very high (4)

long-term toxicity:

 birds: teratogen (5)

water: insoluble

volatile

pirimiphos-methyl

Actellie; Actellifog; Attack (with permethrin); Blex; Cyperallic (with cypermethrin); Giustiziere; Pirigrain; PP-511; Silo-San; Silosan; Singsing (with cypermethrin); Sybol 2

O-[2-(diethylamino)-6-methyl-4-pyrimidinyl] O,O-dimethylphosphorothioate;

2-dimethylamino-6-methylpyrimidin-4-yl dimethyl phosphorothioate

CAS # 29232-93-7

organophosphate

insecticide, acaricide

non-pers (1)

oral: medium (2)

dermal: medium to high (3)

inhalation: ?

mutagen (4)

immediate toxicity:

 birds: high to very high (5)

 fish: “toxic” (5)

water: slightly soluble volatile

potassium azide

Kazoe 10G

potassium azide

CAS # 20762-60-1

azide

herbicide fungicide nematocide insecticide soil fumigant

non-pers (1)

oral: high to very high (1)

dermal: very high (1)

inhalation: “avoid breathing dust or vapor” (1)

?

immediate toxicity:

 birds: very high (1)

 fish: high (2)

 aquatic insects: medium (2)

 crustaceans: medium (2)

long-term toxicity:

 plants & bacteria: mutagen (1)

water: very soluble

transformation product(s):

hydrazoic acid

“highly volatile” (1)

potassium bromide

potassium bromide

CAS # 7758-02-3

miscellaneous

antibiotic algacide

?

oral: low (1)

dermal: low (1)

inhalation: ?

?

immediate toxicity:

 birds: “practically non-toxic”

 fish: “highly toxic” (1)

 crustaceans: “highly toxic” (1)

potassium permanganate

potassium permanganate

CAS # 7722-64-7

miscellaneous

antibiotic, algacide, fungicide

?

oral: medium (1)

dermal: “corrosive to eyes and skin”

inhalation: ?

?

immediate toxicity:

 fish: medium (3)

water: soluble

procymidone

Sialex; Sumiboto; Sumilex; Sumisclex

3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione; N-(3,5-dichlorophenyl)-1,2-dimethyl-1,2-cyclopropane dicarboximide

180CAS # 32809-16-8

amide

fungicide

non-pers (1)

oral: low (2)

dermal: ?

inhalation: ?

carcinogen (3)

water: slightly soluble

slightly volatile

prometon

Atratol (with atrazine); Conquer Liquid Vegetation Killer; G-31435; Gesafram; Gesafram 50; Ontracic 800; Ontrack; Parch (with pentachlorophenol); Pramitol; Pramitol 25E; prometone; Triox Vegetation Killer (with pentachlorophenol)

2,4-bis(isopropylamino)-6-methoxy-triazine; 6-methoxy-N,N-bis(1-methylethyl)-1,3,5-triazine-2,4-diamine

CAS # 1610-18-0

triazine

herbicide

mod-pers to pers (1)

oral: medium (2)

dermal: medium to high (3) inhalation: medium (4)

?

immediate toxicity:

 birds: “very low” (4)

 fish: low to medium (5)

 bees: “nontoxic” (6)

long-term toxicity:

 birds: suspect embryotoxin (7)

water: soluble

slightly volatile

prometryn

Codal (with metolachlor); Gesagard; Gesagard 500; Peaweed (with terbutryn); prometryne

N 2,N 4-di-isopropyl-6-methylthio-1,3,5-triazine-2,4-diamine

CAS # 7287-19-6

triazine

herbicide

mod-pers (1)

oral: medium (1)

dermal: medium (2)

inhalation: medium to high (2)

kidney, liver, and bone marrow damage (3)

testicular damage (3)

immediate toxicity:

 birds: low (3)

 fish: medium (3)

 crustaceans: medium (3)

 molluscs: decreased shell growth (5)

 bees: low to medium (6)

water: slightly soluble

“nonflammable”

pronamide

Clanex; Kerb; Kerb Mix Matrikerb (with clopyralid); Kerb-50-W; propyzamide; RH-315; Siden (with simazine)

N-(1,1 -dimethyl-2-propynyl) 3,5-dichlorobenzamide; 3,5-dichloro-N-(1,1-dimethyl-2-propynyl) benzamide

CAS # 23950-58-5

amide

herbicide

cancelled, most uses, USA, 1979

mod-pers (1)

oral: low (1)

dermal: low (1)

inhalation: low to medium (2)

suspect carcinogen (3)

liver damage (4)

immediate toxicity:

 birds: low (5)

 fish: low (5)

 bees: low (6)

water: slightly soluble

oil: ?

slightly volatile “nonflammable”

transformation product(s):

N-nitrosamide

propachlor

Bexton; CP 31393; Decimate (with DCPA); propachlore (France); Ramrod

2-chloro-N-isopropylacetanilide; vinyl 2-chloroethyl

CAS # 1918-16-7

amide

herbicide

mod-pers (1)

oral: medium (1)

dermal: low (1)

inhalation: ?

cataracts (2)

immediate toxicity:

 birds: high (1)

 fish: very high (1)

 crustaceans: medium (1)

water: soluble

volatile

“nonflammable”

component(s):

aniline

oral: high (1)

skin photosensitization (2)

combustible

propanil

Trio (with bromoxynil & 2,4-D) N-(3,4-dichlorophenyl) propanamide

CAS # 709-98-8

amide

herbicide

restricted use, USA

non-pers (1)

oral: medium (2)

dermal: medium (1)

“should not be breathed or allowed to get in eyes or on skin” (1)

methemoglobinemia (2)

hemolytic anemia (3)

immediate toxicity:

 birds: high (4)

 fish: medium (5)

 crustaceans: medium (4)

long-term toxicity:

 birds: suspect teratogen (6)

 bees: low to medium (7)

components:

tetrachloroazoxy benzene

water: soluble slightly volatile

181 3,3,4,4 tetrachloroazobenzene

chloracne and hyperkeratosis (1)

liver damage (2)

propargite

Comite; Omite; Omite TD (with tertadifon); Uniroyal DO14

2-(p-tert-butylphenoxy)cyclohexyl 2-propynyl sulfite

CAS # 2312-35-8

metal/mineral

sulfur

acaricide

mod-pers (1)

oral: medium (1)

dermal: “severe eye and skin irritant”

inhalation: ?

fetotoxin (1)

eye damage (1)

immediate toxicity:

 birds: low (1)

 fish: “highly toxic” (1)

 crustaceans: very high (2)

 bees: low to medium (3)

water: insoluble

propazine

Gesamil; Milocep (with metalochlor); Milogard

6-chloro-N 2,N 4-di-isopropyl-1,3,5-triazine-2,4-diamine

CAS # 139-40-2

triazine

herbicide

mod-pers (1)

oral: low (1)

dermal: ?

inhalation: ?

carcinogen (1)

suspect mutagen (1)

fetotoxin (1)

immediate toxicity:

 birds: low (1)

 fish: medium (1)

 bees: low (2)

water: slightly soluble

non-volatile

propham

Gold (with chlorpropham & fenuron); Morlex (with fenuron & chlorpropham & ethofumesate); Pink C (with chlorpropham & diuron); Premalox (with fenuron & chlorpropham); Quintex (with fenuron & chlorpropham); Tuberite (with chlorpropham)

isopropyl carbanilate; isopropyl phenylcarbamate

CAS # 122-42-9

carbamate

herbicide

non-pers (1)

oral: low to medium (2)

dermal: medium (3)

inhalation: low (2)

suspect mutagen (4)

fetotoxin (1)

immediate toxicity:

 fish: low (5)

 crustaceans: medium (5)

 bees: low (6)

water: slightly soluble to soluble

volatile

“nonflammable”

propionic acid

ethylformic aicd; Luprosil; methylacetic acid; propanoic acid; Propionic Acid Grain Preserver; Sentry Grain Preserver

CAS # 79-09-4

miscellaneous

fungicide

?

oral: medium (1)

dermal: high (2)

inhalation: ?

?

water: “soluble” flammable

propoxur

aprocarb; arprocarb; BAY 39007; Baygon Spray (with dichlorvos & cyfluthrin); Blattanex Residual Spray (with dichlorvos); Boygon; Brygou; Chemagro 9010; Isocarb; o-IMPC; PHC; Raid Ant & Roach Killer; Raid Wasp & Hornet Killer; Sendran; Suncide; Tat Ant Trap; Unden

o-isopropoxyphenyl-N-methyl carbamate; 2-(1-methylethoxy)phenol methyl carbamate

CAS # 114-26-1

carbamate

insecticide

mod-pers (1)

oral: very high (2)

dermal: medium to high (2)

inhalation: ?

carcinogen (3,4)

suspect mutagen (5)

learning disability (6)

BIOCIDE

immediate toxicity:

 birds: very high (7)

 fish: high (8)

 bees: high (11)

 amphibians: medium (9)

 crustaceans: very high (9)

 aquatic insects: very high (9) 

 aquatic worms: very high (10)

long-term toxicity: toxic to some plants (12)

water: soluble slightly volatile

transformation product(s):

n-nitroso propoxur

mutagen (1)

long-term toxicity:

 plants: mutagen (2)

182 pyrethrum

“Insect powder”

Chrysanthemum cinaeraraefolum; mixture of pyrethrin I & II, cinerin I & II, jasmolin I & II

botanical

insecticide

non-pers (1)

oral: medium to high (1,2)

dermal: ?

inhalation: ?

liver damage, especially with synergists and Freon propellant (3)

allergic reactions (4)

neurotoxin (4)

immediate toxicity:

 birds: low (5)

 fish: very high (6)

 crustaceans: very high (6)

water: “not soluble in water”

oil: “100% in petroleum distillate”

combustible

red squill

Bonide; Bonide Topzol Rat Baits & Killing Syrup; Dethdiet; Rat Nots; Rat Snax; Rat’s End; Rat-O-Cide Rat Bait; Rat-Pak; Rats Squill; Ratspax; Rodene; Rodine; Rough & Ready Rat Bait & Rat Paste; Squill; Topzol

extract of bulbs of Urginea maritima (sea onion) containing cardiac glycosides scilliroside, and scillarens A & B (small amounts of the latter two)

CAS # 507-60-8

botanical

rodenticide

?

oral: very high (1)

dermal: ?

inhalation: ?

?

water: “slightly soluble”

oil: “practically insoluble”

resmethrin

Benzofurolin; Benzyfuroline; Chryson; Chrysron; FMC 17370; For-Synm; Isathrine; NIA 17370; NRDC 104; OMS 1206; Premgard; Pynosect; Pyretherm; resmethrine; Respond; RU 48440; SBP-1382; Scourge; Synthin; Vectrin

5-benzyl-3-furylmethyl[1RS,cis,trans]-2,2-dimethyl-3-(2,2-dimethylvinyl)cyclopropane carboxylate

CAS # 10453-86-8

pyrethroid

insecticide

?

oral: low to high (1,2)

dermal: medium (1)

inhalation: low to medium (1)

suspect neurotoxin (4)

suspect immunotoxin (4)

decrease in hormone release from the brain (5)

immediate toxicity:

 birds: low to medium (6)

 fish: low to high (1,4)

 crustaceans: low to medium (4)

water: insoluble

non-volatile

combustible

isomer(s):

bioresmethrin

Biobenzyfuroline; NRDC 107; Resbuthrin; RU 11484

5-benzyl-3-furylmethyl[1R,trans]-chrysanthemate;

d-trans-resmethrin (±)trans-resmethrin

CAS # 28434-01-7

immediate toxicity:

 birds: low (1)

water: insoluble slightly volatile

cismethrin

5-benzyl-3-furylmethyl[1R,cis]- chrysanthemate; (±)cis-resmethrin

CAS # 35764-59-1

oral: high (1)

ronnel

Ectoral; Etrolene; fenchlorphos (Gr. Britain, France, USSR); Korlan; Nankor; Trolene; Viozene

O,O-dimethyl O-(2,4,5-trichlorophenyl) phosphorothioate

CAS # 299-84-3

organophosphate

insecticide

not manufactured since 1979

?

oral: low to medium (1,2)

dermal: high (2)

inhalation: ?

suspect mutagen (6)

immediate toxicity:

 birds: low to medium (4)

 fish: high (5)

 crustaceans: medium (5)

 bees: high (3)

water: slightly soluble oil: “soluble” volatile

contaminant(s):

TCDD

(see chloroneb)

183 rotenone

Cenol Flea Powder; Cenol Garden Dust;

Chem-Mite; Cibe Extract; Curex Flea Duster;

Derrin; Green Cross Warble Powder;

Nicouline; Noxfish; Powder & Root;

Rotefive; Rotefour; Rotessenol; Rotocide;

Tubatoxin; Warbicide

extracts from Derris or Lonchocarpus (barbasco; cube; haiari; nekos; timbo)

 plants: the principle active ingredient is 1,2,12,12a-tetrahydro-2-α-isopropyl-8,9-dimethoxy(1)benzopyrano(2,4-b)-furo(2,3-h) (1)benzopyrano-6(6aH)-one

CAS # 83-79-4

botanαical

insecticide acaricide piscicide

non-pers (1)

oral: medium to very high (2,3)

dermal: very high (2)

inhalation: ?

suspect carcinogen (4,5,8)

suspect teratogen (6)

suspect fetotoxin (7)

liver and kidney damage (2)

immediate toxicity:

 birds: low to medium (9)

 crustaceans: medium (10)

 aquatic insects: medium to high (11)

water: slightly soluble

oil: slightly soluble

contaminant(s):

tetrachloroethylene

(see tetrachloroethylene)

xylene

(see xylene)

trichloroethene

CAS # 79-01-6

carcinogen (1,2)

suspect mutagen (1,3)

neurotoxin (4)

long-term toxicity:

 plants: mutagen (1)

ethylbenzene

CAS # 100-41-4

teratogen (1)

ryania

Bonide Ryatox; Ryanex; Ryanexcel; Ryanicide

ryanodine, the active insecticidal principle from shrub Ryania speciosa

CAS # 8047-13-0 (ryania) 15662-33-6 (ryanodine)

botanical

insecticide

?

oral: medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 fish: medium (2)

 bees: low (3)

oil: “insoluble”

sabadilla

caustic barley; Cavdilla; Sabacide; Sabane Dust; sevadilla; Shirlan; Veratrine

from lily plant Schoenocaulon officinale (Asagraea officinalis, Sabadilla officinalum); active ingredients are of a complex of alkaloids known collectively as verarin; two of these are cevadine & veratridine

CAS # 8028-57-7

botanical

insecticide

“lost activity rapidly on exposure to sunlight” (1)

oral: medium (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 bees: medium (2)

water: “slightly soluble”

oil: “slightly soluble”

safrole

AA Outdoor Dog Repellent; Rhyuno oil; Shikimol; Shikimole; yellow camphor oil

4-allyl-1,2-methylene dioxybenzene; oil of camphor sassafrass

CAS # 94-59-7

methylenedioxyphenyl

repellent

voluntary cancellation USA, 1977

?

oral: medium (1)

dermal: ?

inhalation: ?

carcinogen (2,3)

crosses placenta (3)

liver damage (4)

water: “insoluble” “combustible”

transformation product(s):

dihydrosafrole

1,2-methylenedioxy-4-propylbenzene

CAS # 94-58-6

methylene dioxy phenyl

intermediate in the synthesis of piperonyl butoxide

oral: medium (1)

carcinogen (1,2)

184 siduron

Supersan in Trey Triple Action Lawn Aid; Trey; Tupersan

1-(2-methylcyclohexyl)-3-phenylurea

CAS # 1982-49-6

urea

herbicide

non-pers to mod-pers (1,2)

oral: low (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 bees: low (3)

water: slightly soluble

volatile

silica aerogel

Cab-O-Sil; Dri-Die; Drianone; Drione (with pyrethrins); Santocel C; SG-67; silica gel; Silikil; Silox; Sprotive Dust SG-67; Warpath (with pyrethrins)

amorphous (fumed) silica dust: 3 micron particiles of silicon dioxide; many formulation contain less than 5% ammonium fluosilicate

CAS # 7631-86-9

metal/mineral

silica

insecticide dessicant

pers

oral: low (1)

dermal: low (1)

inhalation: ?

lung damage (2)

immediate toxicity:

  injures mushrooms (3)

silvex

2,4,5-TP; Aqua-Vex; Ded-Weed; Double Strength; Esteron; Fenoprop; Fruitone T; Garlon; Kuron; Kurosal; Scott’s O-X-D; Silvi-Rhap; Weedone 2,4,5-TP; Weedone TP

2-(2,4,5-trichlorophenoxy)propionic acid

CAS # 93-72-1

phenoxy

herbicide

cancelled USA,1985

mod-pers (1)

oral: medium (2)

dermal: ?

inhalation: ?

teratogen (3)

liver and kidney damage (4)

immediate toxicity:

 birds: low to medium (5)

 fish: medium to high (1)

 amphibians: low to medium (1)

 crustaceans: high (1)

 bees: low (4)

long-term toxicity:

  

 fish: reproductive and liver damage; cumulative (1)

 molluscs: decrease in shell growth (1)

water: soluble

non-volatile to slightly volatile

contaminant(s):

TCDD

(see chloroneb)

simazine

Amizine (with amitrole); Aquazine; Batazina; CDT; CET; Framed; Gesatop; Herbazin; Herbex; Herbox; Herboxy; Hungazin DT; Premazine; Primatol S; Princep; Printop; Radocon; Simadex; Zeapur

2-chloro-4,6-bis(ethylamino)-s-triazine

CAS # 122-34-9

triazine

herbicide soil sterilant

mod-pers to pers (1,2)

oral: low to medium (3,4)

dermal: low to medium (4)

inhalation: low to medium (4)

testes, kidneys, liver & thyroid damage (5)

disturbances in sperm production (5)

immediate toxicity:

 birds: low (6)

 fish: low to medium (4)

 crustaceans: low (4)

 molluscs: low to high (4)

 bees: low (7)

 aquatic insects: medium to high (6)

water: slightly soluble

oil: slightly soluble

non-volatile

“nonflammable”

soap

Cryptocidal Soap; De-Moss; Safer’s Fungicidal Soap; Safer’s Herbicidal Soap; Safer’s Insecticidal Soap

potassium salts of selected fatty acids; cocoa fatty acids

miscellaneous

miticide insecticide algacide herbicide for moss, lichen & liverwort fungicide

?

oral: low (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: low (1)

 fish: low (1)

 bees: “very low” (1)

long-term toxicity:

 plants: toxic to some in high concentrations (2)

water: “highly soluble”

185 sodium azide

Benzide; Noxide; Smite 15G

sodium azide

CAS # 26628-22-8

azide

herbicide fungicide nematocide insecticide soil fumigant

non-pers (1)

oral: very high (2)

dermal: very high (2)

Inhalation: “avoid breathing dust of vapor”

(1)

suspect mutagen (3)

BIOCIDE

immediate toxicity:

 fish: high (4)

 crustaceans: medium (4)

 aquatic insects: medium (4)

long-term toxicity:

 plants & bacteria: mutagen (1)

water: very soluble

transformation product(s):

hydrazoic acid

“highly volatile” (1)

sodium chlorate

Altacide Extra (with atrazine); Altavar (with atrazine & 2,4-D); Chlorax; De-Fol-Ate; Drop-Leaf; Fall; Helena “Clean Up” (with bromacil); Klorex; Kusatol; MBC*; Polybor chlorate; Rasikal; Shed-A-Leaf; Tumbleaf; Ureabor; Weed-Killer #50 (with bromacil & sodium metaborate)

*also used for carbendazim

CAS # 7775-09-9

miscellaneous

herbicide

?

oral: low (1)

dermal: ?

inhalation: ?

methemoglobinemia (2)

kidney damage (2)

immediate toxicity:

 fish: low (3)

long-term toxicity:

 birds: reduction in egg production and fertility (3)

water: very soluble

“dangerously flammable”

sodium cyanide

Cymag; M-44 devices

hydrocyanic acid, sodium salt

CAS # 143-33-9

cyanide

fumigant insecticide rodenticide cancelled most uses, USA, 1988

?

oral: very high

dermal: ?

inhalation: ?

?

?

transformation product(s):

hydrogen cyanide

(see hydrogen cyanide)

sodium fluoroacetate

Compound 1080; Fratol; Yasoknock

sodium fluoroacetate

CAS # 62-74-8

fluoroacetate

rodenticide

suspended, 1972 cancelled, most uses, USA, 1985

?

oral: very high (1,2)

dermal: very high (8)

inhalation: very high (8)

can cause secondary poisoning (3) no antidote (8)

neurotoxin, heart damage (4,5)

kidney, liver, nerve, and thyroid damage (6)

delayed convulsant (fluoroacetate) (7)

immediate toxicity:

 birds: very high (2)

 amphibians: high (2)

 insects: “toxic” (8)

water: “very soluble”

oil: “low solubility”

“non-volatile”

transformation product(s):

fluorocitrate

(see fluoroacetamide)

sodium hypochlorite

CAS # 7681-52-9

miscellaneous

antibiotics, algacide, fungicide

?

oral: high (1)

dermal: “corrosive” (1)

?

186 sodium omadine

Omadine sodium

1-hydroxy-2(1 H)-pyridinethione, sodium salt (CA)

CAS # 15922-78-8

miscellaneous

antibiotic

?

oral: medium (1)

dermal: ?

inhalation: ?

suspect fetotoxin (2)

hind limb paralysis (2)

immediate toxicity:

 birds: “slightly toxic” (2)

 fish: “slightly to very toxic”

 aquatic invertebrates:

 “very toxic” (2)

streptomycin

O-2-deoxy-2-methylamino- α-l-glucopyranosyl-(1→2)-O-5-deoxy-3-C-formyl-α-l-lyxofuranosyl-(1→4)-N 3,N 3-diamidino-d-strepamine

CAS # 57-92-1

antibiotic

antibiotic, fungicide

oral: low (1)

dermal: ?

inhalation: ?

ear damage (2)

water: very soluble

strychnine

strychinidin-10-one

CAS # 57-24-9

botanical

rodenticide, avicide

most uses cancelled, USA by 1988

“stable in the enviornment” (1)

oral: very high (2)

dermal: ?

inhalation: “do not inhale” (3)

immediate toxicity:

 birds: very high (1)

 amphibians: very high (2)

long-term toxicity:

 secondary poisoning

water: slightly soluble

“nonflammable”

sulfoTEPP

ASP-47; Baldafume; BAY-E-393; Bladafum; dithio; dithione; dithioTEPP; Formula 40; Formula CH-200; Lethalaire G-57 Aerosol insecticide; Sulfatep; sulfotep; sulfoTEPP; TEDP; thiotepp

O, O, O, O-tetraethyldithiopyrophosphate; tetraethyl thiodiphosphate

CAS # 3689-24-5

organophosphate

insecticide acaricide

?

oral: very high (1)

dermal: very high (2)

inhalation: very high (1)

?

immediate toxicity:

 birds: high (3)

water: slightly soluble

volatile

sulfur

Bolda (with maneb & carbendazim); brimstone; Colsul; Corosul D and S; Cosan; flour sulfur; flowers of sulfur; Hexasul; Kolo-100 (with dichlone); Kolofog; Kolospray; Kumulus S; Magnetic 70, 90 and 95; precipitated sulfur; Sofril; Spersul; Sulforon; Sulkol; Thiolux; Thiovit sulfur

CAS # 7704-34-9

metal/mineral

sulfur

fungicide acaricide

perm

oral: low (1)

dermal: high (1)

inhalation: low to medium (1)

?

immediate toxicity:

 birds: low (1)

 fish: low (1)

 estuarine/marine organisms: low (1)

 aquatic invertebrates: low (1)

water: “insoluble”

compound(s):

sulfuryl fluoride

sultropene (France); Vikane

CAS # 2699-79-8

metal/mineral

sulfur

fumigant

restricted use, USA, all formulations

oral: high (1)

inhalation: medium (1)

liver and kidney damage (2)

mottled teeth (2)

osteosclerosis (3)

immediate toxicity:

 plants: toxic to some (1)

water: soluble

highly volatile

sulprofos

Bolstar; Helothion

O-ethyl O-4-(methylthio)phenyl S-propylphosphorodithioate

CAS # 35400-43-2

organophosphate

insecticide

restricted use, USA

non-pers to mod-pers (1)

oral: high (1)

dermal: high (1)

inhalation: ?

?

immediate toxicity:

 birds: high (1)

 fish: “highly toxic” (2)

water: soluble

187 2,4,5-T

Bandock (with dicamba & mecoprop); Brushtox; Dacamine; Ded-Weed; Fence Rider; Forron; Fruitone A; Inverton 245; Line Rider; Nettle-Ban (with 2,4-D & dicamba); Reddon; Spontox (with 2,4-D); Tormona; Transamine; Tributon; Trinoxol; Veon 245; Verton 2T; Visko Rhap; Weedar; Weedone

2,4,5 trichlorophenoxyacetic acid

CAS # 93-76-5

phenoxy

herbicide

cancelled USA,1985

non-pers to mod-pers (1,2)

oral: medium to high (16)

dermal: high

(7,8)

inhalation: ?

suspect carcinogen (16)

teratogen (7,8)

fetotoxin (7)

liver & kidney damage (9)

immediate toxicity:

 birds (chicks): high (9)

 fish: low to high (4)

 bees: low to medium (10)

long-term toxicity:

 birds: may cause behavioral effects (11)

 suspect embryotoxin (12)

water: “insoluble” esters

non-volatile to slightly volatile

contaminant(s):

2,4,5-trichlorophenol

(see 2,4,5-trichlorophenol)

transformation product(s):

2,4,5-trichlorophenol

(see 2,4,5-trichlorophenol)

TCDD

(see chloroneb)

tebuthiuron

Brulan; Brush Bullet; Bushwacker; Combine; E-103; Perfmid; Preflan; Prefmid; Reclaim; Scrubmaster; Spike; Tebulan; Tiurolan

1-(5-tert-butyl-1,3,4-thiadiazol-2-yl)-1,3-dimethylurea

CAS # 34014-18-1

urea

herbicide

mod-pers to pers (1)

oral: medium to high (2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: low to medium (3)

 fish: low (3)

 water: soluble

slightly volatile

“nonflammable”

tefluthrin

Elancolan K (with napropamide); Forca; Force; Forza; PP 993; tefluthrine

2,3,5,6-tetrafluoro-4-methylbenzyl (Z)-(1RS)-cis-3-(2-chloro-3,3,3-trifluroprop-1 -enyl]-2,2-dimethylcyclopropanecarboxylate

CAS # 79538-32-2

pyrethroid

insecticide

non-pers to mod-pers (1,2)

oral: very high (1)

dermal: high (1)

inhalation: high (1)

?

immediate toxicity:

 birds: low to medium (1,2)

 fish: very high (1,2)

 crustaceans: very high (2)

 molluscs: high (2)

water: insoluble

slightly volatile

combustible

temephos

Abat; Abate; Abathion; Abazan (with trichlofon); AC 52160; Biothion; Difenthos; Nimitex; Nimitox; Swebate; temophos

O,O,O′,O′-tetramethyl O,O′-thiodi-p-phenylene phosphorothioate;

O,O′-(thio-4,1 -phenylene)bis[O,O-dimethyl phosphorothioate]

CAS # 3383-96-8

organophosphate

insecticide

non-pers (1)

oral: low to medium (2,3)

dermal: medium (4)

inhalation: ?

liver damage (3)

immediate toxicity:

 birds: high to very high (5)

 fish: low to high (6)

 amphibians: low to medium (5)

 crustaceans: very high (7)

 aquatic insects: very high (6)

 bees: high (8)

 water: insoluble

TEPP

Fosuex; G-52 and 56; Gy-TET 40; HETP;

Killex; Killmite; Lethalaire; Lico-40; Nifos T; Pyfos; Pyro-Phos; Teep; TEP; Tetradusto 100; Tetraspra; Tetron; Tetron-100; Vaptone

hexaethyl tetraphosphate; tetraethyl prophosphate

CAS # 107-49-3

organophosphate

insecticide acaricide

cancelled USA, 1984

?

oral: very high (1)

dermal: very high (1)

inhalation: very high (1)

?

BIOCIDE

immediate toxicity:

 birds: very high (2)

 fish: high (2)

 amphibians: high (2)

 crustaceans: very high (2)

 bees: very high (3)

188 terbacil

DuPont Herbicide 732; Geonter; Sinbar

3-tert-butyl-5-chloro-6-methyl uracil; 5-chloro-3-(1,1 -dimethylethyl)-6-methyl-2,4-(1 H,3H)-pyrimidinedione

CAS # 5902-51-2

uracil

herbicide

mod-pers (1)

oral: low (1)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: low to medium (2)

 fish: low (2)

 crustaceans: low (2)

 bees: low (3)

 molluscs: low to medium (2)

water: soluble

slightly volatile

“nonflammable”

terbucarb

Azac; Azak; Azar; Hercules 9573; terbutol (discontinued)

2-6-di-tert-butyl-p-tolyl methylcarbamate

CAS # 1918-11-2

carbamate

herbicide

mod-pers (1)

oral: low (2)

dermal: medium (3)

inhalation: ?

?

immediate toxicity:

 bees: low (4)

water: slightly soluble

oil: insoluble

terbufos

AC 92100; Aragran; Contraven; Corliss (with phorate); Counter; Counter 15G Soil Insecticide; Counter Plus; Cygard (with phorate); Dispell; ST100

S-[tert-butylthiomethyl] O,O-diethylphosphorodithioate

CAS # 13071-79-9

organophosphate

insecticide nematocide

restricted use, USA

non-pers (1)

oral: very high (2)

dermal: very high (3)

inhalation: very high (1)

eye & stomach damage (4)

“disturbance to fetal

development”

(4)

immediate toxicity:

 birds: very high (3)

 fish: very high (2)

 crustaceans: very high (3)

water: slightly soluble

volatile

flammable

transformation product(s):

formaldehyde

(see formaldehyde)

terbutryn

Clarosan; Gesaprim combi (with atrazine); GS 14260; Igran; Plantonit; Preban; Prebane (Gr. Britain); Reflex (with fomesafen); Short Stop E; terburyne; Terbutrex

2-(tert-butylamino)-4-(ethylamino)-6-(methylthio)-s-triazine;

N-(1,1-dimethylethyl)- N′-ethyl-6-(methylthio)-1, 3,5-triazine-2,4-diamine

CAS # 886-50-0

triazine

herbicide

non-pers (1)

oral: medium (1,2)

dermal: low (2)

inhalation: low to medium (3)

suspect carcinogen (2)

immediate toxicity:

 birds: low to medium (4)

 fish: medium to high (2)

 crustaceans: medium (2)

 bees: low (5)

water: slightly soluble

slightly volatile

“nonflammable”

tetrachloroethylene

Ankilostin; carbon bichloride; carbon dichloride; Didakene; ethylene tetrachloride; Nema; per; perc; perchloethylene; perchlor; perchloroethylene; Perclene; perk; Tetracap; tetrachloroethene; Tetropil

1,1,2,2-tetrachloroethylene

CAS # 127-18-4

organochlorine

fumigant

pers (1)

oral: low to medium (2)

dermal: ?

inhalation: low (2)

carcinogen (3,4)

suspect mutagen (3,5)

suspect teratogen (3,4)

kidney, liver and respiratory damage (3,6)

immediate toxicity:

 fish: low to medium (1)

long-term toxicity:

 crustaceans: mutagen (7)

 plants: mutagen (5)

water: soluble

highly volatile

“nonflammable”

transformation product(s):

hexachlorobenzene

(see hexachlorobenzene)

189 tetrachlorvinphos

Z-2-chloro-1-(2,4,5-trichlorophenyl)vinyl

dimethylphosphate

CAS # 22248-79-9

organophosphate

insecticide

non-pers (1)

oral: medium (1)

dermal: low to medium (2)

inhalation: ?

carcinogen (3)

immediate toxicity:

 birds: low to medium (4)

 fish: medium to high (1)carcinogen (3) 

 bees: high (5)

water: slightly soluble

non-volatile

tetradifon

Childion; Dorvert; Folimat T (with omethoate); Kelthion; Neutron (with methyl parathion); Tedane (with dicofol); Tedane Combi PB (with dicofol & dinocap); Tedane Extra (with dincap & dicofol); Tedion V-18; Tedov; Turbair Acaricide (with dicofol)

4-chlorophenyl 2,4,5-trichlorophenyl sulfone; 2,4,4′,5-tetrachlorodiphenyl sulfone

CAS # 116-29-0

organochlorine

acaricide

suspended USA

pers (1)

oral: low (2)

dermal: medium (3)

inhalation: ?

suspect mutagen (7)

suspect teratogen (1)

liver and kidney damage (1)

immediate toxicity:

 birds: low to medium (4)

 fish: medium to high (5)

 crustaceans: very high (5)

 bees: low (6)

water: insoluble

oil: soluble

non-volatile “combustible”

contaminant(s):

2,4,5-T

chlorinated dibenzodioxins

(see class description)

dibenzodioxin

tetramethrin

Butamin; Doom; Duracide 15 (with piperonyl butoxide); Ecothrin; FMC 9260; Multicide; Neo-Pynamin Forte Aerosol (with phenothrin); OMS 1011; Pesguard ANS (with fenitrothion); Pesguard FS (with phenothrin); Pesguard Insect Killer (with phenothrin); Pesguard NS (with fenitrothion); Pesguard NSB (with fenitrothion & piperonyl butoxide); phthalthrin; Py-Kill; Residrin; SP 1103; Sprigone; Spritex; tetramethrine

3,4,5,6-tetrahydrophthalimidomethyl (±)-cis,trans-chrysanthemate

CAS # 7696-12-0

pyrethroid

insecticide

?

oral: low to medium (1,2)

dermal: low to medium (3)

inhalation: ?

?

water: slightly soluble

non-volatile to slightly volatile

isomer(s):

tetramethrin (1R)-isomers

pyrethroid

insecticide

oral: low (1)

immediate toxicity:

 fish: very high (1)

water: slightly soluble

slightly volatile

thiabendazole

Aliette Extra (with fosetyl-al & captan); Apl-Luster; Arbotect; Bioguard; Elmpro; Mertect; RPH; TBZ; Tecto; Thibenzole; Tobaz

2-(4-thiozolyl)-benzimidazole

CAS # 148-79-8

benzimidazole

fungicide

mod-pers (1)

oral: medium (2)

dermal: ?

inhalation: “low” (3)

mutagen (4)

suspect teratogen (5)

blood and bone marrow damage (6)

immediate toxicity:

 earthworm: very high (7)

 fish: low (7)

water: slightly soluble

“volatile at 310 degrees”

190 thiophanate ethyl

Cercobin; Nemafax; Topsin; Verdamax

diethyl 4,4′-(o-phenylene)bis(3-thioallophanate)

CAS # 23564-06-9

carbamate

fungicide

cancelled all products, USA

?

oral: low (1)

dermal: low to medium (2)

inhalation: medium (2)

thyroid damage(3)

immediate toxicity:

 birds: low to medium (2)

 fish: medium (2)

 aquatic invertebrates: medium

thiophanate methyl

Cercobin M; Ditek; Fungo; Hitrun (with vinclozolin); Labilite; Mildothane; NF-44; TD-1881; Thiophanate M; Topsin M; Zyban

dimethyl[1,2-phenylene)bis (iminocarbonothioyl)] bis[carbamate]; dimethyl 4,4′-o-phenylenebis (3-thioallophanate); bis[3-(methoxycarbonyl)-2-thioureido]benzene

CAS # 23564-05-8

carbamate

fungicide

non-pers (1)

oral: low (2)

dermal: low to medium (3)

inhalation: low to medium (3)

decreased body weight of newborn (4)

immediate toxicity:

 birds: low (3)

 fish: medium to high (3)

 earthworms: very high (5)

water: “insoluble”

transformation product(s):

carbendazim

(see carbendazim)

thiram

Accelerator Thiuram; Aules Chipco Thiram 75; Cyuram DS; Deksan; Ekagom TV; Fernasan; Hexthir; Mercuram; Nobencutan; Panoram; Pomarsol Forte; Royal TMTD; Spotrete; Thioknock; Thirasan; Trameton; Tripomol; Tuads; Tues; Tulisan; Vulkacit MTIC

bis(dimethylthiocarbamoyl)disulfide; tetramethylthiuram disulfide; tetramethylthiperoxydicarbonic diamide

CAS # 137-26-8

thiocarbamate

fungicide animal repellent

non-pers (1)

oral: medium (2)

dermal: ?

inhalation: low to high (3)

avoid alcohol ingestion before or after exposure (see disulfiram) (14)

cumulative (4)

suspect mutagen (5,6)

teratogen (7,8)

liver damage (9,10)

immediate toxicity:

 birds: medium to high (3)

 fish: medium to high (3)

 bees: medium (11)

long-term toxicity:

 birds: excess build-up of cartilage in legs (12); reproductive damage (13)

 plants: suspect mutagen (8)

water: slightly soluble

related compound(s):

disulfiram

Antabuse; deters alcohol ingestion; ethyl analogue of thiram

tetraethylthiuram disulfide

neurological effects; 10 times less toxic than thiram (1)

suspect teratogen (1,2)

liver damage (1)

transformation product(s):

N-nitrosodimethylamine

(see ferbam)

tin

compound(s):

CAS # 7440-31-5

compound(s):

metal/mineral

tin

perm

oral: ?

dermal: ?

inhalation: ?

?

191 cyhexatin

cyhexan; Dowco 213; Plictran

tricyclohexyl hydroxytin; tricyclohexyhydroxystannane; tricyclohexyltin hydroxide

CAS # 13121-70-5

organic

acaricide

cancelled USA,1987

oral: medium (1)

dermal: low to high (1,2)

inhalation: ?

immediate toxicity:

 birds: medium (2)

 bees: medium (3)

water: “insoluble”

fenbutatin-oxide

Bendex; Neostanox; SD-14114; Torque; Vendex

hexakis(2-methy-2-phenylpropyl)distannoxane; bis[tris(2-methyl-2-phenylpropyl)tin]oxide

CAS # 13356-08-6

organic

acaricide

oral: low to medium (1)

immediate toxicity:

 birds: low to high (2)

 fish: high (1) 

 bees: low (3)

water: “insoluble”

fentin hydroxide

Dowco 186; Du-Ter; Duter; Super Tin; Suzu H; TPTH; TPTOH; triphenyltin hydroxide (USA, So. Africa); Tubotin; Vancide KS

triphenyltin hydroxide; hydroxytriphenylstannane

CAS # 76-87-9

organic

fungicide

some formulations restricted use, USA

non-pers to mod-pers (1)

oral: high (1)

dermal: high to very high (2)

inhalation: very high (1)

teratogen (1)

immunotoxin (1)

immediate toxicity:

 birds: high (3)

 fish: very high (4)

 bees: low (5)

water: slightly soluble

non-volatile

combustible

tributyltin chloride complex

Tin San

tributyltin chloride complex

CAS # 1461-22-9

organic

restricted use, USA

immediate toxicity:

 fish: very high (1)

long-term toxicity:

 fish: liver damage, reduces growth (1)

tributyltin fluoride

fluorobutylstannane; tributyl stannane fluoride

CAS # 1983-10-4

organic

restricted use, USA

immediate toxicity:

 amphibians: very high (1)

tributyltin oxide

bioMET; Butinox; C-Sn-9; TBTO

bis(tributyltin) oxide; bis(tri-n-butyltin) oxide; hexabutyldistannoxane

CAS # 56-35-9

organic

fungicide (wood preservative) insect repellent

restricted use, USA

oral: high (1)

suspect mutagen (2)

teratogen (3)

immediate toxicity:

 birds: high (4)

 amphibians: very high (5)

triphenyltin acetate

acetoxy-triphenylstannane; Batasan; Brestan; fentin acetate; phentinoacetate; Suzu; Tinamte; TPTA triphenyltin acetate

CAS # 900-95-8

organic

fungicide algaecide mollusicide

oral: high (1)

dermal: high (2)

inhalation: very high (1)

immediate toxicity:

 birds: high (3)

 fish: very high (4)

water: slightly soluble

toluene

Methacide; methylbenzene; phenylmethane; toluol

toluene

CAS # 108-88-3

aromatic hydrocarbon

solvent

?

oral: low (1)

dermal: ?

inhalation: ?

neurotoxin (2)

addictive (3)

brain damage (3)

hearing loss (4)

behavioral effects (5)

immediate toxicity:

 fish: low to medium (6)

long-term toxicity:

 fish: embryotoxin (6)

 crustaceans: teratogen (7)

water: “slightly soluble” flammable

192 toxaphene

Agricide Maggot Killer; Alltox; camphechlor (So. Africa); Camphoclor; Camphofene Huileux; Chem-phene; Clor Chem T-590; Cristoxo; Estanox; Fasco-Terpene; Geniphene; Motox; Octachlorocamphene; Penphene; Phenacide; Phenatox; polychlorocamphene (USSR); Toxadusto-10; Toxakil; Toxaspra-8

mixture of various chlorinated camphenes

CAS # 8001-35-2

organochlorine

insecticide acaricide

cancelled, all products, USA, 1982

pers (1)

oral: high to very high (2)

dermal: ?

inhalation: ?

carcinogen (1,3)

suspect mutagen (4)

suspect fetotoxin (3,5)

liver & kidney damage (1,3)

neurotoxin (8)

adrenal damage (6)

blood damage (1)

immediate toxicity:

 birds: medium to very high (9)

 fish: very high (10)

 amphibians: very high (2)

 crustaceans: high to very high (2)

 bees: medium (11)

 molluscs: high to very high (2)

 aquatic insects: very high (2)

long-term toxicity:

 bioaccumulates in aquatic plants, invertebrates, fish, & birds (2)

 birds: thyroid damage; affects egg production; decrease in backbone collagen (2)

 fish: liver & kidney damage; decrease in backbone collagen; spinal deformities; reduced egg viability (1)

 crustaceans: reduced offspring; reduced growth (1)

 molluscs: effects on shell growth & reproduction (12)

 phytoplankton: decreased photosynthesis (12)

water: slightly soluble

oil: “soluble” highly volatile

tralomethrin

HAG 107; NU 831; OMS 3048; RU 25474; Scout; Scout X-Tra; Tracker; Tralate; tralomethrin

(S)-α-cyano-3-phenoxybenzyl(1R,3S)- 2,2,-dimethyl-3[(RS)-1,2,2,2-tetrabromoethyl]cyclopropanecarboxylyate

CAS # 66841-25-6

pyrethroid

insecticide

?

oral: medium to high (1)

dermal: low to medium (1)

inhalation: high (2)

?

immediate toxicity:

 birds: medium (2)

 fish: very high (1)

 crustaceans: very high (1)

water: slightly soluble

non-volatile

triadimefon

Amiral; BAY ME B6447; Bayleton; Bayleton Total (with carbendazim); Bayleton Triple (with captafol & carbendazim)

1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-2-butanone

CAS # 43121-43-3

triazole

fungicide

mod-pers to pers (1)

oral: low to medium (1)

dermal: low to medium (2)

inhalation: low to high (1)

?

immediate toxicity:

 birds: medium (1)

 fish: low to medium (1)

water: slightly soluble

slightly volatile

flammable

triallate

Buckle (with trifluralin); CP 23426; DATC-BW; Far-Go; tri-allate

193 S-2,2,3-trichloroallyl

di-isopropylthiolcarbamate

CAS # 2303-17-5

thiocarbamate

herbicide

mod-pers (1)

oral: medium (2)

dermal: low to medium (1)

inhalation: ?

suspect carcinogen (3)

suspect mutagen (4)

suspect neurotoxin (3)

brain, liver, and spleen damage (5)

immediate toxicity:

 birds: low to medium (1)

 fish: high (2)

 crustaceans: high (2)

 bees: low to medium (6)

long-term toxicity:

 birds: liver, kidney, and reproductive damage; (7)

delayed neurotoxicity (3)

water: slightly soluble volatile

“nonflammable”

triazophos

Deltaphos (with deltamethrin); Hostathion

O,O-diethyl O-1-phenyl-1 H-1,2,4-triazol-3-yl phosphorothiote

CAS # 24017-47-8

organophosphate

insecticide

mod-pers (1)

oral: high (2)

dermal: low to medium (2)

inhalation: ?

suspect mutagen (3)

immediate toxicity:

 birds: very high (4)

 fish: medium (4)

water: slightly soluble

slightly volatile

trichlorfon

Anthon; BAY L 13/59; Bovinox; Briten; Cekufon; chlorofos (USSR); Ciclosam; Danex; Denkaphon; Dipterex; Diptetes; Ditrifon; Equino-Acid; Leivasom; metrifonate;

Neguvon; Proxol; trichlorofon; Trinex; Tugon

dimethyl (2,2,2-trichloro-1-hydroxyethyl)- phosphonate

CAS # 52-68-6

organophosphate

insecdticide

mod-pers (1)

oral: high (2)

dermal: low to medium (2)

inhalation: low to high (3)

suspect carcinogen (4,5)

suspect mutagen (4,7)

suspect teratogen (4)

fetotoxin (8)

bone marrow & liver damage(4,9)

immunotoxin(10)

BIOCIDE

immediate toxicity:

 birds: high to very high (11)

 fish: medium to high (12)

 aquatic insects: very high (12)

 crustaceans: medium to very high (12)

 aquatic worms: very high (13)

 bees: medium (14)

long-term toxicity:

 plants: suspect mutagen (15)

water: very soluble

oil: “insoluble” slightly volatile

transformation product(s):

dichlorvos

(see dichlorvos)

2,4,5-trichlorophenol

2,4,5-TCP; Collunosol; Dowicide 2; Preventol

2,4,5-trichlorophenol

CAS # 95-95-4

organochlorine

Antibiotic fungicide

cancelled USA, 1987

non-pers to mod-pers (1)

oral: medium (2)

dermal: ?

inhalation: ?

kidney & liver damage (3)

long-term toxicity:

 plants: suspect mutagen (3)

water: soluble

highly volatile

contaminant(s):

pentachlorodibenzo-p-dioxin

(see dibenzodioxin class)

dibenzodioxin

1,3,6,8-tetrachlorodibenzo-p-dioxin

(see dibenzodioxin class)

dibenzodioxin

water: insoluble

2,7-dichlorodibenzo-p-dioxin

(see 2,4-D)

TCDD

(see chloroneb)

194 2,4,6-trichlorophenol

2,4,6-TCP; Dowicide 2S; Omal

2,4,6 trichlorophenol

CAS # 88-06-2

organochlorine

bactericide insecticide fungicide wood preservative

?

oral: medium (1,2)

dermal: ?

inhalation: ?

carcinogen (1)

may cause central nervous system damage (3)

?

contaminant(s):

TCDD

(see chloroneb)

pentachlorodibenzofuran

(see PCB’s)

hexachlorodibenzofuran

(see pentachlorophenol)

triclopyr

Broadshot (with dicamba & 2,4-D); Crossbow; Dowco 233; Fettel (with dicamba & mecoprop); Garlon (also a name for silvex); Garlon 3A; Garlon 4; Herbaron B (with dicamba & mecoprop); Turflon

3,5,6-trichloro-2-pyridinyloxyacetic acid

CAS # 55335-06-3

organochlorine

herbicide

mod-pers (1)

oral: medium to high (2,3)

dermal: ?

inhalation: ?

suspect carcinogen (4,5)

suspect mutagen (4)

immediate toxicity:

 birds: medium (2)

 fish: low, (Garlon 4: high) (3)

 crustaceans: low (6)

water: soluble

slightly volatile

combustible

trifluralin

Buckle (with triallate); Cannon (with alachlor); Carpidor; Commence (with clomazone); Ipersan; Janus; Laurel; Lextra (with linuron); Mudekan; Salute (with metribuzin); Su Seguro Cardidor; Trefanocide; Treficon; Treflan; trifluraline (France)

α,α,α-trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine

CAS # 1582-09-8

dinitroaniline

herbicide

cancelled, most uses, USA, 1982

mod-pers (1,2)

oral: low (3)

dermal: low to medium (4)

inhalation: ?

suspect carcinogen (5,6) suspect mutagen (7,8) suspect teratogen (9)

fetotoxin (5)

immediate toxicity:

 birds: low (5)

 fish: high to very high (10)

 amphibians: very high (11)

 crustaceans: high to very high (10)

 bees: low to medium (12)

 aquatic insects: medium (10)

water: insoluble

volatile

contaminant(s):

N-nitroso-di-n-propylamine

oral: high (1)

carcinogen (2,3)

mutagen (4,5)

trimethacarb

Broot; Landrin; OMS 597; UC 27867

3,4,5-trimethylphenyl methylcarbamate

CAS # 2686-99-9

carbamate

insecticide

non-pers to mod-pers (1)

oral: high (2)

dermal: low to medium (2)

inhalation: ?

?

immediate toxicity: “toxic to fish and wildlife” (3)

water: slightly soluble

slightly volatile

vamidothion

Kilval; Kilvar; Trucidor; Vamidoate

O,O-dimethyl S-2-(1-methylcarbamoylethylthio) ethylphosphorothioate

CAS # 2275-23-2

organophosphate

insecticide

not registered for use in USA

non-pers (1)

oral: high to very high (2)

dermal: ?

inhalation: ?

?

immediate toxicity:

 birds: very high (1)

 fish: low (1)

water: very soluble

oil: “soluble”

“negligible vapor pressure”

195 vernolate

Reward (with atrazine); Surpass (with dichlormid); Vernam (with atrazine)

S-propyl dipropylthiocarbamate

CAS # 1929-77-7

thiocarbamate

herbicide

non-pers (1)

oral: medium (2)

?

immediate toxicity:

 fish: medium (3)

 crustaceans: medium (3)

 bees: low to medium (4)

water: slightly soluble

oil: “miscible”

volatile

combustible

vinclozolin

BAS-3520; Hitrun (with thiophanate-methyl); Konker (with carbendazim); Ornalin;

Ronilan; Ronilan M (with maneb); Ronilan S Combi (with sulfur); Ronilan Spezial (with chlorothalonil); Silbos (with thiram); Vorlan

(R,S)-3-(3,5-dichlorophenyl)-5-methyl-5-vinyl-1,3-oxazolidinedione

CAS # 50471-44-8

amide

fungicide

?

oral: low (1)

dermal: low to medium (2)

inhalation: low (1)

?

immediate toxicity:

 birds: low to medium (2)

 fish: low (1)

water: slightly soluble

oil: soluble

slightly volatile

warfarin

Arab Rat Deth; coumafene (France); Dethmor; Eastern States Duocide; Fasco Fascrat Powder; Fatal; Kypfarin; Martin’s Mar-Frin; Rat & Mice Bait; Rat Gard; Rat-Death; Rat-Kill; Rat-Mix; Rat-Nix; Rat-O-Cide; Rat-Ola; Rataway; Twin Light Rat Away; Warfarat; zoocoumarin (USSR & Netherlands)

3-(α-acetonylbenzyl)-4-hydroxycoumarin

CAS # 81-81-2

coumarin

rodenticide

?

oral: high (1)

dermal: ?

inhalation: ?

teratogen (2,3)

water: slightly soluble

slightly volatile

xylene

ksylene (Poland); xiloli (Italian); xylenen (Dutch); xylol (German)

dimethylbenzene

CAS # 1330-20-7 108-38-3 (meta isomer) 95-47-6 (ortho isomer) 106-42-3 (para isomer)

(commercial xylene is a mixture of isomers)

aromatic hydrocarbon

solvent herbicide

non-pers (1)

oral: medium (2)

dermal: ?

inhalation: low (3)

suspect teratogen (3)

suspect neurotoxin (3)

skin damage (4)

water: “insoluble”

highly volatile

flammable

contaminant(s):

benzene

(see benzene)

zinc phosphide

Gopha-Rid; idall-Zinc; Kilrat; Mole and Gopher Bait; Mouse-con; Phosvin; Rodent Pellets; Rumetan

zinc phosphide

CAS # 1314-84-7

metal/mineral

zinc

insecticide rodenticide

restricted use, USA

“confined, in many countries, to trained personnel”

non-pers “under exposed acid-free conditions will remain active for long periods of time” (1)

“stable when dry” (2)

oral: very high (1)

dermal: ?

inhalation: ?

“do not inhale, avoid skin contact” (3)

?

immediate toxicity:

 birds: very high (4)

 fish: “negligible” (5)

 crustaceans: “in stream killed many” (6)

water: insoluble

transformation product(s):

phosphine gas

(see aluminum phosphide)

196 zineb

Asporum; Blightox; Blizene; Cineb; Crittox; Crystal Zineb; Hexathane; Kupratsin; Kypzin; Lonacol; Micide; Miltox; Novozin N 50; Parzate; Pomarsol S Forte; Thiodow; Tritofterol; Zebtox; Zidan; Zinosan

zinc ethylene bisdithiocarbamate

CAS # 12122-67-7

thiocarbamate

fungicide

cancelled, most products, USA

non-pers to mod-pers (1)

oral: low (2)

dermal: low to medium (3)

inhalation: ?

anemia (3)

immediate toxicity:

 birds: low to medium (4)

long-term toxicity:

 fish: embryotoxin (5)

 amphibians: teratogen (6)

 plants: toxic to some; inhibits germination of pollen in some plants (7)

water: slightly soluble

combustible

transformation product(s):

ethylene thiourea

(see amobam)

ziram

Corozate; Cuman; Fuclasin Ultra; Fuklasin; Hexazir; Karbam; Methasen; Mezene; Milbam; Niagara Z-C Spray; Opalate; Pomarsol Z Fote; Prodaram; Tricarbamix Z; Triscabol; Vancide MZ-96; Z-C Spray; Zerlate; Zincmate; Ziram Technical

bis(dimethyldicarbamato)zinc; zinc dimethyl dithiocarbamate

CAS # 136-30-4

thiocarbamate

fungicide

non-pers (1)

oral: medium (2)

dermal: ?

inhalation: ?

suspect carcinogen (3,4)

suspect mutagen (3,5)

suspect teratogen (6,7)

bone damage (8)

immediate toxicity:

 fish: high (1)

 bees: “nontoxic” (3)

long-term toxicity:

 birds: reproductive damage (9,10)

transformation product(s):

carbon disulfide

(see carbon disulfide)

dimethylamine

(see dimethylamine)

N-nitrosodimethylamine

(see ferbam)