6 Magnetooptic Properties

CCI4tetrachloromethane58925.14.65 CHCI3trichloromethane58920.04.72 CH2Br3tribromomethane58917.99.10 CH202formicacid58920.83.04 CH2Cl2dichloromethane58911.94.65 CH2Bf2dibromomethane58915.97.97 CH2I2diiodomethane58915.04.39 CH3Clmonochloromethane589233.99 CH3Brmonobromomethane5891.55.93 CH3Imonoiodomethane58919.59.74 CH40methylalcohol58918.72.79 CH302Nmononitromethane5899.92.40

2 2 2 2 2 2

2 2 2

Verdet Constants V of Organic Liquids (from Ref. 7)-continued Formula Name 'A(nm) Teq V (rad/T m)

C2H3Br vinylbromide 589 7.8 6.11 C2H40 ethyleneoxide (I ,2-epoxiethane) 589 8.0 2.68 C2H40 acetaldehyde ( ethanal) 589 16.3 2.91 CzH402 acetic acid 589 21.0 3.04 CzH40z methylformate 589 16.5 2.79 C2H4Cl2 1, 1-dichloroethane 589 14.4 4.39 C2H4Cl2 1 ,2-dichloroethane 589 14.4 4.80 C2H4Br2 1 ,2-dibromoethane 589 15.2 7.74 C2H5Cl monochloroethane 589 5.0 3.96 CzH5Br monobromoethane 589 19.7 5.29 C2H5I monoiodoethane 589 18.1 8.58 C2H60 ethyl alcohol 589 16.8 3.29 CzH602 glycol ( 1 ,2-ethanediol) 589 15.1 3.64 C2H6S ethylmercaptan 578 16.0 5.38 C2H20 2Cl2 dichloroacetic acid 589 13.5 4.42 C2H30 2Cl chloroacetic acid ( cloroethanoic acid) 589 64.5 3.87 C2H30 2CI3 chloralhydrate 589 54.6 4.80 C2H50 2N mononitroethane 589 10.2 2.75 C3H40 acrolein (propenal) 578 20.0 5.12 C3H403 pyruvic acid (2-oxopropanoic acid) 589 14.5 3.52 C3H60 allyl alcohol 589 18.3 4.65 C3H60 propyl alcohol (!-propanol) 589 13.6 3.17 C3H60 acetone (2-propanone) 589 20 3.24 C3H602 propionic acid (propanoic acid) 589 20.3 3.20 C3H602 formic acid ethyl ester (ethylmethanoate) 589 18.8 3.05 C3H602 acetic acid methyl ester (methyl acetate) 589 20.0 3.00 C3H7CI propylchloride (1-chloropropane) 589 16.1 3.90 C3H7Cl isopropylchloride (2-chloropropane) 589 17.2 3.90 C3H7Br propylbromide (1-bromopropane) 589 19.2 5.21 C3H7Br isopropylbromide (2-bromopropane) 589 17.1 5.15 C3H7I propyliodide ( 1-iodopropane) 589 18.1 7.82 C3H7I isopropyliodide (2-iodopropane) 589 26.3 7.65 C3H80 n-propyl alcohol (!-propanol) 589 15.6 3.49 C3H80 isopropyl alcohol (2-propanol) 589 20.0 3.58 C3Hs03 glycerine (1 ,2,3-propanetriol) 589 16.0 3.87 C3H9N n-propylamine 589 9.6 3.87 C3H50 9N3 nitroglycerine 589 13.5 2.62 C3H70 2N 1-nitropropane 589 18.9 2.96 C4H6 I ,3-butadiene ( erythrene) 589 15.0 6.28 C4Hs !-butene ( a-butylene) 589 15.0 4.04 C4Hs cis-2-butene (b-butylene) 589 15.0 4.01 C4Hs trans-2-butene 589 15.0 3.75 C4H 10 butane 589 15.0 3.17 C4H10 isobutane (2-methylpropane) 589 15.0 3.23 C4H40 furan ( furfuran) 589 20.0 5.18 C4H4S thiophene (thiofuran) 589 20.0 8.23 C4H603 acetic anhydride ( ethanoic anhydride) 589 20.0 3.24

Verdet Constants V of Organic Lignids (from Ref. 7) -continued Formula Name A.(nm) T("C) V (rad/T m)

C4Hs0z n-butyric acid (butanoic acid) 589 18.8 3.35 C4H80 2 ethyl acetate (ethyl ethanoate) 589 20.0 3.14 C4Hs0z propionic acid methyl ester 589 20.0 3.11 C4H100 ethyl ether (ethoxyethane) 589 20.0 3.17 C4H100 n-butyl alcohol (!-butanol) 589 20.0 3.58 C4H100 isobutyl alcohol (2-methyl-1-propanol) 589 17.7 3.69 C4H100 sec-butyl alcohol (methylethylcarbinol) 589 20.0 3.69 CsH6 cyclopentadiene 589 15.0 5.88 CsHs 1 ,3-pentadiene 589 15.0 6.05 CsHs isoprene (2-methyl-1 ,3-butadiene) 589 15.0 6.05 CsHs cyclopentene 589 15.0 4.42 CsHIO 1-pentene 589 15.0 4.04 CsHIO isopentane (2-methyl-1-butane) 589 15.0 4.04 CsHIO cyclopentane 589 20.0 3.58 CsH12 pentane 589 15.0 3.35 C5H12 isopentane (2-methylbutane) 589 15.0 3.40 CsH402 furfural (2-furancarbonal) 578 20.0 5.99 C5H5N pyridine 589 11.9 7.50 CsHwOz propionic acid ethyl ester 589 20.0 3.29 C5H100z acetic acid propylester 589 15.7 3.29 CsHI4N2 cadaverine (1 ,5-pentanediamine) 589 14.7 4.45 C6H6 benzene 589 15.0 8.73 C6Hl2 cyclohexane 589 20.0 3.61 C6H14 hexane 589 15.0 3.49 C6H4Cl2 1 ,4-dichlorobenzene (p-dichlorobenzene) 589 64.5 7.82 C6H5F fluorobenzene (phenylfluoride) 589 19.0 7.30 C6H5Cl chlorobenzene (phenylchloride) 589 15.0 8.49 C6H5Br bromo benzene (phenylbromide) 589 15.0 9.48 C6H5I iodobenzene (phenyliodide) 589 15.0 11.8 C6H60 phenol (hydroxibenzene) 589 39.0 9.34 C6H7N aniline ( aminobenzene) 589 15.0 12.2 C6H 11Cl chlorocyclohexane ( cyclohexylchloride) 589 13.0 4.25 C6H1203 paraldehyde (paraacetaldehyde) 589 17.3 3.46 C6H140 2-hexanol (butylmethylcarbinol) 589 20.0 3.81 C6H140 3-hexanol ( ethylpropylcarbinol) 589 20.0 3.78 C6HI40 2-methyl-3-pentanol 589 20.0 3.84 C6H404N2 1 ,3-dinitrobenzene ( m-dinitrobenzene) 589 17.1 6.31 C6H50 2N nitrobenzene 589 15.0 6.31 C7Hs toluene (methylbenzene) 589 15.0 7.88 C7H14 1-heptene ( a-heptylene) 589 18.0 4.16 C7H16 heptane 589 15.0 3.58 C7H5N benzonitrile (benzenecarbonitrile) 589 15.7 7.97 C7H7Cl o-chlorotoluene (2-chloro-1-methylbenzene) 589 15.4 8.58 C7H7Cl p-chlorotoluene ( 4-chloro-1-methylbenzene) 589 15.2 7.71 C7H7Br o-bromotoluene (2-bromo-1-methylbenzene) 589 16.7 8.96 C7H7Br p-bromotoluene( 4-bromo-1-methylbenzene) 589 39.0 8.38 C7H80 a-cresol (o-methylphenol) 589 16.0 8.93

Verdet Constants V of Organic Liquids (from Ref. 7)- continued Formula Name 'A(nm) TCC) V (rad/T m)

C7H80 m-cresol (m-methylphenol) 589 17.9 8.41 C7H80 p-cresol (p-methylphenol) 589 17.0 8.46 C7H9N a-toluidine ( o-methylaniline) 589 17.3 11.0 C7H9N m-toluidine (m-methylaniline) 589 15.0 10.4 C7H9N p-toluidine (p-methylaniline) 589 50.0 9.80 C7H140 enanthaldehyde (heptanal) 589 16.2 3.67 C7H160 1-heptanol (n-heptylalcohol) 589 12.6 3.87 C7H160 2-heptanol (amylmethylcarbinol) 589 20.0 3.84 C7H160 3-heptanol (butylethylcarbinol) 589 20.0 3.99 C7H70 2N o-nitrotoluene 589 18.0 6.28 C7H702N p-nitrotoluene 589 54.3 5.73 CsHJO ethylbenzene (phenyl ethane) 589 15.0 8.14 CgH 10 o-xilene ( 1 ,2-dimethy !benzene) 589 15.0 7.62 C8H10 m-xilene ( 1 ,3-dimethylbenzene) 589 15.0 7.18 CsHJO p-xilene (1 ,4-dimethylbenzene) 589 15.0 7.16 CsH16 1-octene (a-octylene) 589 15.0 4.19 CsHJ6 2-octene (b-octy1ene) 589 15.0 4.16 CsH1s octane 589 15.0 3.67 C8H180 1-octano1 (n-octyl alcohol) 589 20.0 3.87 C8H180 2-octanol (methylhexylcarbinol) 589 20.0 3.90 C8H180 3-octanol ( ethylamylcarbinol) 589 20.0 3.87 C9H12 a-ethyl toluene ( 1-ethyl-2-ethylbenzene) 589 15.0 6.75 C9H12 m-ethyltoluene ( 1-ethyl-3-ethylbenzene) 589 15.0 8.46 C9H12 p-ethylbenzene (1-ethyl-4-ethylbenzene) 589 15.0 6.89 C9H12 mesitylene (1-3-5-trimethylbenzene) 589 15.0 6.63 CgH2o nonane 589 15.0 3.72 ClOHs naphthalene 589 89.5 13.0 C10H2o 1-decene (n-decylene) 589 21.0 4.22 C10H22 decane 589 15.0 3.78 C10H7Cl 1-chloronaphthalene (a-chloronaphthalene) 578 18.0 14.3 C10H7Br 1-bromonaphthalene (a-bromonaphthalene) 578 20.0 15.1 C 10H80 b-naphthol (2-hydroxinaphthalene) 578 13.6 14.0 C10H9N 1-naphthylamine (a-naphthylamine) 589 32.6 19.9 C10H1202 isoeugenol (4-propenylguaiacol) 589 19.3 10.33 CwH1202 eugenol ( 4-allylguaiacol) 589 15.4 8.38 C10H1202 benzoic acid propylester (n-propylbenzoate) 589 15.4 6.40 C10H1202 o-toluic acid ethyl ester 589 15.2 6.54 C10H1202 p-toluic acid ethyl ester 589 15.0 6.34 C10H1202 a-toluic acid ethyl ester ( ethylphenylacetate) 589 14.0 6.54 CwH1202 methylsaliciclic acid ethylester 589 18.6 7.27 C10H180 a-terpineol 589 16.0 4.54 ClOHisO Citronella! 589 14.5 4.39 C10H180 4 dipropylsuccinate 589 11.4 3.55 CwHw06 tartaric acid dipropyl ester (propyl tartrate) 589 15.4 3.61 CwH2oO menthol 589 45.2 4.07 C11H24 undecane 589 20.5 3.81 C12H26 dodecane 589 21.5 3.84

Verdet Constants V of Organic Liquids (from Ref. 7)- continued Formula Name A (nm) T(0 C) V (rad/T m)

C,4HIO c,6H34 c,sH14 C,sHzz

phenanthrene hexadecane 1 ,2-diphenylbenzene 1 ,6-diphenylhexane

578 589 589 589

100.0 17.0 15.0 3.93 15.0 13.7 20.0 8.00

Dispersion of the Verdet Constant V in the Near Ultraviolet and Visible V("A)(rad!f·m), "A(nm)

Formula Name 347.1 457.9 488.0 514.5 580.0

CH3N02 nitromethane 4.07 3.58 3.26 2.60 CH40 methanol 8.46 4.68 4.16 3.69 3.00 CzH40z acetic acid 9.75 5.29 4.65 4.13 3.29 C2H60 ethanol 10.5 5.61 4.95 4.45 3.49 C3H60 acetone 10.5 5.64 4.95 4.45 3.46 H20 water 12.4 6.78 5.85 5.24 4.10 CC14 carbon tetrachloride 15.4 8.03 7.04 6.31 4.95 C6H5N02 nitrobenzene 10.7 9.60 8.41 6.66 C7Hs toluene 31.4 14.3 12.2 10.7 8.09 C6H6 benzene 16.0 13.6 12.1 9.13 CS2 carbon disulfide 22.2 19.2 16.8 12.9

Liquids are listed in increasing order of the Verdet constantS

0 Carbon disulfide

i ""':

"" 20 oa

"" ... 4J > 5

Wavelength (nm) Dispersion of the Verdet constant for several liquids

listed in the table above

632.8 694.3

2.15 1.67 2.40 1.88 2.71 2.09 2.90 2.30 2.84 2.79 3.35 2.66 4.04 3.23 5.41 4.33 6.60 5.24 7.39 5.93

10.4 8.26

Dispersion of the Verdet Constant V in the Near Infrared2 VA-) (rad/T·m), A-(um)

Formula Name 0.6 0.8 1.0 1.5 2.0

H20 water 3.67 2.04 1.28 (0.844 at 1.25 _m) SnCI4 tin tetrachloride 11.9 6.31 3.93 1.75 0.902 TiCI4 titanium tetrachloride -3.81 -1.45 -0.756 -0.291 -0.145 CC14 carbon tetrachloride 4.68 2.59 1.66 0.727 0.378 CS2 carbon disulfide 11.5 6.23 3.93 1.69 0.902 CHCI3 chloroform 4.51 2.50 1.63 0.698 0.378 CH3I methyl iodide 9.25 5.18 3.26 1.40 0.785 CH2I2 methylene iodide 13.8 7.80 4.92 2.12 1.16 CH40 methyl alcohol 2.71 1.48 0.931 0.553 0.378 C2H5I ethyl iodide 8.12 4.39 2.82 1.19 0.698 C2H60 ethyl alcohol 3.23 1.75 1.11 0.553 0.291 C3H60 acetone 3.00 1.77 1.16 0.495 0.262 C4H100 ethyl ether 2.97 1.69 1.05 0.465 0.233 C4H100 n-butyl alcohol 3.49 1.95 1.25 0.524 0.407 C6H6 benzene 8.17 4.45 2.76 1.13 0.640 C6H5N02 nitrobenzene 6.08 3.32 2.12 0.902 0.524 C7Hs toluene 7.50 3.99 2.53 1.02 0.582 C7H16 n-heptane 3.46 1.92 1.25 0.524 0.262 CsHJO xilene 6.75 3.72 2.33 1.02 0.553 C10H7Br a-bromonaphthalene 13.4 7.13 4.42 1.83 1.02

Temperature= 23°C.